3,5-Dimethyl-4-iodopyrazole
- Product Name
- 3,5-Dimethyl-4-iodopyrazole
- CAS No.
- 2033-45-6
- Chemical Name
- 3,5-Dimethyl-4-iodopyrazole
- Synonyms
- SALOR-INT L119644-1EA;LABOTEST-BB LT01148501;4-IODO-3,5-DIMETHYLPYRAZOLE;3,5-DIMETHYL-4-IODOPYRAZOLE;3,5-dimethyl-4-iodo-pyrazol;3.5-Dimethyl-4-lodo pyrazole;Pyrazole, 3,5-dimethyl-4-iodo-;4-Iodo-3,5-dimethylpyrazole>4-IODO-3,5-DIMETHYL-1H-PYRAZOLE;3,5-DIMETHYL-4-IODO-1H-PYRAZOLE
- CBNumber
- CB5735673
- Molecular Formula
- C5H7IN2
- Formula Weight
- 222.03
- MOL File
- 2033-45-6.mol
3,5-Dimethyl-4-iodopyrazole Property
- Melting point:
- 136-140 °C
- Boiling point:
- 297.3±35.0 °C(Predicted)
- Density
- 1.920±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- form
- powder to crystal
- pka
- 14.11±0.50(Predicted)
- color
- White to Almost white
- Sensitive
- Light Sensitive
- λmax
- 223nm(EtOH)(lit.)
- CAS DataBase Reference
- 2033-45-6(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 37/38-41
- Safety Statements
- 24/25-39-26
- WGK Germany
- 3
- RTECS
- UQ6517000
- HazardClass
- IRRITANT
- HS Code
- 29331990
- Toxicity
- mouse,LD50,intraperitoneal,550mg/kg (550mg/kg),Farmakologiya i Toksikologiya Vol. 25, Pg. 27, 1962.
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 683523
- Product name
- 3,5-Dimethyl-4-iodo-1H-pyrazole
- Purity
- 97%
- Packaging
- 5g
- Price
- $78.4
- Updated
- 2025/07/31
- Product number
- 683523
- Product name
- 3,5-Dimethyl-4-iodo-1H-pyrazole
- Purity
- 97%
- Packaging
- 1g
- Price
- $65
- Updated
- 2023/01/07
- Product number
- I0771
- Product name
- 4-Iodo-3,5-dimethylpyrazole
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $20
- Updated
- 2025/07/31
- Product number
- I0771
- Product name
- 4-Iodo-3,5-dimethylpyrazole
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $49
- Updated
- 2025/07/31
- Product number
- D474208
- Product name
- 3,5-Dimethyl-4-iodopyrazole
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
3,5-Dimethyl-4-iodopyrazole Chemical Properties,Usage,Production
Chemical Properties
white crystalline chunks
Synthesis
67-51-6
2033-45-6
In a 250 mL round bottom flask, 3,5-dimethyl-1H-pyrazole (0.5 g, 5 mmol), iodine (I2, 0.79 g, 30 mmol) and ceric ammonium nitrate (CAN, 1.71 g, 3 mmol) were dissolved in 70 mL of acetonitrile (CH3CN). The reaction mixture was stirred at room temperature for 16 hours. After completion of the reaction, the solvent was removed by rotary evaporator. The residue was dissolved in ethyl acetate (AcOEt) and washed sequentially with 10% aqueous sodium thiosulfate (Na2S2O3) and saturated saline. The aqueous phase was extracted once more with ethyl acetate, all organic phases were combined, dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated to dryness to afford 1.15 g (100% yield) of crude 4-iodo-3,5-dimethyl-1H-pyrazole, which was used in the subsequent reaction without further purification.LC-MS (MH+): 223.
References
[1] Patent: WO2006/128692, 2006, A2. Location in patent: Page/Page column 76
[2] Canadian Journal of Chemistry, 1992, vol. 70, # 4, p. 1121 - 1128
[3] Tetrahedron Letters, 2005, vol. 46, # 40, p. 6833 - 6837
[4] Tetrahedron Letters, 2001, vol. 42, # 5, p. 863 - 865
[5] Synthesis, 2001, # 11, p. 1711 - 1715
3,5-Dimethyl-4-iodopyrazole Preparation Products And Raw materials
Raw materials
Preparation Products
3,5-Dimethyl-4-iodopyrazole Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 3,5-Dimethyl-4-iodopyrazole manufacturers
- Product
- 3,5-Dimethyl-4-iodopyrazole 2033-45-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- 3,5-Dimethyl-4-iodopyrazole 2033-45-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2019-05-24