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4-Bromotriphenylamine

Product Name
4-Bromotriphenylamine
CAS No.
36809-26-4
Chemical Name
4-Bromotriphenylamine
Synonyms
4-BROMO-N,N-DIPHENYLANILINE;Bromotriphenylamine;K0062;4-BTPA;4-BromotriphenyL;4-Bromotrienidine;4-BROOTRIPHENYLAMINE;4-BROMOTRIPHENYLAMINE;4- broMothree aniline;1-Bromotriphenylamine
CBNumber
CB5450596
Molecular Formula
C18H14BrN
Formula Weight
324.21
MOL File
36809-26-4.mol
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4-Bromotriphenylamine Property

Melting point:
108-112 °C (lit.)
Boiling point:
185 °C / 2.5mmHg
Density 
1.369±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Toluene
form 
powder to crystal
pka
-3.66±0.30(Predicted)
color 
White to Almost white
InChIKey
SQTLUXJWUCHKMT-UHFFFAOYSA-N
CAS DataBase Reference
36809-26-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38-43
Safety Statements 
26-36/37
WGK Germany 
3
HS Code 
29214200
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
643831
Product name
4-Bromotriphenylamine
Purity
97%
Packaging
5g
Price
$35.36
Updated
2024/03/01
Sigma-Aldrich
Product number
643831
Product name
4-Bromotriphenylamine
Purity
97%
Packaging
25g
Price
$97.8
Updated
2024/03/01
TCI Chemical
Product number
B2633
Product name
4-Bromotriphenylamine
Purity
>97.0%(GC)
Packaging
5g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
B2633
Product name
4-Bromotriphenylamine
Purity
>97.0%(GC)
Packaging
25g
Price
$94
Updated
2024/03/01
Alfa Aesar
Product number
H60328
Product name
4-Bromotriphenylamine, 99%
Packaging
5g
Price
$76.65
Updated
2024/03/01
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4-Bromotriphenylamine Chemical Properties,Usage,Production

Chemical Properties

White powder or crystal

Uses

4-bromotriphenylamine could be used as material to synthesize a novel type of Schiff base fluorescent probe molecule N′-((5-(4-(diphenylamino)phenyl)thiophen-2-yl)methylene)benzenesulfonohydrazide (BS). BS exhibited excellent solvatochromic effect and aggregation-induced emission enhancement and had rapid recognition, high selectivity and specificity for Hg2+; the detection limit was as low as 2.84×10?8?M, and the response time was only 15 s[1].

Synthesis

To a solution of triphenylamine(2.1 g, 8.16 mmol) in 40mL CCl4, NBS (1.6g,8.16 mmol) was added and the reaction mixture refluxed for 4 h under nitrogen (N2) atmosphere. During the reaction, a solid was formed, which conformed as succinimide. After filtering, the reaction mixture, filtrate was evaporated and recrystallized from ethanol to yield 4-Bromotriphenylamine 93%.

References

[1] Songsong Xue. “Highly Selective and Sensitive Sulfonylhydrazone Type Fluorescent Probe for Rapid Detection of Mercury(II) and Its Application in Logic Gate and Adsorption.” ChemistrySelect 6 28 (2021): 7123–7129.

4-Bromotriphenylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromotriphenylamine Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from 4-Bromotriphenylamine manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
4-Bromotriphenylamine 36809-26-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99.5% HPLC
Supply Ability
10 tons
Release date
2024-03-18
Shanghai Daken Advanced Materials Co.,Ltd
Product
4-Bromotriphenylamine 36809-26-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG /month
Release date
2021-11-19
Shaanxi Dideu Medichem Co. Ltd
Product
4-Bromotriphenylamine 36809-26-4
Price
US $1.00-1.00/KG
Min. Order
1g
Purity
99%
Supply Ability
50ton
Release date
2020-05-20

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