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Methyl trioctyl ammonium chloride

Description Reference
Product Name
Methyl trioctyl ammonium chloride
CAS No.
5137-55-3
Chemical Name
Methyl trioctyl ammonium chloride
Synonyms
ALIQUAT 336;aliquat;ADOGEN 464;METHYLTRIOCTYLAMMONIUM CHLORIDE;TRICAPRYLYLMETHYLAMMONIUM CHLORIDE;TOMAC;TRIOCTYLMETHYLAMMONIUM CHLORIDE;TRICAPRYLMETHYLAMMONIUM CHLORIDE;METHYLTRI-N-OCTYLAMMONIUM CHLORIDE;trioctylmethylammonium
CBNumber
CB4412612
Molecular Formula
C25H54N.Cl
Formula Weight
404.16
MOL File
5137-55-3.mol
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Methyl trioctyl ammonium chloride Property

Melting point:
-20°C
Boiling point:
240°C
Density 
0.884 g/mL at 25 °C(lit.)
vapor pressure 
0Pa at 25℃
refractive index 
n20/D 1.4665(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
soluble in Chloroform, Hexanes
form 
Viscous Liquid
color 
Colourless to pale orange
Odor
Ammonical
Water Solubility 
Partially insoluble
Sensitive 
Hygroscopic
BRN 
4039255
Stability:
Stable. Incompatible wth strong oxidizing agents. Hygroscopic.
InChIKey
XKBGEWXEAPTVCK-UHFFFAOYSA-M
LogP
4.5 at 25℃
CAS DataBase Reference
5137-55-3(CAS DataBase Reference)
EPA Substance Registry System
Methyltrioctylammonium chloride (5137-55-3)
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Safety

Hazard Codes 
Xn,N,C
Risk Statements 
22-38-41-50/53-36/37/38-20/21/22-34
Safety Statements 
26-39-60-61-36-45-36/37/39
RIDADR 
UN 2810 6.1/PG 3
WGK Germany 
3
RTECS 
UZ2997500
F 
3-10
HazardClass 
6.1
PackingGroup 
III
HS Code 
29239000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
69485
Product name
Methyltrioctylammonium chloride
Purity
≥97.0% (AT)
Packaging
10g
Price
$109
Updated
2024/03/01
Sigma-Aldrich
Product number
69485
Product name
Methyltrioctylammonium chloride
Purity
≥97.0% (AT)
Packaging
50g
Price
$385
Updated
2024/03/01
TCI Chemical
Product number
T1365
Product name
Methyltri-n-octylammonium Chloride
Purity
>95.0%(T)
Packaging
25g
Price
$106
Updated
2024/03/01
TCI Chemical
Product number
T1365
Product name
Methyltri-n-octylammonium Chloride
Purity
>95.0%(T)
Packaging
500g
Price
$1189
Updated
2024/03/01
Usbiological
Product number
261427
Product name
Tricaprylylmethylammonium chloride
Packaging
100g
Price
$333
Updated
2021/12/16
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Methyl trioctyl ammonium chloride Chemical Properties,Usage,Production

Description

Methyltrioctylammonium chloride is a water insoluble quaternary ammonium salt, which is widely used as a counter ion in solvent extraction of anionic metal complexes. It is widely used as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. In comparison to traditional method of oxidizing cyclohexanol or cyclohexanone with nitric acid or potassium permanganate, the usage of methyltrioctylammonium chloride is a more environmentally friendly reaction.

Reference

N. Pourreza, H. Zavvar Mousavi, Determination of cadmium by flame atomic absorption spectrometry after preconcentration on naphthalene– methyltrioctylammonium chloride adsorbent as tetraiodocadmate (II) ions, Analytica Chimica Acta, 2004, vol. 503, pp. 279-282

Chemical Properties

viscous colourless to pale orange liquid

Uses

Methyltrioctylammonium chloride can be used:

  • As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.
  • As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.
  • As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H2O.

Uses

Mixture of C8 and C10 chains with C8 predominating. Used as a metal extraction reagent and a phase-transfer catalyst.

Definition

ChEBI: An organic chloride salt having methyltrioctylammonium as the cation.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-.

Purification Methods

A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]

Methyl trioctyl ammonium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

1,3-Dimethyl-2-imidazolidinone 4-Chlorobenzylsulfonyl chloride (2-CHLORO-PHENYL)-METHANESULFONYL CHLORIDE (4-BROMOTHIOPHEN-2-YL)METHANESULFONYL CHLORIDE 3-NITROPHENYLMETHANESULFONYL CHLORIDE 6-BENZYLOXYPURINE (5-BROMOTHIOPHEN-3-YL)METHANESULFONYL CHLORIDE
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View Lastest Price from Methyl trioctyl ammonium chloride manufacturers

Anhui Royal Chemical Co., Ltd.
Product
METHYL TRIOCTYL AMMONIUM CHLORIDE 5137-55-3
Price
US $2430.00/kg
Min. Order
900kg
Purity
90%
Supply Ability
10 tons
Release date
2024-05-22
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Methyl trioctyl ammonium chloride 5137-55-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-30
HebeiShuoshengImportandExportco.,Ltd
Product
Methyl trioctyl ammonium chloride 5137-55-3
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-08

5137-55-3, Methyl trioctyl ammonium chlorideRelated Search:

Tetraoctylammonium chloride Ammonium sulfate Potassium chloride Sodium chloride Triethylmethylammonium chloride Polyvinyl chloride Triton X-100 Calcium chloride Ammonium hydroxide Sulfuryl chloride Choline chloride Ammonium acetate Ammonium chloride Ferric chloride Methyltrioctylammonium bromide 4-tert-Octylphenol Methyltriphenylphosphonium bromide Methyltriphenylphosphonium iodide

  • TRICAPRYLMETHYLAMMONIUM CHLORIDE
  • TRICAPRYLYLMETHYLAMMONIUM CHLORIDE
  • TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE
  • TRI-N-OCTYLMETHYLAMMONIUM CHLORIDE
  • TRIOCTYLMETHYLAMMONIUM CHLORIDE
  • TOMAC
  • TricapryL
  • CAPRIQUAT
  • METHYLTRIOCTYLAMMONIUM CHLORIDE
  • METHYLTRIOCTYLAMINE HYDROCHLORIDE
  • METHYLTRI-N-OCTYLAMMONIUM CHLORIDE
  • Aliquat(rg 336
  • METHYLTRICAPRYLAMMONIUM CHLORIDE
  • Methyltri-n-octylammonium chloride~Tricaprylylmethylammonium chloride
  • Trictylmethylammonium chloride
  • METHYLTRI-N-OCTYLAMMONIUM
  • N-Methyl-N,N,N-trioctylammonium chloride
  • AliquatÖÖ(rg336
  • Trioctylmethylammonium Chloride (R=C6-C10) [Phase-transfer Catalyst]
  • ALIQUAT(R) 336
  • ALIQUAT(TM) 336
  • ALIQUAT 336
  • ADOGEN 464
  • Aliquat 336, average MW 442
  • AMMONIUM,METHYLTRIOCTYL-,CHLORIDE
  • ALIQUAT 336 (TRIOCTYLMETHYLAMMONIUM CHLORIDE)
  • Trioctylmonomethylammonium chloride
  • Methyltrioctylammonium chloride ,90%
  • Aliquat 336N
  • Aliquat 336-PTC
  • Methyltri(octyl)aminium
  • Methyltrioctylaminium
  • 1-Octanaminium,N-methyl-N,N-dioctyl-,chloride
  • aliquat
  • methyltricaprylylammoniumchloride
  • methyltrioctyl-ammoniuchloride
  • n-methyl-n,n-dioctyl-1-octanaminiuchloride
  • n-methyl-n,n-dioctyl-1-octanaminiumchloride
  • trioctylmethylammonium
  • Methyltrioctylammonium
  • N-Methyl-N,N,N-trioctylaminium
  • Trioctylmethylaminium
  • TRICAPRYLYL MONOMETHYLAMMONIUM CHLORIDE, 75% SOLN
  • Methyltrioctylammoni
  • Methyltrioctylammonium chloride purum, >=97.0% (AT)
  • Nsc61369
  • Trioctylmethylammonium chloride ,98%
  • TOMAC 75
  • N-Methyl-N,N-dioctyloctan-1-aMiniuM chloride
  • DeMecolcine research grade
  • 1-OctanaMiniuM,N-Methyl-N,N-dioctyl-, chloride (1:1)
  • MethyltrioctylaMMoniuM chloride >=97.0% (AT)
  • Three octyl diMethyl aMMoniuM chloride (5137-55-3) Methyl octyl three aMMoniuM chloride
  • MethyltrioCLylaMMoniuM Chloride
  • N8,8,8,1Cl
  • Methyl trioctyl ammonium chloride Liquid
  • Methyl Trioctylammonum Chloride
  • Aliquat 336Aliquat 336