ADOGEN(R) 464 Property

Boiling point:

>240℃

Density 

0.898 g/mL at 25 °C(lit.)

vapor density 

>1 (vs air)

vapor pressure 

33 mm Hg ( 20 °C)

refractive index 

n20/D 1.4665(lit.)

Flash point:

>230 °F

storage temp. 

Store below +30°C.

solubility 

Miscible with benzene and chloroform.

form 

Viscous Liquid

color 

Amber

Water Solubility 

1.023g/L at 20℃

Sensitive 

Hygroscopic

LogP

2.93 at 25℃

EPA Substance Registry System

Quaternary ammonium compounds, tri-C8-10-alkylmethyl, chlorides (63393-96-4)

Safety

Hazard Codes 

C,N,Xn

Risk Statements 

10-22-34-50/53-41-38-67

Safety Statements 

16-26-27-36/37/39-45-61-60-39

RIDADR 

UN 2924 3/PG 3

WGK Germany 

3

RTECS 

UZ2997500

TSCA 

Yes

HS Code 

3824 99 92

HazardClass 

8

PackingGroup 

III

Toxicity

LD50 orally in Rabbit: 220 mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H318Causes serious eye damage

H400Very toxic to aquatic life

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P405Store locked up.

P501Dispose of contents/container to..…

ADOGEN(R) 464 Chemical Properties,Usage,Production

Chemical Properties

amber viscous liquid at room temperature

Uses

Aliquat 336 is widely utilized as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. It is involved in the total synthesis of Manzamine A. It serves as an anti-static agent for textile fabrics and carpeting. It finds application in waste water treatment to control foaming. It has a major application as a metal extraction reagent for cadmium, zinc, iron and rare earth metals. It is used as an effective catalyst for the preparation of methylphenyl ether from sodium phenolate with for methyl bromide.

Uses

Quat suitable for nearly all PTC applications without aqueous work-up

Definition

ChEBI: Methyltrioctylammonium chloride is an organic chloride salt having methyltrioctylammonium as the cation. It has a role as a phase-transfer catalyst. It is a quaternary ammonium salt and an organic chloride salt. It contains a methyltrioctylammonium.

Flammability and Explosibility

Not classified

Purification Methods

A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]