ChemicalBook > CAS DataBase List > METHYL 4-IODO-3-NITROBENZOATE

METHYL 4-IODO-3-NITROBENZOATE

Product Name: METHYL 4-IODO-3-NITROBENZOATE
CAS No.: 89976-27-2
Chemical Name: METHYL 4-IODO-3-NITROBENZOATE
Synonyms: METHYL 4-IODO-3-NITROBENZOATE;4-iodo-3-nitrobenzoic acid methyl ester;Benzoic acid, 4-iodo-3-nitro-, methyl ester;Methyl-4-iodo-3-nitrobenzoate SynonyMs 4-Iodo-3-Nitrobenzoic Acid Methyl Ester
CBNumber: CB5256646
Molecular Formula: C8H6INO4
Formula Weight: 307.04
MOL File: 89976-27-2.mol

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METHYL 4-IODO-3-NITROBENZOATE Property

Melting point:: 103-105°C
Boiling point:: 360.1±32.0 °C(Predicted)
Density: 1.904±0.06 g/cm3(Predicted)
storage temp.: 2-8°C(protect from light)
Appearance: Yellow to brown Solid
Water Solubility: Soluble in DCM 10mg/0.5mL. Insoluble in water.
Sensitive: Light Sensitive

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Safety

Risk Statements: 20/21/22-36/37/38
Safety Statements: 26-37/39
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: M321628
Product name: Methyl4-Iodo-3-nitrobenzoate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M321628
Product name: Methyl4-Iodo-3-nitrobenzoate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

AK Scientific

Product number: J96288
Product name: Methyl4-iodo-3-nitrobenzoate
Packaging: 250mg
Price: $10
Updated: 2021/12/16

AK Scientific

Product number: Z5306
Product name: Methyl4-iodo-3-nitrobenzoate
Packaging: 1g
Price: $26
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-H-12
Product name: Methyl 4-iodo-3-nitrobenzoate
Packaging: 25g
Price: $408
Updated: 2021/12/16

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METHYL 4-IODO-3-NITROBENZOATE Chemical Properties,Usage,Production

Uses

Methyl 4-iodo-3-nitrobenzoate is used as pharmaceutical intermediate.

Synthesis

67-56-1

35674-27-2

89976-27-2

Example 1: General procedure for the preparation of methyl 4-iodo-3-nitrobenzoate using methanol/sulfuric acid 1. dissolve 4-iodo-3-nitrobenzoic acid (3 g, 10 mmol) in methanol (30 ml) and cool the solution to 0°C. 2. sulfuric acid (3.4 g, 34.6 mmol) was added slowly to the above cooled solution. 3. the reaction mixture was gradually warmed to room temperature and subsequently heated to reflux (about 70 °C) and maintained for 8 hours. 4. Upon completion of the reaction, the reaction mixture was cooled and neutralized to pH neutral with solid NaHCO3 and filtered to remove the resulting salt. 5. The filtrate was concentrated under pressure to give a crude product. 6. Water (30 ml) was added to the crude product and extracted with methyl tertiary butyl ether (MTBE, 30 ml x 2). 7. The organic phases were combined, washed with saturated brine, dried over anhydrous sodium sulfate and filtered. 8. The solvent was evaporated under pressure to give methyl 4-iodo-3-nitrobenzoate as a yellow solid (2.67 g, 85% yield, 98% HPLC purity).

References

[1] Dalton Transactions, 2015, vol. 44, # 5, p. 2047 - 2051
[2] Chemical Communications, 2017, vol. 53, # 55, p. 7808 - 7811
[3] Patent: US2013/172618, 2013, A1. Location in patent: Paragraph 0025
[4] Patent: WO2017/48954, 2017, A1. Location in patent: Paragraph 00095
[5] Patent: WO2005/40157, 2005, A2. Location in patent: Page/Page column 68

METHYL 4-IODO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 4-IODO-3-NITROBENZOATE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: METHYL 4-IODO-3-NITROBENZOATE 89976-27-2
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-06-05

89976-27-2, METHYL 4-IODO-3-NITROBENZOATERelated Search:

4-Iodo-3-nitrobenzoic acid 4-iodo-2-Methyl-benzoic acid Methyl ester Methyl 3-nitrobenzoate METHYL 2-IODO-3-NITROBENZOATE 4-IODO-3-NITRO-BENZOIC ACID ETHYL ESTER 4-IODO-3-NITROTOLUENE METHYL 3-AMINO-4-IODOBENZOATE METHYL 4-IODO-3-NITROBENZOATE

METHYL 4-IODO-3-NITROBENZOATE

Methyl-4-iodo-3-nitrobenzoate SynonyMs 4-Iodo-3-Nitrobenzoic Acid Methyl Ester

4-iodo-3-nitrobenzoic acid methyl ester

Benzoic acid, 4-iodo-3-nitro-, methyl ester

89976-27-2