2-(Trifluoromethoxy)bromobenzene
- Product Name
- 2-(Trifluoromethoxy)bromobenzene
- CAS No.
- 64115-88-4
- Chemical Name
- 2-(Trifluoromethoxy)bromobenzene
- Synonyms
- 1-Bromo-2-(trifL;light yellow liquid,bp185;2-(TRIFLUOROMETHOXY)BENZENE;O-TRIFLUOROMETHOXYBROMOBENZENE;2-(Trifluoromethoxy)bromobenze;2-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(TRIFLUOROMETHOXY)BROMOBENZENE;O-BROMO(TRIFLUOROMETHOXY)BENZENE;2-(trifluoromrthoxy)bromobenzene;2-Bromo-6-(trifluoromethyl)anisole
- CBNumber
- CB5299205
- Molecular Formula
- C7H4BrF3O
- Formula Weight
- 241.01
- MOL File
- 64115-88-4.mol
2-(Trifluoromethoxy)bromobenzene Property
- Boiling point:
- 158-160 °C(lit.)
- Density
- 1.62 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.464(lit.)
- Flash point:
- 140 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- clear liquid
- color
- Colorless to Light yellow
- BRN
- 1947768
- CAS DataBase Reference
- 64115-88-4(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-37
- RIDADR
- UN1993
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29093090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 553891
- Product name
- 1-Bromo-2-(trifluoromethoxy)benzene
- Purity
- 97%
- Packaging
- 5g
- Price
- $41.6
- Updated
- 2022/05/15
- Product number
- T2147
- Product name
- 1-Bromo-2-(trifluoromethoxy)benzene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $18
- Updated
- 2025/07/31
- Product number
- T2147
- Product name
- 1-Bromo-2-(trifluoromethoxy)benzene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $33
- Updated
- 2025/07/31
- Product number
- B695168
- Product name
- 1-Bromo-2-(trifluoromethoxy)benzene
- Packaging
- 5g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 001378
- Product name
- 1-Bromo-2-(trifluoromethoxy)benzene
- Purity
- 99%
- Packaging
- 100g
- Price
- $83
- Updated
- 2021/12/16
2-(Trifluoromethoxy)bromobenzene Chemical Properties,Usage,Production
General Description
1-Bromo-2-(trifluoromethoxy)benzene can be prepared from (trifluoromethoxy)benzene.
Synthesis
1035797-66-0
88284-48-4
64115-88-4
In a glove box, KF (78.4 mg, 1.35 mmol, 4.5 eq.) was added to a 20 mL polyethylene (PE) plastic tube. Subsequently, dicyclohexane-18-crown-6 (503 mg, 1.35 mmol, 4.5 eq.) and 6. Next, ethylidene precursor (0.3 mmol, 1.0 eq.), 1-bromophenylacetylene (218 mg, 1.2 mmol, 4.0 eq.) or perfluorohexyl bromide (479 mg, 1.2 mmol, 4.0 eq.) or pentafluorophenyl bromide ( 296 mg, 1.2 mmol, 4.0 equiv) and trifluoromethyl benzoate (171 mg, 0.9 mmol, 3.0 equiv). The reaction tube was sealed and the reaction was carried out at room temperature for 12 hours. At the end of the reaction, the F-spectral yield was first determined by 19F NMR. Finally, the reaction mixture was filtered, dried and purified directly by column chromatography.
References
[1] Patent: CN108516935, 2018, A. Location in patent: Paragraph 0166; 0167; 0168; 0169; 0170; 0171
[2] Journal of the American Chemical Society, 2018, vol. 140, # 22, p. 6801 - 6805
2-(Trifluoromethoxy)bromobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(Trifluoromethoxy)bromobenzene manufacturers
- Product
- 2-(Trifluoromethoxy)bromobenzene 64115-88-4
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.0% min
- Supply Ability
- 100 tons min
- Release date
- 2025-05-26
- Product
- 2-(Trifluoromethoxy)bromobenzene 64115-88-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 10mg
- Purity
- 99%
- Supply Ability
- 2000tons
- Release date
- 2020-01-16
- Product
- 2-(Trifluoromethoxy)bromobenzene 64115-88-4
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-25