ChemicalBook > CAS DataBase List > Ethyl 4-bromophenylacetate

Ethyl 4-bromophenylacetate

Product Name: Ethyl 4-bromophenylacetate
CAS No.: 14062-25-0
Chemical Name: Ethyl 4-bromophenylacetate
Synonyms: ethyl 2-(4-broMophenyl)acetate;4-bromophenylacetic acid ethyl ester;4-broMoethyl acetate;ETHYL 4-BROMOPHENYLACETATE;ETHYL P-BROMOPHENYLACETATE;2-(4-bromophenyl)butanoate;Ethyl4-Bromophenylacetate>Ethyl 4-bromophenylacetate,99%;Ethyl 4-bromophenylacetate 99%;Ethyl 4-bromophenylacetate ,97%
CBNumber: CB5109173
Molecular Formula: C10H11BrO2
Formula Weight: 243.1
MOL File: 14062-25-0.mol

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Ethyl 4-bromophenylacetate Property

Melting point:: 29-33 °C(lit.)
Boiling point:: 88-90°C 0,35mm
Density: 1.389±0.06 g/cm3(Predicted)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
form: Liquid or Low Melting Solid
color: Clear colorless to pale yellow
InChI: InChI=1S/C10H11BrO2/c1-2-13-10(12)7-8-3-5-9(11)6-4-8/h3-6H,2,7H2,1H3
InChIKey: ZFDCWHPNBWPPHG-UHFFFAOYSA-N
SMILES: C1(CC(OCC)=O)=CC=C(Br)C=C1
CAS DataBase Reference: 14062-25-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 22
Safety Statements: 36
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 631353
Product name: Ethyl 4-bromophenylacetate
Purity: 97%
Packaging: 5g
Price: $34.05
Updated: 2025/07/31

Sigma-Aldrich

Product number: 631353
Product name: Ethyl 4-bromophenylacetate
Purity: 97%
Packaging: 25g
Price: $70.8
Updated: 2025/07/31

TCI Chemical

Product number: E0903
Product name: Ethyl 4-Bromophenylacetate
Purity: >98.0%(GC)
Packaging: 5g
Price: $23
Updated: 2025/07/31

TCI Chemical

Product number: E0903
Product name: Ethyl 4-Bromophenylacetate
Purity: >98.0%(GC)
Packaging: 25g
Price: $58
Updated: 2025/07/31

TRC

Product number: B680110
Product name: 4-Bromo-benzeneaceticAcidEthylEster
Packaging: 1g
Price: $50
Updated: 2021/12/16

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Ethyl 4-bromophenylacetate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

4-Bromo-benzeneacetic Acid Ethyl Ester is used to prepare highly selective and orally active Lysophosphatidic Acid (LPA) receptor-1 antagonists with potent activity on human lung fibroblasts.

Synthesis

64-17-5

1878-68-8

14062-25-0

Preparation of the intermediate 1-bromo-4-(2-methoxy-2-methyldienyl)benzene (1AG-1): 2-(4-bromophenyl)acetic acid (75 g, 340 mmol) was suspended in ethanol (341 mL). Concentrated sulfuric acid (0.682 mL, 12.79 mmol) was added slowly and the reaction mixture was subsequently heated to reflux and maintained for 24 hours. Upon completion of the reaction, the mixture was concentrated to remove the solvent. The residue was diluted with ether and saturated sodium bicarbonate solution for acid-base neutralization. The organic and aqueous layers were carefully separated and the organic layer was subsequently washed with brine and dried over sodium sulfate. The dried organic phase was filtered and the filtrate was concentrated to give ethyl 2-(4-bromophenyl)acetate (80.2 g, 97% yield) as an off-white solid.

References

[1] Patent: WO2010/86820, 2010, A1. Location in patent: Page/Page column 53
[2] Journal of Medicinal Chemistry, 2008, vol. 51, # 21, p. 6665 - 6681
[3] Patent: US2013/79320, 2013, A1. Location in patent: Paragraph 0473; 0474
[4] Patent: WO2013/45451, 2013, A1. Location in patent: Paragraph 51
[5] European Journal of Medicinal Chemistry, 2014, vol. 86, p. 714 - 723

Ethyl 4-bromophenylacetate Preparation Products And Raw materials

Raw materials

Ethanol 4-Bromophenylacetic acid Sulfuric acid

Preparation Products

ETHYL 4-ACETYLBENZOATE

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View Lastest Price from Ethyl 4-bromophenylacetate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Ethyl 4-bromophenylacetate 14062-25-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-11-04

Honest Joy Holdings Limited

Product: Ethyl 4-bromophenylacetate 14062-25-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.1%
Supply Ability: 100 tons
Release date: 2022-01-26

Career Henan Chemical Co

Product: Ethyl 4-bromophenylacetate 14062-25-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 150KG
Release date: 2019-07-09

14062-25-0, Ethyl 4-bromophenylacetateRelated Search:

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ETHYL P-BROMOPHENYLACETATE

ETHYL 4-BROMOPHENYLACETATE

4-bromophenylacetic acid ethyl ester

Ethyl 4-bromophenylacetate 99%

Ethyl 4-bromophenylacetate,99%

2-(4-bromophenyl)butanoate

Ethyl p-Bromophenylacetate Ethyl

Ethyl 4-bromophenylacetate ,97%

ethyl 2-(4-broMophenyl)acetate

1-Bromo-4-(2-ethoxy-2-oxoethyl)benzene

Ethyl 4-broMophenylacetate, 99% 5GR

4-broMoethyl acetate

Ethyl 2-(4-broMophenyl)acetate, 95+%

4-Bromophenylacetic acid ethyl ester, Ethyl 2-(4-bromophenyl)ethanoate

Ethyl4-Bromophenylacetate&gt

Benzeneacetic acid, 4-bromo-, ethyl ester

Ethyl 4-bromophenylacetate, 95% (Custo

14062-25-0

Esters

Building Blocks

C10 to C11

Carbonyl Compounds

Organic Building Blocks

Pyrimidines

Aromatic Esters

C10 to C11

Carbonyl Compounds

Esters

Acids and Derivatives