Ethephon Property

Melting point:

70-72 °C(lit.)

Boiling point:

265°C(lit.)

Density 

1.2000

storage temp. 

2-8°C

Water Solubility 

Completely soluble in water

solubility 

DMF: 30 mg/ml,DMSO: 30 mg/ml,Ethanol: 25 mg/ml,PBS (pH 7.2): 10 mg/ml

pka

1.88±0.10(Predicted)

form 

Powder

color 

White to beige

Sensitive 

Hygroscopic

Merck 

14,3732

BRN 

1751208

Stability:

Hygroscopic

InChIKey

UDPGUMQDCGORJQ-UHFFFAOYSA-N

LogP

-0.220

CAS DataBase Reference

16672-87-0(CAS DataBase Reference)

NIST Chemistry Reference

Phosphonic acid, (2-chloroethyl)-(16672-87-0)

EPA Substance Registry System

Ethephon (16672-87-0)

Safety

Hazard Codes 

C

Risk Statements 

20/21-34-52/53

Safety Statements 

26-28-36/37/39-45-61-28A

RIDADR 

UN 2928 6.1/PG 2

WGK Germany 

2

RTECS 

SZ7100000

HazardClass 

6.1

PackingGroup 

II

HS Code 

29319090

Hazardous Substances Data

16672-87-0(Hazardous Substances Data)

Toxicity

LD50 orally in mice: 2850 mg/kg (Hennighausen)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Ethephon Chemical Properties,Usage,Production

Chemical Properties

white to beige powder

Chemical Properties

Ethephon is a white to tan powder. Commercial product is a white, waxy solid. Commercial products may be available as aqueous solutions or soluble concentrates.

Uses

2-Chloroethyl)phosphonic acid (Ethephon) is the most widely used plant growth regulator. Ethephon is often used on wheat, coffee, tobacco, cotton, and rice in order to help the plant's fruit reach mat urity more quickly. The toxicity of Ethephon is actually very low, and any Ethephon used on the plant is converted very quickly to ethylene.

Uses

Accelerates the preharvest ripening of fruits and vegetables.

Definition

ChEBI: A phosphonic acid compound having a 2-chloroethyl substituent attached to the P-atom.

Agricultural Uses

Plant growth regulator: Ethephon is a plant growth regulator used to promote fruit ripening, abscission, flower induction, and other responses. It is registered for use on a number of food, feed and nonfood crops (rubber plants, flax), greenhouse nursery stock, and outdoor residential ornamental plants, but is used primarily on cotton. Ethephon is applied to plant foliage by either ground or aerial equipment. It also may be applied by hand sprayer to certain home garden vegetables and ornamentals. Use practice limitations include prohibitions against applying ethephon through any type of irrigation system; feeding or grazing livestock in treated areas; and treating within 2 to 60 days of harvest, depending on the crop.

Trade name

AMCHEM® 68-250; ARVEST®; BASE® 250; BOLL’D®; BROMEFLOR®; BROMOFLOR®; CAMPOSAN®; CEPHA®; CEPHA® 10LS; CERONE®; CHIPCO® FLOREL PRO; ETHEPON®; ETHEL®; ETHEVERSE®; ETHREL®; FINISH®; FLORDIMEX®; FLOREL®; G-996®; KAMPOSAN®; PREP®; ROLLFRUCT®; TERPAL® (with mepiquat chloride); T-EXTRA®; TOMATHREL®

Safety Profile

Moderately toxic by ingestion. Mddly toxic by skin contact. A plant growth regulator. Caution: Spray formulations are quite acidic, about pH 1 .O. May be irritating to exposed skin and eyes, or if inhaled. When heated to decomposition it emits toxic fumes of Cl and POx.

Potential Exposure

Ethephon is an organophosphonate plant growth regulator used to promote fruit ripening, abscission, flower induction, and other responses. It is registered for use on a number of food, animal feed and nonfood crops (rubber plants, flax), greenhouse nursery stock, and outdoor residential ornamental plants, but is used primarily on cotton. Ethephon is applied to plant foliage by either ground or aerial equipment. It also may be applied by hand sprayer to certain home garden vegetables and ornamentals. Use practice limitations include prohibitions against applying ethephon through any type of irrigation system; feeding or grazing livestock in treated areas; and treating within 2 to 60 days of harvest, depending on the crop

Environmental Fate

Soil. Degrades rapidly in soil to phosphoric acid, ethylene and chloride ions (Hartley and Kidd, 1987) and naturally occurring substances (Humburg et al., 1989).
Chemical/Physical. In an aqueous solution at pH 3.5, ethepon begins to hydrolyze, releasing ethylene (Windholz et al., 1983).

Shipping

UN2928 Toxic solids, corrosive, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, 8-Corrosive material, Technical Name Required

Incompatibilities

Hygroscopic. Aqueous solutions are highly acidic. May cause corrosion if metals, especially when moisture is present. Contact with flammable material may cause fire and explosions. Contact with combustible or oxidizable materials may form heat-, shock-, and frictionsensitive explosive mixtures. Static electricity may also cause explosions. Keep away from all acids, especially dibasic organic acids, ammonium compounds, antimony sulfide, arsenic trioxide, metal sulfides, powdered metals, calcium aluminum hydride, cyanides, manganese dioxide, phosphorus, selenium, sulfur, thiocyanates, and zinc.

Waste Disposal

Destruction by alkali hydrolysis or incineration. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.