Diethylene Glycol Monoethyl Ether

ChemicalBook > CAS DataBase List > Diethylene Glycol Monoethyl Ether

Diethylene Glycol Monoethyl Ether

Product Name: Diethylene Glycol Monoethyl Ether
CAS No.: 111-90-0
Chemical Name: Diethylene Glycol Monoethyl Ether
Synonyms: Transcutol;CARBITOL;2-(2-ETHOXYETHOXY)ETHANOL;Dowanol;ETHYL CARBITOL;ETHYL DIGLYCOL;Dowanol DE;ETHYL DIGOL;ETHOXYETHOXYETHANOL;ethyldiethyleneglycol
CBNumber: CB5376207
Molecular Formula: C6H14O3
Formula Weight: 134.17
MOL File: 111-90-0.mol

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Diethylene Glycol Monoethyl Ether Property

Melting point:: -80 °C
Boiling point:: 202 °C(lit.)
Density: 0.999 g/mL at 25 °C(lit.)
vapor density: 4.63 (vs air)
vapor pressure: 0.12 mm Hg ( 20 °C)
refractive index: n20/D 1.427(lit.)
Flash point:: 205 °F
storage temp.: Store below +30°C.
solubility: water: soluble
pka: 14.37±0.10(Predicted)
form: Liquid
color: Clear colorless
Odor: Weakly fruity; mild and characteristic.
biological source: synthetic
explosive limit: 1.8-12.2%(V)
Water Solubility: Miscible
Sensitive: Hygroscopic
Merck: 14,1800
BRN: 1736441
Stability:: Stable. Combustible. Note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides. Hygroscopic.
InChIKey: XXJWXESWEXIICW-UHFFFAOYSA-N
LogP: -0.54 at 20℃
CAS DataBase Reference: 111-90-0(CAS DataBase Reference)
NIST Chemistry Reference: Ethanol, 2-(2-ethoxyethoxy)-(111-90-0)
EPA Substance Registry System: Diethylene glycol monoethyl ether (111-90-0)

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Safety

Hazard Codes: Xn,Xi
Risk Statements: 36-20-36/37/38
Safety Statements: 23-24/25-39-26-36
WGK Germany: 1
RTECS: KK8750000
Autoignition Temperature: 204 °C
TSCA: Yes
HS Code: 29094400
Hazardous Substances Data: 111-90-0(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 8.69 g/kg (Smyth, Carpenter)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.03127
Product name: Diethylene glycol monoethyl ether
Purity: for synthesis
Packaging: 1L
Price: $38.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.03127
Product name: Diethylene glycol monoethyl ether
Purity: for synthesis
Packaging: 2.5L
Price: $64.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.03127
Product name: Diethylene glycol monoethyl ether
Purity: for synthesis
Packaging: 25L
Price: $382
Updated: 2024/03/01

Sigma-Aldrich

Product number: 537616
Product name: Diethylene glycol monoethyl ether
Purity: ReagentPlus , 99%
Packaging: 1l
Price: $76
Updated: 2024/03/01

Sigma-Aldrich

Product number: 537616
Product name: Diethylene glycol monoethyl ether
Purity: ReagentPlus , 99%
Packaging: 4l
Price: $256
Updated: 2024/03/01

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Diethylene Glycol Monoethyl Ether Chemical Properties,Usage,Production

Chemical Properties

Diethylene glycol monoethyl ether is a colorless, stable, hygroscopic liquid of a mild, pleasant odor. It is completely miscible with water, alcohols, ethers, ketones, aromatic and aliphatic hydrocarbons, and halogenated hydrocarbons. Owing to the fact that it contains an ether-alcohol-hydrocarbon group in the molecule, it has the power to dissolve a wide variety of substances such as oils, fats, waxes, dyes, camphor and natural resins like copal resin, kauri, mastic, rosin, sandarac, shellac, as well as several types of synthetic resins. It is used as a solvent in synthetic resin coating compositions, and in lacquers, where high-boiling solvents are desired.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Diethylene glycol monoethyl ether has low setting point and low viscocity at low temperature so it is used in manufacturing brake fluid. It is used as a flow and gloss promoter in paint industries, in production of printing ink and as a cleaner in offset printing. Also used in textile as a solvent for dyestuff in the printing and dying of fiber & fabrics, in the production & wood preservaties.

Uses

Di(ethylene glycol) ethyl ether is suitable for use as solvent for the polymer electrospinning.

Uses

Usually used as solvent for the polymer electrospinning.

Preparation

From ethyl alcohol plus ethylene oxide (Arctander, 1969).

Definition

ChEBI: A primary alcohol that is ethanol substituted by a 2-ethoxyethoxy group at position 2.

General Description

A colorless, slightly viscous liquid with a mild pleasant odor. Flash point near 190°F. Used to make soaps, dyes, and other chemicals.

Air & Water Reactions

Slightly denser than water and soluble in water. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164].

Reactivity Profile

Mixing 2(2-Ethoxyethoxy)ethanol in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid and oleum, NFPA 1991.

Health Hazard

None expected.

Fire Hazard

2(2-Ethoxyethoxy)ethanol is combustible.

Chemical Reactivity

Reactivity with Water : No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: V; Inhibitor of Polymerization: Not pertinent.

Safety Profile

irritation, and unspecified eye effects, cough,

Metabolism

The major part of an administered dose of diethylene glycol monoethyl ether is oxidized in the body or excreted as the glucuronate, administration to rabbits orally or by sc injection being followed by a marked increase in the urinary content of glucuronic acid (Fellows, Luduena & Hanzlik, 1947).

Purification Methods

Ethylene glycol can be removed by extracting 250g in 750mL of *benzene with 5mL portions of water, allowing for phase separation, until successive aqueous portions show the same volume increase. Dry, and free from peroxides, as described for diethylene glycol mono-n-butyl ether. [Beilstein 1 IV 2393.]

Toxics Screening Level

The initial threshold screening level (ITSL) for diethylene glycol monoethyl ether (DGEE) is 1750 μg/m3 based on an annual averaging time.

Diethylene Glycol Monoethyl Ether Preparation Products And Raw materials

Raw materials

Diethylene glycol Ethanol ETHYLENE OXIDE Diethyl sulfate

Preparation Products

Diethylene glycol diethyl ether 7-METHOXY-3(2H)-BENZOFURANONE methyl 2-(7-hydroxybenzofuran-3-yl)acetate Car brake fluid

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View Lastest Price from Diethylene Glycol Monoethyl Ether manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 1-hydroxy-3,6-dioxaoctane 111-90-0
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-17

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Diethylene Glycol Monoethyl Ether 111-90-0
Price: US $120.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-09

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Diethylene Glycol Monoethyl Ether 111-90-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-11

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Diethylene glycol monoethyl ether,2-(2-Ethoxyethoxy)ethanol, CARBITOL, Diethylene glycol ethyl ether, Ethyldiglycol

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2(2-Ethoxyethoxy)ethanol, 98+%, pure

2(2-Ethoxyethoxy)ethanol, 98+% 1LT

DE Solvent

ETHOXY DIGLYCOL

ETHOXYETHOXYETHANOL

ETHYL CARBITOL

ETHYL DIGOL

ETHYL DIGLYCOL

DIETHYLENE GLYCOL MONOETHYL ETHER

DI(ETHYLENE GLYCOL)ETHYL ETHER

DIGLYCOL MONOETHYL ETHER

CARBITOL(R)

CARBITOL SOLUTION

CARBITOL(TM)

Carbit0l

CARBITOL

2-(2-ETHOXYETHOXY)ETHANOL

DECS