ChemicalBook > CAS DataBase List > 3-Methylbenzoyl chloride

3-Methylbenzoyl chloride

Product Name
3-Methylbenzoyl chloride
CAS No.
1711-06-4
Chemical Name
3-Methylbenzoyl chloride
Synonyms
m-ToL;toluoylchloride;Toluoyl chloride;3-ToluylChloride;3-toluoylchloride;M-TOLUYL CHLORIDE;3-Toluoyl chloride;M-TOLUOYL CHLORIDE;meta-toluoyl chloride;m-Toluoyl chloride,99%
CBNumber
CB5344365
Molecular Formula
C8H7ClO
Formula Weight
154.59
MOL File
1711-06-4.mol
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3-Methylbenzoyl chloride Property

Melting point:
-23°C
Boiling point:
86 °C/5 mmHg (lit.)
Density 
1.173 g/mL at 25 °C (lit.)
refractive index 
1.5475-1.5495
Flash point:
76 °C
storage temp. 
Inert atmosphere,2-8°C
form 
Liquid
Specific Gravity
1.17
color 
Clear colorless to light brown
Water Solubility 
Reacts with water.
Sensitive 
Moisture Sensitive
BRN 
878419
InChIKey
YHOYYHYBFSYOSQ-UHFFFAOYSA-N
CAS DataBase Reference
1711-06-4(CAS DataBase Reference)
NIST Chemistry Reference
Benzoyl chloride, 3-methyl-(1711-06-4)
EPA Substance Registry System
Benzoyl chloride, 3-methyl- (1711-06-4)
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Safety

Hazard Codes 
C
Risk Statements 
34-36/37
Safety Statements 
24/25-45-36/37/39-27-26-23
RIDADR 
3265
WGK Germany 
1
RTECS 
DM6644000
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
122254
Product name
m-Toluoyl chloride
Purity
99%
Packaging
5g
Price
$37.3
Updated
2025/07/31
Sigma-Aldrich
Product number
122254
Product name
m-Toluoyl chloride
Purity
99%
Packaging
100g
Price
$86.1
Updated
2025/07/31
TCI Chemical
Product number
T0309
Product name
m-Toluoyl Chloride
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$39
Updated
2025/07/31
TCI Chemical
Product number
T0309
Product name
m-Toluoyl Chloride
Purity
>98.0%(GC)(T)
Packaging
500g
Price
$210
Updated
2023/06/20
Usbiological
Product number
454092
Product name
m-Toluoyl Chloride
Packaging
1g
Price
$312
Updated
2021/12/16
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3-Methylbenzoyl chloride Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light brown liquid

Uses

m-Toluoyl chloride has been used to derivatize the C1-C4 aliphatic amines for their determination in air by HPLC. It has been used in determination of atmospheric ammonia by denuder-sampling and HPLC-UV detection.

General Description

m-Toluoyl chloride is an efficient derivatization reagent for amines.

Synthesis

99-04-7

1711-06-4

In a 1000 mL three-necked flask equipped with a thermometer, a mechanical stirrer, a reflux condenser tube and an off-gas absorption device, 540.56 g of m-methylbenzoic acid, 573.0 g of thionyl chloride and 1.0 g of N,N-dimethylformamide were added sequentially. The reaction mixture was heated to 90°C and the reaction was continuously stirred at this temperature for 3 hours. Upon completion of the reaction, the system was clear. The excess thionyl chloride was removed by distillation under reduced pressure, and 610.0 g of m-toluoyl chloride was finally obtained, which was determined to have a purity of 98.2% and a yield of 99.3%.

References

[1] Patent: CN107417518, 2017, A. Location in patent: Paragraph 0028
[2] Patent: CN105348085, 2016, A. Location in patent: Paragraph 0026; 0027; 0028; 0029; 0030
[3] Patent: CN107400052, 2017, A. Location in patent: Paragraph 0016
[4] Canadian Journal of Chemistry, 1963, vol. 41, p. 2962 - 2968
[5] Chemische Berichte, 1879, vol. 12, p. 2300

3-Methylbenzoyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

(1R,2R)-(-)-1,2-Diaminocyclohexane (1S,2S)-(+)-1,2-Diaminocyclohexane 3-Methylbenzophenone trans-1,4-Diaminocyclohexane cis-1,2-Diaminocyclohexane 3-METHYLHIPPURIC ACID
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View Lastest Price from 3-Methylbenzoyl chloride manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
3-Methylbenzoyl chloride 1711-06-4
Price
US $99.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-14
Hebei Chuanghai Biotechnology Co., Ltd
Product
3-Methylbenzoyl chloride 1711-06-4
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Hebei Yanxi Chemical Co., Ltd.
Product
3-Methylbenzoyl chloride 1711-06-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000kgs
Release date
2023-08-04

1711-06-4, 3-Methylbenzoyl chlorideRelated Search:

Choline chloride Benzoyl chloride Thionyl chloride Sodium chloride 2,4,6-Trimethylbenzoyl chloride Ammonium chloride 4-Cyanobenzoyl chloride Calcium chloride 2-(Trifluoromethyl)benzoyl chloride 3-(Trifluoromethyl)benzoyl chloride 4-Methoxybenzoyl chloride 4-Fluorobenzoyl chloride alpha,alpha,alpha-Trifluoro-o-toluoyl chloride Pivaloyl chloride 4-(Chloromethyl)benzoyl chloride Polyvinyl chloride 4-Chlorobenzoyl chloride Potassium chloride

  • 3-Methylbenzenecarbonyl chloride
  • 3-Methylbenzoic acid chloride
  • m-Methylbenzoic acid chloride
  • m-Toluoyl chloride,99%
  • M-Toluoyl chloride, 99% 5GR
  • 3-METHYLBENZOYL CHLORIDE FOR SYNTHESIS
  • Benzoyl chloride,3-Methyl-
  • <i>m</i>-Toluoyl chloride
  • m-Toluoyl chloride 99%
  • 3-METHYLBENZOYL CHLORIDE
  • 3-methyl-benzoylchlorid
  • 3-Toluoyl chloride
  • 3-toluoylchloride
  • meta Methyl benzoyl chloride
  • Toluoyl chloride
  • toluoylchloride
  • M-TOLUOYL CHLORIDE
  • M-TOLUYL CHLORIDE
  • M-METHYLBENZOYL CHLORIDE
  • m-ToL
  • meta-toluoyl chloride
  • 3-ToluylChloride
  • Benzoyl chloride, 3-methyl- (9CI)
  • m-Toluoyl chloride(m-Toluicchloride)
  • 3-METHYLBENZOYL CHLORIDE / M-TOLUOYL CHLORIDE
  • m-Toluoyl chloride, 98.5%
  • m-Toluoyl Chloride &gt
  • 3-Methylbenzoyl chloride ISO 9001：2015 REACH
  • m-Toluoyl Chloride, ≥ 98.0%
  • m-Toluoyl chloride, 10 mM in DMSO
  • 1711-06-4
  • 1711-06-04
  • 1711-06-0
  • Building Blocks
  • Carbonyl Compounds
  • Organic Building Blocks
  • Acid Halides
  • ACID CHLORIDE
  • Thiophenes
  • Acid HalidesDerivatization Reagents
  • Carbonyl Compounds
  • Derivatization Reagents HPLC
  • Organic Building Blocks
  • UV-VIS
  • ACIDHALIDE