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Tetraethyl orthocarbonate

Product Name
Tetraethyl orthocarbonate
CAS No.
78-09-1
Chemical Name
Tetraethyl orthocarbonate
Synonyms
TETRAETHOXYMETHANE;ethyl orthocarbonate;Tetraethyl orthocarb;Four ethyl carbonate;Ethane, 1,1‘,1‘‘,1‘‘‘-;Tetraethyl-2-carbonate;triethoxymethoxy-ethane;TRIETHYL ORTHOCARBONATE;Teraethyl orthocarbonate;Tetraehtylorthocarbonate
CBNumber
CB4702616
Molecular Formula
C9H20O4
Formula Weight
192.25
MOL File
78-09-1.mol
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Tetraethyl orthocarbonate Property

Melting point:
222 °C
Boiling point:
159 °C (lit.)
Density 
0.919 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.392(lit.)
Flash point:
127 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Chloroform, Methanol
form 
clear liquid
Specific Gravity
0.919
color 
Colorless to Almost colorless
Water Solubility 
Insoluble
Sensitive 
Moisture Sensitive
BRN 
1747401
CAS DataBase Reference
78-09-1(CAS DataBase Reference)
NIST Chemistry Reference
Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis-(78-09-1)
EPA Substance Registry System
Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis- (78-09-1)
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Safety

Hazard Codes 
Xi,F
Risk Statements 
10-36/37/38
Safety Statements 
37/39-26-16-36-24/25
RIDADR 
UN 3272 3/PG 3
WGK Germany 
3
21
HazardClass 
3
PackingGroup 
III
HS Code 
29209010
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
163627
Product name
Tetraethyl orthocarbonate
Purity
97%
Packaging
5g
Price
$32.34
Updated
2024/03/01
Sigma-Aldrich
Product number
163627
Product name
Tetraethyl orthocarbonate
Purity
97%
Packaging
25g
Price
$97.2
Updated
2024/03/01
TCI Chemical
Product number
T1107
Product name
Tetraethoxymethane
Purity
>97.0%(GC)
Packaging
5mL
Price
$45
Updated
2024/03/01
TCI Chemical
Product number
T1107
Product name
Tetraethoxymethane
Purity
>97.0%(GC)
Packaging
25mL
Price
$132
Updated
2024/03/01
Alfa Aesar
Product number
A17835
Product name
Tetraethyl orthocarbonate
Purity
97+%
Packaging
25g
Price
$163
Updated
2024/03/01
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Tetraethyl orthocarbonate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Tetraethyl Orthocarbonate is used in the synthesis of chemokine receptor-5 inhibitors against HIV-1, benzobisoxazoles and in the preparation of organic semiconductors. It is also employed in the synthesis of 2,7-dimethylene-1,4,6,9-tetraoxaspiro[4,4]nonane and in the synthesis of cross linked poly(orthocarbonate)s used as organic solvent absorbent.

Purification Methods

Likely impurities are hydrolysis products. Shake the orthocarbonate with brine (saturated NaCl, dilute with a little Et2O if amount of material is small) and dry (MgSO4). The organic layer is filtered off and evaporated, and the residue is distilled through a helices packed fractionating column with a total reflux partial take-off head. All distillations can be done at atmospheric pressure in an inert atmosphere (e.g. N2). [Roberts & McMahon Org Synth Coll Vol IV 457 1963, Connolly & Dyson J Chem Soc 828 1937, Tieckelmann & Post J Org Chem 13 266 1948, for review see Kantlehner et al. Justus Liebigs Ann Chem 507 207 1982, Beilstein 3 IV 6.]

Tetraethyl orthocarbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetraethyl orthocarbonate Suppliers

CHEMOS GmbH & Co. KG
Tel
--
Fax
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Email
chemos@chemos.de
Country
Germany
ProdList
6727
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58
Merck Millipore
Tel
--
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Email
ccc@merckgroup.com
Country
Germany
ProdList
2008
Advantage
58
Evonik Industries AG.
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Email
@evonik.com
Country
Germany
ProdList
351
Advantage
58
Alfa Aesar, Thermo Fisher Scientific
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Fax
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Email
es@alfa.com
Country
Germany
ProdList
5123
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58
Aaron Chemistry GmbH
Tel
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Email
sales@aaron-chemistry.de
Country
Germany
ProdList
579
Advantage
60
ratiochem GmbH
Tel
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Email
info@ratiochem.org
Country
Germany
ProdList
310
Advantage
34
ABCR GmbH & CO. KG
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Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Service Chemical Inc.
Tel
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Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
Fine & Performance Chemicals Ltd
Tel
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Email
enquiries@fpci.co.uk
Country
Germany
ProdList
68
Advantage
51
Merck Schuchardt OHG
Tel
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Fax
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Email
schuchardt-vertrieb@merck.de
Country
Germany
ProdList
5827
Advantage
74
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View Lastest Price from Tetraethyl orthocarbonate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Tetraethyl orthocarbonate 78-09-1
Price
US $200.00-95.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-24
Hebei Weibang Biotechnology Co., Ltd
Product
Tetraethyl orthocarbonate 78-09-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-22
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetraethyl orthocarbonate 78-09-1
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
1000KGS
Release date
2021-06-30

78-09-1, Tetraethyl orthocarbonateRelated Search:


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  • Acetals/Ketals/Ortho Esters
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  • 78-09-1