ChemicalBook > CAS DataBase List > 2,2,2-Trifluoroethyl trifluoromethanesulfonate
2,2,2-Trifluoroethyl trifluoromethanesulfonate
- Product Name
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate
- CAS No.
- 6226-25-1
- Chemical Name
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate
- Synonyms
- 2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULPHONATE;2,2,2-TRIFLUOROETHYL TRIFLATE;TFOL-TF;2,2,2-Trifluoroethyl Triflante;2,2,2-Trifluoroethyl trifluoromethanesulf;2-Trifluoroethyl trifluoromethanesulfonate;2,2,2-Trifluoroethytrifluoromethanesulfonate;2,2,2-Trifluoroethyl trifluoromethanesulfote;2,2,2-Trifluoroethyl trifluoroMethylsulfonate;2,2,2-TRIFLUOROETHYL TRIFLUOROMETHANESULFONATE
- CBNumber
- CB5142808
- Molecular Formula
- C3H2F6O3S
- Formula Weight
- 232.1
- MOL File
- 6226-25-1.mol
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2,2,2-Trifluoroethyl trifluoromethanesulfonate Property
- Boiling point:
- 89-91°C
- Density
- 1,61 g/cm3
- refractive index
- 1.3037
- RTECS
- PB2775000
- Flash point:
- >110°(230°F)
- storage temp.
- 2-8°C
- solubility
- Chloroform, Methanol (Slightly)
- form
- Liquid
- color
- Colorless to yellow
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Moisture Sensitive
- InChIKey
- RTMMSCJWQYWMNK-UHFFFAOYSA-N
- CAS DataBase Reference
- 6226-25-1(CAS DataBase Reference)
- EPA Substance Registry System
- Methanesulfonic acid, trifluoro-, 2,2,2-trifluoroethyl ester (6226-25-1)
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Safety
- Hazard Codes
- Xi,T,C
- Risk Statements
- 36/37/38-34-23/25
- Safety Statements
- 26-36/37/39-45
- RIDADR
- 3265
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- TOXIC, CORROSIVE
- HazardClass
- 8
- PackingGroup
- Ⅱ
- HS Code
- 29055900
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H314Causes severe skin burns and eye damage
H330Fatal if inhaled
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 752924
- Product name
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate
- Purity
- 95%
- Packaging
- 5g
- Price
- $135
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1604
- Product name
- 2,2,2-Trifluoroethyl Trifluoromethanesulfonate
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $142
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1604
- Product name
- 2,2,2-Trifluoroethyl Trifluoromethanesulfonate
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $354
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H61603
- Product name
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate, 95%
- Packaging
- 5g
- Price
- $128.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- H61603
- Product name
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate, 95%
- Packaging
- 25g
- Price
- $462.65
- Updated
- 2024/03/01
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2,2,2-Trifluoroethyl trifluoromethanesulfonate Chemical Properties,Usage,Production
Uses
A fluorine-containing alkyl alkanesulfonate with cyctotoxity towards cultured leukemia L1210 cells.
Uses
2,2,2-Trifluoroethyl trifluoromethanesulfonate is a powerful trifluoroethylating agent which is useful for synthesis of fluorinated amino acids. It is used as a reagent in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines.
Uses
Reagent used in thenantioselective preparation of cyclic N-aryl hydroxamic acids via phase-transfer catalyzed alkylation of nitrobenzyl bromides to give nirophenylalanines
Synthesis
In a 100-ml flask equipped with a stirrer, a thermometer, a nitrogen introducing pipe, and a condenser, 50 ml (0.297 mol) of trifluoromethane sulfonic anhydride and 25 ml (0.342 moles) of 2,2,2-trifluoroethanol were placed at room temperature and stirred for 30 minutes in a nitrogen atmosphere, followed by reflux for 3 hours. After distillation, 50.3 g of 2,2,2-trifluoroethyl trifluoromethanesulfonate was obtained in a yield of 73%.
2,2,2-Trifluoroethyl trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
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2,2,2-Trifluoroethyl trifluoromethanesulfonate Suppliers
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View Lastest Price from 2,2,2-Trifluoroethyl trifluoromethanesulfonate manufacturers
LY Global chemicals co.,ltd .
- Product
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate 6226-25-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000KG
- Release date
- 2023-03-09
Henan Aochuang Chemical Co.,Ltd.
- Product
- 2,2,2-Trifluoroethyl trifluoromethanesulfonate 6226-25-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 2,2,2-Trifluoroethyl Trifluoromethanesulfonate 6226-25-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
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