ChemicalBook > CAS DataBase List > Dimethyl 2-(2-methoxyphenoxy)malonate

Dimethyl 2-(2-methoxyphenoxy)malonate

Product Name
Dimethyl 2-(2-methoxyphenoxy)malonate
CAS No.
150726-89-9
Chemical Name
Dimethyl 2-(2-methoxyphenoxy)malonate
Synonyms
2-MethoxyphenoxyMalonate;Dimethyl (o-Methoxyphenoxy)malonate;DIMETHYL (2-METHOXYPHENOXY)MALONATE;Dimethyl-2-(2-methoxyphenoxy)malonate;1,3-diMethyl 2-(2-Methoxyphenoxy)propanedioate;2-(2-Methoxyphenoxy)malonic acid dimethyl ester;(2-Methoxyphenoxy)-propanedioic Acid Dimethyl Ester;2-methoxy-2-phenoxypropanedioic acid dimethyl ester;Propanedioic acid, 2-(2-methoxyphenoxy)-, 1,3-dimethyl ester;TIANFUCHEM--150726-89-9--High purity Dimethyl 2-(2-methoxyphenoxy)malonate in stock
CBNumber
CB4738859
Molecular Formula
C12H14O6
Formula Weight
254.24
MOL File
150726-89-9.mol
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Dimethyl 2-(2-methoxyphenoxy)malonate Property

Boiling point:
320.5±27.0 °C(Predicted)
Density 
1.206±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Dichloromethane, Methanol
form 
Solid
pka
12.17±0.59(Predicted)
color 
White
InChI
InChI=1S/C12H14O6/c1-15-8-6-4-5-7-9(8)18-10(11(13)16-2)12(14)17-3/h4-7,10H,1-3H3
InChIKey
SBUXKADXTZOBJV-UHFFFAOYSA-N
SMILES
C(OC)(=O)C(OC1=CC=CC=C1OC)C(OC)=O
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
D474785
Product name
Dimethyl2-Methoxyphenoxymalonate
Packaging
5g
Price
$1175
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD22240
Product name
Dimethyl 2-methoxyphenoxymalonate
Packaging
10Kg
Price
$1365
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0014259
Product name
DIMETHYL 2-METHOXYPHENOXYMALONATE
Purity
95.00%
Packaging
5G
Price
$2044.35
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD22240
Product name
Dimethyl 2-methoxyphenoxymalonate
Packaging
2Kg
Price
$428
Updated
2021/12/16
Matrix Scientific
Product number
074660
Product name
Dimethyl 2-(2-methoxyphenoxy)malonate
Purity
95+%
Packaging
10g
Price
$572
Updated
2021/12/16
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Dimethyl 2-(2-methoxyphenoxy)malonate Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Dimethyl 2-Methoxyphenoxymalonate (cas# 150726-89-9) is a compound useful in organic synthesis.

Synthesis

28868-76-0

90-05-1

150726-89-9

Sodium methanol solution (2.3 g Na, 0.10 mol, 1.0 eq., dissolved in 75 ml of methanol) was slowly added dropwise to a stirred mixture of guaiacol (12.5 g, 0.100 mol, 1.0 eq.) and dimethyl 2-chloromalonate (19.0 g, 0.114 mol, 1.14 eq.). The reaction mixture was stirred at 45 °C for 1 hour. After completion of the reaction, the volatiles were evaporated by rotary evaporator. The residue was dissolved in toluene and washed sequentially with deionized water and 1% aqueous sodium bicarbonate. The organic phase was dried over anhydrous sodium sulfate and concentrated under reduced pressure to give 20.0 g (78.7% yield) of dimethyl 2-(2-methoxyphenoxy)malonate as a viscous oil. The product characterization data were as follows: boiling point 131 °C (literature value 128 °C); 1H NMR (CDCl3) δ 7.12-7.00 (m, 2H), 6.98-6.90 (m, 1H), 6.90-6.82 (m, 1H), 5.27 (s, 1H), 3.85 (s, 3H), 3.84 (s, 6H); 13C NMR ( CDCl3) δ 166.2 (2C), 150.4,146.0,124.4,120.8,119.0,112.5,78.4,55.8,53.0 (2C); HRMS calculated value of C12H14O6 255.0869 (M+H+), measured value 255.0870 (M+H+).

References

[1] European Journal of Medicinal Chemistry, 2016, vol. 121, p. 658 - 670
[2] Organic Preparations and Procedures International, 2016, vol. 48, # 6, p. 481 - 491
[3] Bioorganic and Medicinal Chemistry, 2001, vol. 9, # 4, p. 897 - 907
[4] Patent: US5292740, 1994, A
[5] Patent: WO2011/24056, 2011, A2. Location in patent: Page/Page column 19

Dimethyl 2-(2-methoxyphenoxy)malonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Dimethyl 2-(2-methoxyphenoxy)malonate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
Dimethyl 2-(2-methoxyphenoxy)malonate 150726-89-9
Price
US $0.00-0.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-30
Hebei Yanxi Chemical Co., Ltd.
Product
Dimethyl 2-(2-methoxyphenoxy)malonate 150726-89-9
Price
US $150.00-100.00/kg
Min. Order
1kg
Purity
604-747-9
Supply Ability
20MT/Month
Release date
2023-11-16
Hebei Chuanghai Biotechnology Co,.LTD
Product
Dimethyl 2-(2-methoxyphenoxy)malonate 150726-89-9
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-22

150726-89-9, Dimethyl 2-(2-methoxyphenoxy)malonateRelated Search:

(Trifluoromethoxy)benzene Dimethyl sulfoxide Dimethyl sulfate Malonic acid ETHANE 4-Methoxybenzoic acid Dimethyl methylmalonate 4-Methoxybenzoyl chloride Dimethyl malonate N,N-Dimethylformamide Malononitrile p-Anisaldehyde Diethyl malonate Dimethyl carbonate Dimethyl fluoromalonate 4-Methoxybenzyl alcohol Dimethyl isobutylmalonate 2,2-DIMETHYL-MALONIC ACID DIMETHYL ESTER

  • Dimethyl-2-(2-methoxyphenoxy)malonate
  • (2-Methoxyphenoxy)-propanedioic Acid Dimethyl Ester
  • Dimethyl (o-Methoxyphenoxy)malonate
  • 2-(2-Methoxyphenoxy)malonic acid dimethyl ester
  • DIMETHYL (2-METHOXYPHENOXY)MALONATE
  • 2-methoxy-2-phenoxypropanedioic acid dimethyl ester
  • 1,3-diMethyl 2-(2-Methoxyphenoxy)propanedioate
  • 2-MethoxyphenoxyMalonate
  • Propanedioic acid, 2-(2-methoxyphenoxy)-, 1,3-dimethyl ester
  • TIANFUCHEM--150726-89-9--High purity Dimethyl 2-(2-methoxyphenoxy)malonate in stock
  • 150726-89-9
  • Aromatics Compounds
  • Aromatics