ChemicalBook > CAS DataBase List > Methyl 2-iodobenzoate

Methyl 2-iodobenzoate

Product Name
Methyl 2-iodobenzoate
CAS No.
610-97-9
Chemical Name
Methyl 2-iodobenzoate
Synonyms
IBM;2-Iodobenzoate;2-Iodo Methyl Benzoate;methyl iodobenzoate;Methy1;O-Methyl iodide;Methyl 2-iodobenzo;RARECHEM AL BF 0562;Methyl-2-iodbenzoat;METHYL 2-IODOBENZOATE
CBNumber
CB5468414
Molecular Formula
C8H7IO2
Formula Weight
262.04
MOL File
610-97-9.mol
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Methyl 2-iodobenzoate Property

Melting point:
64°C
Boiling point:
149-150 °C/10 mmHg (lit.)
Density 
1.784 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.604(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform, Ethyl Acetate (Slightly), Methanol
form 
Crystalling or Flaky Powder
color 
White
Water Solubility 
INSOLUBLE
Sensitive 
Light Sensitive
BRN 
2206859
Stability:
Light Sensitive
InChIKey
BXXLTVBTDZXPTN-UHFFFAOYSA-N
CAS DataBase Reference
610-97-9(CAS DataBase Reference)
NIST Chemistry Reference
Methyl-2-iodobenzoate(610-97-9)
EPA Substance Registry System
Benzoic acid, 2-iodo-, methyl ester (610-97-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
3
TSCA 
T
HazardClass 
IRRITANT
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
532851
Product name
Methyl 2-iodobenzoate
Purity
97%
Packaging
50g
Price
$83.1
Updated
2025/07/31
Sigma-Aldrich
Product number
532851
Product name
Methyl 2-iodobenzoate
Purity
97%
Packaging
250g
Price
$185
Updated
2023/06/20
TCI Chemical
Product number
I0586
Product name
Methyl 2-Iodobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$50
Updated
2025/07/31
TCI Chemical
Product number
I0586
Product name
Methyl 2-Iodobenzoate
Purity
>98.0%(GC)
Packaging
250g
Price
$196
Updated
2025/07/31
TRC
Product number
M313675
Product name
Methyl 2-iodobenzoate
Packaging
250g
Price
$310
Updated
2021/12/16
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Methyl 2-iodobenzoate Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW LIQUID

Uses

Methyl 2-iodobenzoate may be used in the preparation of:

  • N-substituted 4-methylene-3,4-dihydro-1(2H)-isoquinolin-1-ones
  • methyl diphenylacetylene-2-carboxylate
  • methyl 2-heptynylphenylbenzoate
  • (E)-2-[3-[3-[2-(7-chloro-2-quinolinyl)ethenyl]phenyl]-3-oxopropyl]benzoic acid methyl ester
  • 4-(2-carbomethoxyphenyl)-3-(1-methylethoxy)cyclobut-3-ene-1,2-dione
  • 3-(2-carbomethoxyphenyl)-4-methylcyclobuten-3-ene-1,2-dione 2-(ethylene acetal)

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 4845, 1971 DOI: 10.1021/ja00748a030

General Description

Methyl 2-iodobenzoate can be prepared from 2-iodobenzoic acid via esterification. It undergoes cobalt-catalyzed cyclization with aldehydes to form phthalide derivatives. The microbial dihydroxylation of methyl 2-iodobenzoate forms a nonracemic iodocyclohexene carboxylate intermediate. This intermediate forms the precursor for preparing kibdelone C.

Synthesis

67-56-1

88-67-5

610-97-9

To a 200 mL methanol solution of 2-iodobenzoic acid (15 g, 60 mmol) was slowly added 8.8 mL of concentrated sulfuric acid dropwise. The reaction mixture was heated to reflux for 16 hours. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated by rotary evaporator to about 20 mL. Subsequently, the concentrate was partitioned between water (appropriate amount) and dichloromethane (appropriate amount). The aqueous phase was further extracted with dichloromethane (2 × 150 mL). The organic layers were combined and washed sequentially with saturated sodium bicarbonate solution (3 × 100 mL) and water (3 × 100 mL). The organic layers were dried over anhydrous sodium sulfate, filtered and the solvent was evaporated to give methyl 2-iodobenzoate (47) as a light yellow oil (15.4 g, 98% yield).The infrared spectrum of methyl 2-iodobenzoate (47) (KBr, νmax, cm?1): 3444, 3057, 2994, 2946, 2894, 2836, 1728, 1579, 1459, 1428, 1290. 1459, 1428, 1290, 1249, 1127, 1100, 1013, 738.

References

[1] Organic and Biomolecular Chemistry, 2018, vol. 16, # 17, p. 3213 - 3219
[2] Organometallics, 2013, vol. 32, # 11, p. 3220 - 3226
[3] European Journal of Medicinal Chemistry, 2013, vol. 69, p. 798 - 816
[4] Synthetic Communications, 2017, vol. 47, # 12, p. 1175 - 1184
[5] Angewandte Chemie - International Edition, 2017, vol. 56, # 39, p. 11995 - 11999

Methyl 2-iodobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

2-Methoxycarbonylphenylboronic acid
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Methyl 2-iodobenzoate Suppliers

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View Lastest Price from Methyl 2-iodobenzoate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Methyl 2-Iodobenzoate 610-97-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-05
Hebei Chuanghai Biotechnology Co., Ltd
Product
Methyl 2-iodobenzoate 610-97-9
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl 2-iodobenzoate 610-97-9
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-09

610-97-9, Methyl 2-iodobenzoateRelated Search:

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  • 610-97-9
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  • Organic Building Blocks
  • Esters
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  • bc0001
  • 610-97-9