ChemicalBook > CAS DataBase List > Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt

Product Name
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
CAS No.
63995-70-0
Chemical Name
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
Synonyms
TPPTS;Sodium 3,3',3''-phosphanetriyltribenzenesulfonate;TRIS(3-SULFONATOPHENYL)PHOSPHINE HYDRATE SODIUM SALT;TRIS(3;TPPTS-Na;10% oxide);Triphenylphosphine-3,3;TRISODIUM TRIPHENYLPHOSPHINE-3 3' 3''-T&;TRI(M-SULFOPHENYL)PHOSPHINE, SODIUM SALT;TRIS(3-SULFONATOPHENYL) PHOSPHINE HYDRATE
CBNumber
CB5171996
Molecular Formula
C18H16NaO9PS3
Formula Weight
526.46
MOL File
63995-70-0.mol
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Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Property

Melting point:
>300°C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Slightly), Water (Slightly)
form 
Powder
color 
white to off-white
Water Solubility 
Soluble in water.
BRN 
3584807
Stability:
Hygroscopic
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
1
F 
10
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
744034
Product name
Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt
Purity
≥95.0%
Packaging
1g
Price
$211
Updated
2024/03/01
Sigma-Aldrich
Product number
744034
Product name
Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt
Purity
≥95.0%
Packaging
5g
Price
$1010
Updated
2024/03/01
TCI Chemical
Product number
T2187
Product name
Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt
Purity
>97.0%(HPLC)(T)
Packaging
1g
Price
$95
Updated
2024/03/01
TCI Chemical
Product number
T2187
Product name
Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt
Purity
>97.0%(HPLC)(T)
Packaging
5g
Price
$248
Updated
2024/03/01
Alfa Aesar
Product number
039538
Product name
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate
Purity
tech. 85%
Packaging
0.25g
Price
$120
Updated
2021/12/16
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Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Chemical Properties,Usage,Production

Chemical Properties

White to off-white solid

Uses

Tris(3-sulfophenyl)phosphine Trisodium Salt (Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt) is a reagent used in organic synthesis such as benzothiazole-based cycloplatinated chromophores.

Preparation

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) is synthesized by sulfonation of triphenylphosphine with oleum (i.e., concentrated H2SO4 and SO3). Various parameters (triphenylphosphine/oleum ratio,wt % of SO3, time, temperature, and agitation speed) have been studied and modified to suppress the formation of by-products such as phosphines with a low degree of sulfonation and phosphine oxides. One particularly attractive method employs orthoboric acid B(OH)3, concentrated H2SO4, and a controlled SO3 concentration and cleanly affords either disulfonated ligand (TPPDS) or TPPTS with negligible oxidation and no by-products.

Application

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) can be used as a capping agent in the synthesis of TPPTS stabilized palladium nanoparticles (PdNPs) using K2PdCl4 as the palladium source and HCOONa as the reductant. The TPPTS stabilized PdNPs are applicable as an efficient catalyst in the aqueous phase Suzuki-Miyaura coupling reaction at room temperature. TPPTS is also a ligand in the metal-catalyzed hydroformylation of functionalized olefins and direct arylation polymerization reactions.

storage

Solid Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt (TPPTS) is substantially stable to air, but bottles of TPPTS should be flushed with N2 or Ar and kept tightly closed for prolonged storage. TPPTS is slowly oxidized to the phosphine oxide in the solution. Therefore, oxygen-free solvents are preferred.

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Preparation Products And Raw materials

Raw materials

Preparation Products

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Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt Suppliers

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View Lastest Price from Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt manufacturers

Shanghai UCHEM Inc.
Product
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt 63995-70-0
Price
US $10.00-171.00/g
Min. Order
1g
Purity
0.90
Supply Ability
25kg
Release date
2024-04-12
Hebei Chuanghai Biotechnology Co,.LTD
Product
Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt 63995-70-0
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-20
Shaanxi Dideu Medichem Co. Ltd
Product
Triphenylphosphine-3,3',3''-trisulfonic Acid Trisodium Salt 63995-70-0
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2020-01-15

63995-70-0, Triphenylphosphine-3,3',3''-trisulfonic acid trisodium saltRelated Search:

Citric acid Hyaluronic acid Folic acid Triphenylphosphine Antirust agent T702 (+/-)-10-CAMPHORSULFONIC ACID SODIUM SALT 1-DODECANESULFONIC ACID SODIUM SALT Ethyl 2-(Chlorosulfonyl)acetate Sodium 1-octanesulfonate Sodium lignosulfonate Tris(triphenylphosphine)ruthenium(II) chloride Tris(hydroxymethyl)aminomethane acetate salt Triphenylphosphine oxide Triphenylphosphine hydrobromide Triphenylmethanol Tribenzylamine N-BOC-IMINO-(TRIPHENYL)PHOSPHORANE PROPARGYLTRIPHENYLPHOSPHONIUM BROMIDE

  • TRI(M-SULFOPHENYL)PHOSPHINE, SODIUM SALT
  • TRIS(3-SULFONATOPHENYL) PHOSPHINE HYDRATE
  • TRIS(3-SULFONATOPHENYL)PHOSPHINE HYDRATE SODIUM SALT
  • TRIS(3-SULFONATOPHENYL) PHOSPHINE HYDRATE, TRISODIUM SALT
  • TRIS(3-SULFONATOPHENYL)PHOSPHINE TETRAHYDRATE, SODIUM SALT
  • TRIS(3-SULFOPHENYL)PHOSPHINE TRISODIUM SALT
  • TRIPHENYLPHOSPHINE-3,3',3''-TRISULFONIC ACID TRISODIUM SALT
  • 3,3',3''-PHOSPHINIDYNETRIS(BENZENESULFONIC ACID) TRISODIUM SALT
  • trisodium 3,3',3''-phosphinetriyltris(benzene-1-sulphonate)
  • TRISODIUM TRIPHENYLPHOSPHINE-3 3' 3''-T&
  • Tris(3-sulfonatophenyl)phosphinehydrate,sodiumsalt(10-15%oxide)
  • Trinatrium-3,3′,3′′-phosphintriyltris(benzol-1-sulfonat), wssrige Lsung
  • Tris(3-sulfornatophenyl)-phosphine tetrahydrate, sodium salt
  • Tri(methyl-sulfophenyl)phosphine,sodium salt
  • 3,3',3"-Phosphinidynetrisbenzenesulfoic acid trisodium salt
  • Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate, 85+%
  • 3,3',3"-phosphinidynetris(benzenesulfonic acid), trisodium
  • Tris(3-sulfophenyl)phosphine trisodium salt, Triphenylphosphine-3,3μ,3μμ-trisulfonic acid trisodium salt, 3,3μ,3-Phosphinidynetris(benzenesulfonic acid) trisodium salt
  • Trisodium triphenylphosphine-3,3μ,3-trisulfonate
  • 3,3',3''-(Phosphinetriyl)tris(benzenesulfonic acid sodium) salt
  • 3,3',3''-(Phosphinidyne)tris(benzenesulfonic acid sodium) salt
  • 3,3',3''-Phosphinetriyltris(benzenesulfonic acid sodium) salt
  • 3,3',3''-Phosphinidynetris(benzenesulfonic acid sodium) salt
  • TPPTS
  • TPPTS-Na
  • Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate, tech. 85%
  • Tris(3-sulfonatophenyl)phosphine hydrate, sodium salt (<10% oxide)
  • Sodium 3,3',3''-phosphanetriyltribenzenesulfonate
  • TRIS(3
  • Tris(3-sulfophenyl)phosphine trisodium salt, 3,3μ,3-Phosphinidynetris(benzenesulfonic acid) trisodium salt
  • Tris(3-sulfonatophenyl)phosphine hydrate sodium salt ,95%
  • 3,3',3''-Phosphinidynetris(benzenesulfonicacid)trisodiumsalt(TPPTS)
  • Tris-(3-Sulfornatophenyl)-Phosphine4-Hydratesodiumsalt
  • Tris(3-sulfonatophenyl)phosphine hydrate, sodium salt ,5-8% oxide
  • Tris(3-sulfonatophenyl)phosphine hydrate, sodium salt (<5% oxide)
  • SodiuM 3,3',3''-phosphinetriyltribenzenesulfonate
  • Tris(3-sulfonatophenyl)phosphine sodium salt hydrate
  • Benzenesulfonic acid, 3,3',3''-phosphinidynetris-, trisodiuM salt
  • Benzenesulfonic acid, 3,3',3''-phosphinidynetris-, sodiuM salt (1:3)
  • Triphenylphosphine-3,3
  • Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt >=95.0%
  • Tris(3-sulfonatophenyl)phosphine tetrahydrate, sodium salt (10-15% oxide)
  • Triphenylphosphine-3,3,3-Trisulfonic Acid Trisodium Salt Hydrate
  • Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate, technical, 85%
  • trisodium 4-bis(4-sulfonatophenyl)phosphinobenzenesulfonate
  • Tris(3-sulfonatophenyl)phosphine hydrate, sodium salt (&lt
  • Tris(3-sulfophenyl)phosphine Trisodium (~85%)
  • 10% oxide)
  • Sodium salt of triphenylphosphine trimesulfonate
  • Tris(3-sulfonatophenyl)phosphine sodium hydrate
  • Trisodium 3,3',3''-Phosphinetriyltribenzenesulfonate
  • Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt, ≥95%
  • 3,3',3''-phosphinidynetris-Benzenesulfonic acid sodium salt (1:3)
  • Tris(3-sulfonatophenyl)phosphine hydrate, sodium salt (no oxide)
  • Triphenylphosphine sodium trimetasulfonate
  • Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt
  • Sodium 3,3',3''-phosphinetriyltribenzenesulfonate
  • Triphenylphosphine-3,3'',3''''-trisulfonic acid trisodium salt