Bis(2-ethylhexyl) phosphate Property

Melting point:

−60 °C(lit.)

Boiling point:

48 °C (12 mmHg)

Density 

0.965 g/mL at 25 °C(lit.)

vapor pressure 

<0.1 hPa (20 °C)

refractive index 

n20/D 1.443(lit.)

Flash point:

>230 °F

storage temp. 

Store below +30°C.

solubility 

ethanol: soluble100mg/mL, clear

form 

Liquid

pka

1.47±0.50(Predicted)

Specific Gravity

0.974

color 

Colorless

PH

3 (< 1g/l, H2O)

Water Solubility 

slightly soluble

FreezingPoint 

-60℃

BRN 

1712988

Stability:

Moisture Sensitive

InChIKey

SEGLCEQVOFDUPX-UHFFFAOYSA-N

LogP

2.88 at 25℃

CAS DataBase Reference

298-07-7(CAS DataBase Reference)

NIST Chemistry Reference

Bis(2-ethylhexyl)hydrogen phosphate(298-07-7)

EPA Substance Registry System

Bis(2-ethylhexyl) phosphate (298-07-7)

Safety

Hazard Codes 

C

Risk Statements 

21-34

Safety Statements 

26-36/37/39-45-25

RIDADR 

UN 1902 8/PG 3

WGK Germany 

1

RTECS 

TB7875000

Autoignition Temperature

255 °C

TSCA 

Yes

HazardClass 

8

PackingGroup 

III

HS Code 

29190090

Hazardous Substances Data

298-07-7(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 4940 mg/kg LD50 dermal Rabbit 1250 mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H312Harmful in contact with skin

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Bis(2-ethylhexyl) phosphate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Additive to lubrication oils, corrosion inhibitor, and antioxidant. Used as extractant in the hydrometallurgical separation of cobalt and nickel. Metal extraction and separation, intermediate for wetting agents and detergents . Feedstock for chemical synthesis; extraction fluid for metal salts; cation extracting agent.

Uses

Extraction of metals.Bis(2-ethylhexyl) phosphate is used as a lubricant additive, corrosion inhibitor and a metal extractant. It is involved in the solvent extraction of uranium salts and rare earth metals. Iron(II) ions are extracted after reduction of Iron(III) ions. Further, it is used as a plasticizer and as a solvent in the synthesis of plastic.

Production Methods

Produced by chlorinating bis(2-ethylhexyl) phosphonate to give the phosphate diester chloride, followed by hydrolysis, or by saponification of tris(2-ethylhexyl) phosphate .

Synthesis

2-ethylhexan-1-ol could be used as a starting material to synthesize Bis(2-ethylhexyl) phosphate.

General Description

Odorless light yellow liquid. Floats on water.

Reactivity Profile

Organophosphates, such as Bis(2-ethylhexyl) phosphate, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Mildly corrosive to most metals; may form flammable hydrogen gas [USCG, 1999].

Health Hazard

Contact with liquid irritates eyes and may cause serious injury; consult an eye specialist. Also causes skin irritation on contact. Ingestion produces irritation similar to that caused by strong vinegar.

Fire Hazard

Special Hazards of Combustion Products: Irritating phosphorus oxides may be released.

Flammability and Explosibility

Non flammable

Purification Methods

Contaminants of commercial samples include the monoester, polyphosphates, pyrophosphate, 2-ethylhexanol and metal impurities. Dissolve the acid in n-hexane to give an 0.8M solution. Wash this with an equal volume of M HNO3, then with saturated (NH4)2CO3 solution, with 3M HNO3, and twice with water [Petrow & Allen Anal Chem 33 1303 1961]. Similarly, the impure sodium salt, after scrubbing with pet ether, is acidified with HCl and the free organic acid is extracted into pet ether and purified as above [Peppard et al. J Inorg Nucl Chem 7 231 1958], or as described by Stewart & Crandall [J Am Chem Soc 73 1377 1951]. It can be purified via its copper salt [McDowell et al. J Inorg Nucl Chem 38 2127 1976]. [Beilstein 1 IV 1796.]