ChemicalBook > CAS DataBase List > 4-Methoxy-2-nitrobenzoic acid

4-Methoxy-2-nitrobenzoic acid

Product Name
4-Methoxy-2-nitrobenzoic acid
CAS No.
33844-21-2
Chemical Name
4-Methoxy-2-nitrobenzoic acid
Synonyms
RARECHEM AL BO 1421;2-Nitro-p-anisic Acid;2-NITRO-4-METHOXYBENZOIC ACID;4-METHOXY-2-NITROBENZOIC ACID;4-Methoxy-2-nitronbenzoic acid;Benzoic acid, 4-methoxy-2-nitro-;4-METHOXY-2-NITROBENZOIC ACID 98%;4-Carboxy-3-nitroanisole, 2-Nitro-p-anisic acid;4-Methoxy-2-nitrobenzoic acid ISO 9001:2015 REACH
CBNumber
CB5675333
Molecular Formula
C8H7NO5
Formula Weight
197.14
MOL File
33844-21-2.mol
More
Less

4-Methoxy-2-nitrobenzoic acid Property

Melting point:
196.5-200.5 °C (lit.)
Boiling point:
372.9±27.0 °C(Predicted)
Density 
1.430±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
pka
2.46±0.25(Predicted)
color 
White to Light yellow to Light orange
CAS DataBase Reference
33844-21-2(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
36
WGK Germany 
2
HS Code 
2918999090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
638722
Product name
4-Methoxy-2-nitrobenzoic acid
Purity
97%
Packaging
1g
Price
$40
Updated
2023/06/20
Sigma-Aldrich
Product number
638722
Product name
4-Methoxy-2-nitrobenzoic acid
Purity
97%
Packaging
5g
Price
$156
Updated
2023/06/20
TCI Chemical
Product number
M2828
Product name
4-Methoxy-2-nitrobenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$57
Updated
2025/07/31
TCI Chemical
Product number
M2828
Product name
4-Methoxy-2-nitrobenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$171
Updated
2025/07/31
TRC
Product number
M327003
Product name
4-Methoxy-2-nitrobenzoic Acid
Packaging
1g
Price
$75
Updated
2021/12/16
More
Less

4-Methoxy-2-nitrobenzoic acid Chemical Properties,Usage,Production

Uses

4-Methoxy-2-nitrobenzoic acid can serve as a key step in chemical reactions for synthesizing certain drug molecules, or play a role in the synthesis of certain types of dyes, fragrances, and other chemicals.

Synthesis

17484-36-5

33844-21-2

Step 1: A mixed solution of 4-methyl-3-nitroanisole (3.6 g, 18 mmol) with potassium permanganate (10 g, 63 mmol) in 200 mL of water was refluxed for 24 hours. After completion of the reaction, it was cooled to room temperature and filtered to remove insoluble solids. The filtrate was acidified to pH 2 with 1 N hydrochloric acid and subsequently extracted with chloroform (3 x 50 mL). The organic phases were combined, dried with anhydrous magnesium sulfate and filtered. The filtrate was concentrated under reduced pressure and the precipitate precipitated was collected to give 4-methoxy-2-nitrobenzoic acid in 80% yield.

References

[1] Patent: US5665719, 1997, A
[2] Journal of Organic Chemistry, 2018, vol. 83, # 15, p. 8092 - 8103
[3] Chemische Berichte, 1918, vol. 51, p. 14
[4] Patent: US4781750, 1988, A

4-Methoxy-2-nitrobenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

4-Methoxy-2-nitrobenzoic acid Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9310
Advantage
66
Shangchem Co., Ltd.
Tel
+86-21-68182121
Fax
+86-21-68182121
Country
China
ProdList
882
Advantage
52
NOTA Chemical (Shanghai) Co.,Ltd
Tel
021-50189163
Fax
021-51687927
Email
sales@notachem.com
Country
China
ProdList
205
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
Advantage
59
More
Less

View Lastest Price from 4-Methoxy-2-nitrobenzoic acid manufacturers

Henan Fengda Chemical Co., Ltd
Product
4-Methoxy-2-nitrobenzoic acid 33844-21-2
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Methoxy-2-nitrobenzoic acid 33844-21-2
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Shaanxi Dideu Medichem Co. Ltd
Product
4-Methoxy-2-nitrobenzoic acid 33844-21-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%+
Supply Ability
100 tons
Release date
2020-01-07

33844-21-2, 4-Methoxy-2-nitrobenzoic acidRelated Search:


  • 4-METHOXY-2-NITROBENZOIC ACID
  • 2-NITRO-4-METHOXYBENZOIC ACID
  • RARECHEM AL BO 1421
  • 4-Carboxy-3-nitroanisole, 2-Nitro-p-anisic acid
  • 4-METHOXY-2-NITROBENZOIC ACID 98%
  • Benzoic acid, 4-methoxy-2-nitro-
  • 2-Nitro-p-anisic Acid
  • 4-Methoxy-2-nitrobenzoic acid ISO 9001:2015 REACH
  • 4-Methoxy-2-nitronbenzoic acid
  • 33844-21-2
  • Organic Building Blocks
  • Building Blocks
  • C8
  • Carboxylic Acids
  • Carbonyl Compounds
  • Building Blocks
  • Carbonyl Compounds
  • Carboxylic Acids
  • Chemical Synthesis
  • Organic Building Blocks
  • Benzoic acid
  • C8
  • Carbonyl Compounds
  • Carboxylic Acids
  • blocks
  • Carboxes
  • NitroCompounds