ChemicalBook > CAS DataBase List > ETHYL 2 3-BUTADIENOATE 95

ETHYL 2 3-BUTADIENOATE 95

Product Name
ETHYL 2 3-BUTADIENOATE 95
CAS No.
14369-81-4
Chemical Name
ETHYL 2 3-BUTADIENOATE 95
Synonyms
2,3-Butadienoate;ethyl buta-2,3-dienoate;Ethyl2,3-Butadienoate>ETHYL 2,3-BUTADIENOATE 95%;ETHYL 2 3-BUTADIENOATE 95;2,3-Butadienoic Acid Ethyl Ester
CBNumber
CB4499448
Molecular Formula
C6H8O2
Formula Weight
112.13
MOL File
14369-81-4.mol
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ETHYL 2 3-BUTADIENOATE 95 Property

Boiling point:
80 °C60 mm Hg(lit.)
Density 
0.966 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.46(lit.)
Flash point:
116 °F
storage temp. 
<0°C
form 
clear liquid
color 
Colorless to Light yellow
λmax
209nm(MeOH)(lit.)
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Safety

Risk Statements 
10
RIDADR 
UN 1993 3/PG 2
WGK Germany 
3
HazardClass 
3
PackingGroup 
III
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
494992
Product name
Ethyl 2,3-butadienoate
Purity
95%
Packaging
1g
Price
$66
Updated
2024/03/01
Sigma-Aldrich
Product number
494992
Product name
Ethyl 2,3-butadienoate
Purity
95%
Packaging
5g
Price
$226.2
Updated
2024/03/01
TCI Chemical
Product number
E0820
Product name
Ethyl 2,3-Butadienoate
Purity
>95.0%(GC)
Packaging
1g
Price
$86
Updated
2024/03/01
TCI Chemical
Product number
E0820
Product name
Ethyl 2,3-Butadienoate
Purity
>95.0%(GC)
Packaging
5g
Price
$343
Updated
2024/03/01
TRC
Product number
E900990
Product name
EthylButa-2,3-dienoate
Packaging
100mg
Price
$60
Updated
2021/12/16
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ETHYL 2 3-BUTADIENOATE 95 Chemical Properties,Usage,Production

Uses

Ethyl Buta-2,3-dienoate is a useful reactant for the synthesis of 9H-?pyrrolo[1,?2-?a]?indole derivatives via a phosphine-?promoted Michael addn.?/intramol. Wittig reaction.

Uses

Ethyl 2,3-butadienoate may be used in the synthesis of dihydropyrans by reacting with acyclic enones. It may also be used to synthesize spiranic heterocycles by reacting with heterocyclic bis-arylidene ketones via phosphine-catalyzed [3+2] annulations.

General Description

Ethyl 2,3-butadienoate is an α-allenic ester. The reaction of ethyl 2,3-butadienoate with N-tosylated imines in the presence of DABCO (1,4-diazabicyclo[2.2.2]octane) or DMAP (4-dimethylaminopyridine) forms azetidine derivatives or novel dihydropyridine derivatives respectively. The performance of bifunctional N-acyl aminophosphines to catalyze the asymmetric [3+2] cycloaddition of phenylidenemalononitrile with ethyl 2,3-butadienoate has been evaluated.

ETHYL 2 3-BUTADIENOATE 95 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ETHYL 2 3-BUTADIENOATE 95 manufacturers

Huida Pharmaceutical Technology (Shanghai) Co., Ltd.
Product
ETHYL 2 3-BUTADIENOATE 95 14369-81-4
Price
US $0.00-0.00/kg
Min. Order
0.1kg
Purity
98%+
Supply Ability
100kg
Release date
2023-03-01

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  • ETHYL 2 3-BUTADIENOATE 95
  • ETHYL 2,3-BUTADIENOATE 95%
  • 2,3-Butadienoic Acid Ethyl Ester
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