Triclopyr

ChemicalBook > CAS DataBase List > Triclopyr

Product Name: Triclopyr
CAS No.: 55335-06-3
Chemical Name: Triclopyr
Synonyms: Rely;opyr;Mutan;TricL;M 3724;Exetor;Garlon;Redeem;Remedy;TRIDENT
CBNumber: CB4666264
Molecular Formula: C7H4Cl3NO3
Formula Weight: 256.47
MOL File: 55335-06-3.mol

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Triclopyr Property

Melting point:: 148-150°C
Boiling point:: 290°C
Density: 1.7626 (rough estimate)
refractive index: 1.6200 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form: Liquid
pka: 2.68(at 25℃)
color: Fluffy solid
Water Solubility: 0.43g/L(temperature not stated)
Merck: 13,9730
BRN: 225301
CAS DataBase Reference: 55335-06-3(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid, [(3,5,6-trichloro-2-pyridinyl)oxy]-(55335-06-3)
EPA Substance Registry System: Triclopyr (55335-06-3)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 22-24/25
RIDADR: UN3082 (liquid)
WGK Germany: 3
RTECS: AJ9000000
HS Code: 2933.39.2500
Hazardous Substances Data: 55335-06-3(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 713 mg/kg (Kenaga)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

H371May cause damage to organs

H373May cause damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

P391Collect spillage. Hazardous to the aquatic environment

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 32016
Product name: Triclopyr
Purity: PESTANAL
Packaging: 250mg
Price: $35.3
Updated: 2024/03/01

TCI Chemical

Product number: T3742
Product name: Triclopyr
Packaging: 5G
Price: $77
Updated: 2024/03/01

TCI Chemical

Product number: T3742
Product name: Triclopyr
Packaging: 25G
Price: $231
Updated: 2024/03/01

Chem-Impex

Product number: 39365
Product name: Triclopyr,96%(Assaybytitration,GC)
Purity: 96%(Assaybytitration,GC)
Packaging: 25G
Price: $286.72
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: AGR0000048
Product name: TRICLOPYR
Purity: 95.00%
Packaging: 1G
Price: $203.7
Updated: 2021/12/16

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Triclopyr Chemical Properties,Usage,Production

Chemical Properties

White to Off-White Solid

Uses

Selective postemergence herbicide to control many woody and broad-leaved weeds.

Uses

Triclopyr is a selective post-emergence herbicide.

Definition

ChEBI: A monocarboxylic acid that is (pyridin-2-yloxy)acetic acid substituted by chloro groups at positions 3, 5 and 6. It is an agrochemical used as a herbicide.

Agricultural Uses

Herbicide: Triclopry is a systemic herbicide used on rice, range land and pasture, rights-of-way, forestry and grasslands, including home lawns, for control of broadleaf weeds and woody plants. Triclopry is usually available as a triclopyr butoxyethyl ester (BEE) or as a triclopry triethylamine salt (TEA). Registered for use in the U.S. Some products may be classified as Restricted Use Pesticides (RUP). Registered for use in EU countries . U.S. Maximum Allowable Residue Levels for Triclopyr and its metabolites 3,5,6,-trichloro-2-pyridinol and 2-methoxy-3,5,6-trichloropyridine [40 CFR 180.417 (a)(1)]: for the combined residues of the herbicide in or on the following raw agricultural commodities: fish 3.0 ppm; grass, forage 500 ppm; grass, forage, hay 500 ppm;shellfish3.5 ppm.[40 CFR 180.417 (a)(2)]: in or on the following agricultural commodities: egg 0.05 ppm; meat, fat, and meat byproducts, except kidney and liver, of cattle, goat, hog, horse and sheep 0.05 ppm; meat, fat, and meat byproducts, except kidney, of poultry 0.1 ppm; milk 0.01 ppm; liver and kidney of cattle, goat, hog, horse and sheep 0.5 ppm; rice, grain 0.3 ppm; rice, straw10.0 ppm.

Trade name

[Note: See the following record, Triclopyr, triethylamine salt, for trade names containing the salt of triclopry] ACCESS®; CROSSBOW®, (triclopyr + 2,4-D ester); ET®; GARLON®; GRAZON® Triclopyr; PATHFINDER®; REDEEM®; RELY®; REMEDY®; RIVERDALE TAHOE® Nufarm (Australia); TURFLON®

Safety Profile

Moderately toxic by ingestion. Anexperimental teratogen. Experimental reproductiveeffects. Used as an herbicide. When heated todecomposition it emits toxic fumes of Clí and NOx.

Environmental Fate

Soil. In soil, triclopyr degraded to 3,5,6-trichloro-2-pyridinol and 2-methoxy-3,5,6- trichloropyridine (Norris et al., 1987). The major route of dissipation from soil is likely due to microbial degradation (Newton et al., 1990).
Fifty-four days after triclopyr was applied to soil at a rate of 5.6 kg/ha, the majority (65%) remained in the top 10 cm of soil (Lee et al., 1986a).
Ashton and Monaco (1991) reported triclopyr had an average half-life of 46 days and is in?uenced by soil type and climatic conditions.
Plant. Lewer and Owen (1989) found 3,5,6-trichloro-2-pyridinol as the major metab- olite in plants. Cultured soybean cells metabolized triclopyr to dimethyl triclopyr-aspartate and dimethyl triclopyr-glutamate which can be rehydrolyzed to form the parent compound.
At an application rate of 3.4 kg/ha, the dissipation half-life was 3.7 days. At an application rate of 3.3 kg/ka, the dissipation half-lives of triclopyr in brown, browse and litter samples were 73.5, 202.3 and 31 days, respectively (Norris et al., 1987).

Metabolic pathway

After 7 days in a soybean cell suspension culture, the major metabolites of trichlopyr are formed and identified as the aspartate (major) and glutamate (minor) amide conjugates.

Metabolism

The average half-life of triclopyr in soil is 46 days. Because triclopyr is sensitive to light, the length of time that it remains on the surface may moderate its persistence. Adsorption to soil is limited and is governed by the anion exchange capacity. Insignificant amounts are lost via volatilization. The propensity of triclopyr to translocate in the environment with soil water, is unknown.

Toxicity evaluation

The acute oral LD₅₀ of triclopyr is 692 mg/kg and 577 mg/kg for male and female rat, respectively. It does not appear to undergo significant transformation and is excreted in the urine primarily unchanged.

Triclopyr Preparation Products And Raw materials

Raw materials

2,3,5,6-Tetrachloropyridine

Preparation Products

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Triclopyr Suppliers

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View Lastest Price from Triclopyr manufacturers

Hebei Mojin Biotechnology Co., Ltd

Product: Triclopyr 55335-06-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-20

Hebei Guanlang Biotechnology Co., Ltd.

Product: Triclopyr 55335-06-3
Price: US $10.00/KG
Min. Order: 100KG
Purity: 99%
Supply Ability: 100 mt
Release date: 2021-11-08

Career Henan Chemical Co

Product: Triclopyr 55335-06-3
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 1000KGS
Release date: 2019-12-24

55335-06-3, TriclopyrRelated Search:

Trichloroacetic acid Acetoxyacetic acid Methoxyacetic acid Methyl trichloroacetate 4-Methoxyphenylacetic acid acetic acid, triethoxy-, ethyl ester 3,5-DICHLORO-2-PYRIDONE 3,5-Dichloropyridine TRICLOPYR METHYL ESTERSUFFIX ADDED TO CAS TO DIFFERENTIATE FROM NON-DEUTERATED/DERIVATIZED COMPOUND. 2-CHLORO-6-ETHOXYPYRIDINE (2-Pyridinyloxy)acetic acid 2-Ethoxypyridine 2,3-Dichloropyridine 5-CHLORO-2-HYDROXYPYRIDINE Sodium 3,5,6-trichloropyridin-2-olate 5-Chloro-2-methoxypyridine 3-Chloropyridin-2-ol 3-Chloro-2-ethoxypyridine

TIMTEC-BB SBB003109

TRIDENT

TRICLOPYR

(3,5,6-trichloro-2-pyridyloxy)-aceticaci

[(3,5,6-trichloropyridin-2-yl)oxy]ethanoicacid

3,5,6-trichloro-2-pyridinyloxyethanoicacid

Ace-brush

Acetic acid, ((3,5,6-trichloro-2-pyridyl)oxy)-

Crossbow

3,5,6-TRICHLORO-2-PYRIDINE OXYACETIC ACID

3,4,6-trichloro-2-pyridinyloxyacetic acid

[(3,5,6-trichloropyridin-2-yl)oxy]acetic acid

TRICLOPYR ACID

TRICLOPYR, 500MG, NEAT

TRICLOPYR PESTANAL (3,5,6-TRICHLORO-2-PY

TRICLOPYR [3.5.6-TRICHOLOR-2-PYRIDINE OXYACETIC ACID ]

3.5.6-tricholor-2-pyridine oxyacetic acid

Hca-60%

Acetic acid, (3,5,6-trichloro-2-pyridinyl)oxy-

TRICHLORPYR

M 3724

3,5,6-Trichloro-2-pyridinyloxyacetic acid - Parent, esters, salts

2-(3,5,6-trichloropyridin-2-yl)oxyacetic acid

2-(3,5,6-trichloropyridin-2-yl)oxyethanoic acid

2-[(3,5,6-trichloro-2-pyridyl)oxy]acetic acid

Triclopyr 500mg [55335-06-3]

[(3,5,6-tTichloro-2-pyridyl)oxy]acetic Acid

2-[(3,5,6-Trichloro-2-pyridinyl)oxy]acetic Acid

Triclopyr Standard

CrossbowTurflon

Curtail

Dowco 233

dowco233

Exetor

Garlon

grazonet

Mutan

Redeem

Rely

Remedy

Timbrel

Trichlopyr

Tticlopyr

Turflon

GARLON(R)

[(3,5,6-TRICHLORO-2-PYRIDINYL)OXY]-ACETIC ACID

[(3，5，6-Trichloro-2-pyridyl)oxy]aceticacid

3,5,6-TPA

Garlon 2

Garlon 250

NSC 190671

2-((3,5,6-Trichloropyridin-2-yl)

Triclopyr Solution, 1000ppm

Crossbow(TM)

Triclopyr @100 μg/mL in AcCN

TriclopyrSolution,1,000mg/L,1ml

Triclopyr @100 μg/mL in MeOH

TriclopyrSolution,100mg/L,1ml