Benzyltriphenylphosphonium chloride
- Product Name
- Benzyltriphenylphosphonium chloride
- CAS No.
- 1100-88-5
- Chemical Name
- Benzyltriphenylphosphonium chloride
- Synonyms
- BTPPC;BPP;BTPPCl;NSC 116712;AURORA KA-1173;Benzyltriphenylphosp;Benzyltriphenylchlorophosphine;Triphenylbenzylidenephosphorane;BENZYLIDENE(TRIPHENYL)PHOSPHORANE;benzyltriphenyl-phosphoniuchloride
- CBNumber
- CB5738942
- Molecular Formula
- C25H22ClP
- Formula Weight
- 388.87
- MOL File
- 1100-88-5.mol
Benzyltriphenylphosphonium chloride Property
- Melting point:
- ≥300 °C (lit.)
- Density
- 1.18 g/cm3 (20℃)
- vapor pressure
- 0.1 hPa
- Flash point:
- 300°C
- storage temp.
- Store at <= 20°C.
- form
- Crystalline Powder
- color
- White to almost white
- Water Solubility
- SOLUBLE
- Sensitive
- Hygroscopic
- BRN
- 3599868
- Stability:
- Stable. Incompatible with strong oxidizing agents.
- InChIKey
- USFRYJRPHFMVBZ-UHFFFAOYSA-M
- LogP
- -0.7 at 20℃
- CAS DataBase Reference
- 1100-88-5(CAS DataBase Reference)
- EPA Substance Registry System
- Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5)
Safety
- Hazard Codes
- T,Xi
- Risk Statements
- 25-36/37/38-24/25
- Safety Statements
- 26-36/37/39-45-36
- RIDADR
- UN 2811 6.1/PG 2
- WGK Germany
- 3
- RTECS
- TA2416500
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29310095
- Toxicity
- LD50 orally in Rabbit: 43 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H318Causes serious eye damage
H335May cause respiratory irritation
H372Causes damage to organs through prolonged or repeated exposure
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- B32807
- Product name
- Benzyltriphenylphosphonium chloride
- Purity
- 99%
- Packaging
- 25g
- Price
- $32.52
- Updated
- 2024/03/01
- Product number
- B32807
- Product name
- Benzyltriphenylphosphonium chloride
- Purity
- 99%
- Packaging
- 100g
- Price
- $95.4
- Updated
- 2024/03/01
- Product number
- B0824
- Product name
- Benzyltriphenylphosphonium Chloride
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $36
- Updated
- 2024/03/01
- Product number
- B0824
- Product name
- Benzyltriphenylphosphonium Chloride
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 500g
- Price
- $391
- Updated
- 2024/03/01
- Product number
- A14034
- Product name
- Benzyltriphenylphosphonium chloride, 99%
- Packaging
- 100g
- Price
- $77
- Updated
- 2024/03/01
Benzyltriphenylphosphonium chloride Chemical Properties,Usage,Production
Chemical Properties
Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks.
Uses
Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity.
Application
Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites
Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes
Flammability and Explosibility
Not classified
reaction suitability
reaction type: C-C Bond Formation
Purification Methods
Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.]
Benzyltriphenylphosphonium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Benzyltriphenylphosphonium chloride manufacturers
- Product
- Benzyltriphenylphosphonium chloride 1100-88-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%min
- Supply Ability
- 30tons/month
- Release date
- 2023-02-23
- Product
- Benzyltriphenylphosphonium chloride 1100-88-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-21
- Product
- Benzyltriphenylphosphonium chloride 1100-88-5
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-20