4-Bromo-1,2-(methylenedioxy)benzene

Product Name: 4-Bromo-1,2-(methylenedioxy)benzene
CAS No.: 2635-13-4
Chemical Name: 4-Bromo-1,2-(methylenedioxy)benzene
Synonyms: 5-bromobenzo[d][1,3]dioxole;5-BROMO-1,3-BENZODIOXOLE;1,2-METHYLENEDIOXY-4-BROMOBENZENE;1-BROMO-3,4-(METHYLENEDIOXY)BENZENE;enedioxy)benzene;BROMOBENZODIOXOLE;TIMTEC-BB SBB006662;4-Bromo-1,2-(methyL;4-Bromo pepper ring;Paroxetine Impurity 89
CBNumber: CB5398696
Molecular Formula: C7H5BrO2
Formula Weight: 201.02
MOL File: 2635-13-4.mol

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4-Bromo-1,2-(methylenedioxy)benzene Property

Boiling point:: 85-86 °C1 mm Hg(lit.)
Density: 1.669 g/mL at 25 °C(lit.)
refractive index: n20/D 1.583(lit.)
Flash point:: >230 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform, Methanol (Sparingly)
form: Liquid
Specific Gravity: 1.669
color: Clear yellow-orange
BRN: 127407
Stability:: Light Sensitive
InChI: InChI=1S/C7H5BrO2/c8-5-1-2-6-7(3-5)10-4-9-6/h1-3H,4H2
InChIKey: FBOYMIDCHINJKC-UHFFFAOYSA-N
SMILES: O1C2=CC=C(Br)C=C2OC1
CAS DataBase Reference: 2635-13-4(CAS DataBase Reference)
NIST Chemistry Reference: 4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 288314
Product name: 1-Bromo-3,4-(methylenedioxy)benzene
Purity: 97%
Packaging: 100g
Price: $67.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 288314
Product name: 1-Bromo-3,4-(methylenedioxy)benzene
Purity: 97%
Packaging: 25g
Price: $111
Updated: 2024/03/01

TCI Chemical

Product number: B1230
Product name: 4-Bromo-1,2-methylenedioxybenzene
Purity: >98.0%(GC)
Packaging: 5g
Price: $36
Updated: 2024/03/01

TCI Chemical

Product number: B1230
Product name: 4-Bromo-1,2-methylenedioxybenzene
Purity: >98.0%(GC)
Packaging: 25g
Price: $94
Updated: 2024/03/01

Alfa Aesar

Product number: A17906
Product name: 4-Bromo-1,2-(methylenedioxy)benzene, 98%
Packaging: 5g
Price: $29.65
Updated: 2024/03/01

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4-Bromo-1,2-(methylenedioxy)benzene Chemical Properties,Usage,Production

Chemical Properties

clear yellow-orange liquid

Synthesis Reference(s)

Tetrahedron, 64, p. 4999, 2008 DOI: 10.1016/j.tet.2008.03.085

General Description

The coupling of 1-bromo-3,4-(methylenedioxy)benzene with β-methallyl alcohol was catalyzed by Pd(OAc)₂ in combination with P(t-Bu)₃.

Synthesis

NBS (1.87 g, 10.50 mmol, 1.05 equiv.), HPLC-grade acetonitrile and benzo[d][1,3]dioxole (10 mmol) were placed into a flask and stirred until completely homogeneous. The solution was pumped through the Corning G1 photoreactor at the desired flow rate. The reaction mixture was collected from the reactor and combined with the two separate streams of toluene and water into a 10-mL Vapourtec static mixer coil; then, the mixture was pumped into a Zaiput liquid-liquid membrane separator, the organic phase was collected and passed twice more through the Zaiput membrane separator. The organic phase was evaporated under reduced pressure, providing the corresponding brominated product 4-Bromo-1,2-(methylenedioxy)benzene.

4-Bromo-1,2-(methylenedioxy)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

3,4-METHYLENEDIOXYPHENYLBORONIC ACID

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4-Bromo-1,2-(methylenedioxy)benzene Suppliers

Americas 1 Belgium 2 Canada 1 China 240 Europe 4 Germany 7 India 16 Japan 3 Poland 1 Slovakia 1 Switzerland 3 The Netherlands 1 United Kingdom 14 United States 47 Global 341

Shijiazhuang Benchu Technology Co., Ltd.

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INTATRADE GmbH

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future industrial shanghai co., ltd

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View Lastest Price from 4-Bromo-1,2-(methylenedioxy)benzene manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: 4-Bromo-1,2-(methylenedioxy)benzene 2635-13-4
Price: US $1.00/PCS
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-06-15

Hebei Mojin Biotechnology Co., Ltd

Product: 4-Bromo-1,2-(methylenedioxy)benzene 2635-13-4
Price: US $500.00/g
Min. Order: 100g
Purity: 99%
Supply Ability: 200ton
Release date: 2023-08-30

Hebei Best Biological Technology Co., Ltd

Product: 5-Bromo-1,3-benzodioxole 2635-13-4
Price: US $200.00/g
Min. Order: 10g
Purity: 99%
Supply Ability: 1000t/month
Release date: 2022-11-30

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2635-13-4

128577-477-9

Protected Alcohols/Phenols

Oxygen Compounds

Organic Building Blocks

Building Blocks

ARYL HALIDE

Building Blocks

Chemical Synthesis

Organic Building Blocks

Oxygen Compounds

Protected Alcohols/Phenols

Miscellaneous

Bromine Compounds

Miscellaneous Compounds

Aromatic Hydrocarbons (substituted) & Derivatives

2635-13-4