ChemicalBook > CAS DataBase List > N-Phenyl-bis(trifluoromethanesulfonimide)

N-Phenyl-bis(trifluoromethanesulfonimide)

Product Name
N-Phenyl-bis(trifluoromethanesulfonimide)
CAS No.
37595-74-7
Chemical Name
N-Phenyl-bis(trifluoromethanesulfonimide)
Synonyms
PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
CBNumber
CB5289550
Molecular Formula
C8H5F6NO4S2
Formula Weight
357.25
MOL File
37595-74-7.mol
More
Less

N-Phenyl-bis(trifluoromethanesulfonimide) Property

Melting point:
100-102 °C(lit.)
Boiling point:
305.3±52.0 °C(Predicted)
Density 
1.766±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.
form 
Crystals or Crystalline Powder
pka
-13.12±0.50(Predicted)
color 
White or colorless
Sensitive 
Moisture Sensitive
BRN 
1269141
Stability:
Moisture Sensitive
InChI
InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
InChIKey
DIOHEXPTUTVCNX-UHFFFAOYSA-N
SMILES
C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O
CAS DataBase Reference
37595-74-7(CAS DataBase Reference)
NIST Chemistry Reference
N-phenyltrifluoromethanesulfonimide(37595-74-7)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
F 
21
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29242100
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
295973
Product name
N-Phenyl-bis(trifluoromethanesulfonimide)
Purity
99%
Packaging
5g
Price
$82.1
Updated
2024/03/01
Sigma-Aldrich
Product number
295973
Product name
N-Phenyl-bis(trifluoromethanesulfonimide)
Purity
99%
Packaging
25g
Price
$201
Updated
2024/03/01
TCI Chemical
Product number
P1257
Product name
N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
Purity
>98.0%(GC)
Packaging
5g
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
P1257
Product name
N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
Purity
>98.0%(GC)
Packaging
25g
Price
$80
Updated
2024/03/01
Alfa Aesar
Product number
L12531
Product name
N-Phenylbis(trifluoromethanesulfonimide), 99%
Packaging
5g
Price
$72.1
Updated
2024/03/01
More
Less

N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Usage,Production

Description

N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. 

Chemical Properties

white to off-white crystalline powder

Uses

N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.

Uses

Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes

Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation

Synthesis

Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).

N-Phenyl-bis(trifluoromethanesulfonimide) Preparation Products And Raw materials

Raw materials

Sodium hydride Ethanol Sodium chloride Trifluoromethanesulfonyl chloride Potassium carbonate Trifluoromethanesulfonic anhydride Triethylamine Tetrahydrofuran Aniline Dichloromethane Sodium hydroxide Magnesium sulfate

Preparation Products

More
Less

N-Phenyl-bis(trifluoromethanesulfonimide) Suppliers

Americas 1 Belgium 3 Canada 1 China 406 Europe 2 France 3 Germany 5 India 28 Italy 1 Japan 6 Switzerland 2 United Kingdom 12 United States 42 Global 512
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
Accela ChemBio Inc.
Tel
+1(858) 699-3322
Fax
+1(858) 876-1948
Email
marketing@accelachem.com
Country
United States
ProdList
6024
Advantage
65
Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Accela ChemBio Inc.
Tel
+1-858-6993322
Fax
(+1)-858-876-1948
Email
info@accelachem.com
Country
United States
ProdList
17777
Advantage
58
Alchem Pharmtech,Inc.
Tel
8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Aceschem Inc.
Tel
+1-817863-6948 +1-（817）863-6948
Email
sales@aceschem.com
Country
United States
ProdList
19632
Advantage
58
United States Biological
Tel
--
Fax
--
Email
sales@advtechind.com
Country
United States
ProdList
6075
Advantage
58
Abblis Chemicals LLC
Tel
--
Fax
--
Email
info@abblis.com
Country
United States
ProdList
1272
Advantage
0
SynQuest Laboratories, Inc. (Part of Central Glass Co., Ltd.)
Tel
--
Fax
--
Email
nfo@synquestlabs.com
Country
United States
ProdList
1897
Advantage
58
Fluorochem Ltd.
Tel
--
Fax
--
Email
enquiries@fluorochem.co.uk
Country
United States
ProdList
4583
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Crescent Chemical Company
Tel
--
Fax
--
Email
fran@creschem.com
Country
United States
ProdList
1441
Advantage
58
Redox Scientific
Tel
--
Fax
--
Email
info@redoxsci.com
Country
United States
ProdList
2380
Advantage
58
Aceschem Inc.
Tel
--
Fax
--
Email
sales@aceschem.com
Country
United States
ProdList
3
Advantage
58
OChem Incorporation
Tel
--
Fax
--
Email
sales@ocheminc.com
Country
United States
ProdList
6501
Advantage
60
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
TCI America, Inc. (part of Tokyo Chemical Industry)
Tel
--
Fax
--
Email
Angelina.Crew@tcichemicals.com
Country
United States
ProdList
2053
Advantage
58
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Anvia Chemicals, LLC
Tel
--
Fax
--
Email
sales@anviachem.com
Country
United States
ProdList
3933
Advantage
0
Angene International Limited
Tel
--
Fax
--
Email
sales@angenechemical.com
Country
United States
ProdList
100
Advantage
50
Wilshire Chemical Company Inc.
Tel
--
Fax
--
Email
WilshrChem@AOL.COM
Country
United States
ProdList
3498
Advantage
58
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
Carbocore, Inc.
Tel
--
Fax
--
Email
sales@carbocore.com
Country
United States
ProdList
1436
Advantage
60
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Chem-Impex International, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6730
Advantage
64
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Ryan Scientific, Inc.
Tel
--
Fax
--
Email
ryan.reichlyn@ryansci.com
Country
United States
ProdList
6439
Advantage
60
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
American Custom Chemicals Corporation
Tel
--
Fax
--
Email
sales@acccorporation.com
Country
United States
ProdList
6820
Advantage
51
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
ASDI Incorporated
Tel
--
Fax
--
Email
customerservice@asdi.net
Country
United States
ProdList
6922
Advantage
67
Digital Specialty Chemicals, Inc.
Tel
--
Fax
--
Email
sales@digitalchem.com
Country
United States
ProdList
710
Advantage
85
More
Less

View Lastest Price from N-Phenyl-bis(trifluoromethanesulfonimide) manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-11-18
WUHAN FORTUNA CHEMICAL CO., LTD
Product
N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
98%min GC
Supply Ability
500 KGS
Release date
2021-06-10
Hebei Weibang Biotechnology Co., Ltd
Product
N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-25

37595-74-7, N-Phenyl-bis(trifluoromethanesulfonimide)Related Search:

Triphenylmethyl Chloride O-Phthalimide Lithium bis(trifluoromethanesulphonyl)imide Aniline Succinimide Bismaleimide Trifluoromethanesulfonyl chloride Trifluoromethanesulfonimide Dimethyl sulfone N-Phenylmethanesulfonamide N-PHENYLETHYLENEDIAMINE N-phenyl-1,3,5-triazin-2-amine N-Iodosuccinimide N-Carbobenzyloxy-D-asparagine N-Fluorobenzenesulfonimide (3-Nitrobenzyl)methylamine N-Phenylmaleimide N-PHENYLMETHACRYLAMIDE

  • phenyltrifluoromethanesulfonimide
  • N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE)
  • N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE)
  • N-PHENYLTRIFLUOROMETHANESULFONIMIDE
  • N-PHENYLTRIFLUOROMETHANESULPHONIMIDE
  • N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE
  • 1,1,1-TRIFLUORO-N-PHENYL-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE
  • N-Phenylbis(trifluoromethanesulphonimide), Phenyl triflimide
  • NSC 240874
  • N-Phenyl bis trifluorosulphonamide
  • N-Bis(trifluoromethylsulfonyl)aniline
  • 1,1,1-trifluoro-N-(methylsulfonyl)methanesulfonamide
  • N- phenyl-bis (trifluoromethanesulfonyl) imide
  • N-Phenylbis(trifluoroMethanesulfoniMide), 97% 5GR
  • N,N-Bis(trifluoromethylsulfonyl)aniline Phenyl Triflimide N-Phenyltrifluoromethanesulfonimide
  • N,N-Bis(trifluoroMethylsufonyl)aniline
  • N,N-Bis(trifluoroMethylsulfonyl)aniline SynonyMs N-Phenylbis(trifluoroMethanesulfon)iMide
  • N-phenyldouble(threefluoro Methanesulfonic acidiMide
  • N-Phenyl-bis(trifluoroMethanesulfoniMide) >=98.0% (HPLC)
  • 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
  • N-phenyl bis(trifluoromethanesulfonyl)amide
  • N-PHENYLT
  • N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
  • N,N-Bis(trifluoromethylsulfonyl)aniline 37595-74-7
  • PHENYL TRIFLIMIDE
  • N,N-Bis(trifluoromethanesulphonyl)aniline~Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
  • Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
  • N-PHENYL-BIS-(TRIFLUORMETHANSULFONIMID)
  • N,N-BIS-(TRIFLUOROMETHANESULFONYL)ANILINE
  • 1,1,1-Trifluoro-N-phenyl-N-(trifluoromethyl)sulphonylmethanesulphonamide
  • n-phenylbis(trifluorometanesulfonimide)
  • N-Phenyl-bis(trifluoromethyl)sulfonimide
  • N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
  • N-phenyl-bis(trifluoromethanesulfonamide)
  • N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Phenyl triflimide, 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
  • N-Phenyltrifluoromethanesulfonimide ,98%
  • N-Phenyl-bis(trifluoromethanesulfonimide),1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Pheny
  • N,N-Bis(trifluoromethylsulphonyl)aniline 98%
  • N-Phenylbis(trifluoromethanesulfonyl)amine
  • N-Phenylbis(trifluoromethylsulfonyl)amine
  • N-Phenyl-N,N-bis(trifluoromethylsulfonyl)amine
  • N-Phenylbis(trifluoromethanesulphonimide)97%
  • N-Phenylbis(trifluoromethanesulfonimide),97%
  • N-Phenylbis(trifluromethanesulphonimide)99%
  • trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide
  • -bis(trifL
  • fonimide)
  • N-Phenylbis(trifluoromethanesulfonimide)[TriflatingReagent]&gt
  • Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]-
  • 1,1,1-trifluoro-N-phenyl-N
  • TIANFUCHEM--37595-74-7--N-Phenyl-bis(trifluoromethanesulfonimide) factory price
  • Bis(trifluoromethylsulfonyl)aniline
  • N- phenylbis (trifluoromethanesulfonyl) imine
  • N-PHENYL-BIS(TRIFLUROMETHANSULPHONIMIDE)
  • N-phenylbis (trifluoromesulfonimide)
  • N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide
  • 37595-74-7
  • 7595-74-7