ChemicalBook > CAS DataBase List > 2-(4-BROMOPHENYL)PROPAN-2-OL

2-(4-BROMOPHENYL)PROPAN-2-OL

Product Name
2-(4-BROMOPHENYL)PROPAN-2-OL
CAS No.
2077-19-2
Chemical Name
2-(4-BROMOPHENYL)PROPAN-2-OL
Synonyms
p-Bromocumyl alcohol;2-(4-BroMophenyl)-2-propanol;2-(4-BROMOPHENYL)PROPAN-2-OL;4-Bromophenyldimethylcarbinol;2-(4-Bromophenyl)-2-propanol,98%;Benzenemethanol, 4-bromo-α,α-dimethyl-;4-Bromo-alpha,alpha-dimethylbenzyl Alcohol;p-Bromo-alpha,alpha-dimethylbenzyl alcohol
CBNumber
CB52467765
Molecular Formula
C9H11BrO
Formula Weight
215.09
MOL File
2077-19-2.mol
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2-(4-BROMOPHENYL)PROPAN-2-OL Property

Melting point:
45.6℃
Boiling point:
75-85℃ /0.1mm
Density 
1.356
refractive index 
1.5520
storage temp. 
Sealed in dry,Room Temperature
form 
Solid
pka
14.29±0.29(Predicted)
color 
White
Water Solubility 
Slightly soluble in water (1.4 g/L) (25°C)
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Safety

HS Code 
2905599890
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B5274
Product name
2-(4-Bromophenyl)-2-propanol
Purity
>98.0%(GC)
Packaging
1g
Price
$120
Updated
2025/07/31
TCI Chemical
Product number
B5274
Product name
2-(4-Bromophenyl)-2-propanol
Purity
>98.0%(GC)
Packaging
5g
Price
$359
Updated
2025/07/31
TRC
Product number
B698528
Product name
2-(4-Bromophenyl)-2-propanol
Packaging
100mg
Price
$65
Updated
2021/12/16
TRC
Product number
B698528
Product name
2-(4-Bromophenyl)-2-propanol
Packaging
250mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB143935
Product name
2-(4-Bromophenyl)propan-2-ol
Packaging
2g
Price
$225
Updated
2021/12/16
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2-(4-BROMOPHENYL)PROPAN-2-OL Chemical Properties,Usage,Production

Uses

It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. It is a medicine intermediate.

Synthesis

75-16-1

99-90-1

2077-19-2

1. 1-(4-Bromophenyl)ethanone (9.25 g, 46.5 mmol) was dissolved in tetrahydrofuran (200 mL). 2. The reaction system was cooled at -50 °C in a low temperature bath. 3. An ether solution of methylmagnesium bromide (3 M, 46.5 mL, 139 mmol) was added slowly and dropwise over 15 minutes. 4. After the dropwise addition, the reaction system was allowed to warm gradually to room temperature and stirring was continued for 20 hours. 5. Upon completion of the reaction, the reaction was quenched with saturated aqueous ammonium chloride solution. 6. The reaction mixture was extracted with ethyl acetate and the organic phases were combined. 7. The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to obtain the crude product as an oil. 8. The crude product was purified by silica gel column chromatography (eluent: 0-20% ethyl acetate/hexane gradient elution) to afford the target product 2-hydroxy-2-(4-bromophenyl)propane (9.1 g, 46.2 mmol, 91% yield). 9. The product was identified by mass spectrometry (MS). 9. The product was characterized by mass spectrometry (ESI): m/z 197.1 [M]? , 199.1 [M+2]?

References

[1] Journal of Medicinal Chemistry, 1995, vol. 38, # 17, p. 3368 - 3383
[2] Patent: WO2010/62571, 2010, A1. Location in patent: Page/Page column 92
[3] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 15, p. 2169 - 2174
[4] Journal of the American Chemical Society, 1971, vol. 93, p. 6877 - 6887
[5] Journal of the American Chemical Society, 1999, vol. 121, # 14, p. 3557 - 3558

2-(4-BROMOPHENYL)PROPAN-2-OL Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(4-BROMOPHENYL)PROPAN-2-OL Suppliers

Americas 1 China 104 Europe 1 India 5 Japan 1 Switzerland 1 United Kingdom 3 United States 6 Global 122
Achemica
Tel
--
Fax
--
Email
contact@achemica.com
Country
Switzerland
ProdList
6155
Advantage
50
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View Lastest Price from 2-(4-BROMOPHENYL)PROPAN-2-OL manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-(4-BROMOPHENYL)PROPAN-2-OL 2077-19-2
Price
US $101.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-28
Career Henan Chemical Co
Product
2-(4-BROMOPHENYL)PROPAN-2-OL 2077-19-2
Price
US $2.00/KG
Min. Order
1g
Purity
98%MIN
Supply Ability
ASK
Release date
2020-01-07

2077-19-2, 2-(4-BROMOPHENYL)PROPAN-2-OLRelated Search:

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  • 2-(4-BROMOPHENYL)PROPAN-2-OL
  • 4-Bromophenyldimethylcarbinol
  • p-Bromo-alpha,alpha-dimethylbenzyl alcohol
  • p-Bromocumyl alcohol
  • 2-(4-BroMophenyl)-2-propanol
  • Benzenemethanol, 4-bromo-α,α-dimethyl-
  • 2-(4-Bromophenyl)-2-propanol,98%
  • 4-Bromo-alpha,alpha-dimethylbenzyl Alcohol
  • 2077-19-2