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Benzyltriphenylphosphonium chloride

Product Name
Benzyltriphenylphosphonium chloride
CAS No.
1100-88-5
Chemical Name
Benzyltriphenylphosphonium chloride
Synonyms
BTPPC;BPP;BTPPCl;NSC 116712;AURORA KA-1173;Benzyltriphenylphosp;Benzyltriphenylchlorophosphine;Triphenylbenzylidenephosphorane;BENZYLIDENE(TRIPHENYL)PHOSPHORANE;benzyltriphenyl-phosphoniuchloride
CBNumber
CB5738942
Molecular Formula
C25H22ClP
Formula Weight
388.87
MOL File
1100-88-5.mol
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Benzyltriphenylphosphonium chloride Property

Melting point:
≥300 °C (lit.)
Density 
1.18 g/cm3 (20℃)
vapor pressure 
0.1 hPa
Flash point:
300°C
storage temp. 
Store at <= 20°C.
form 
Crystalline Powder
color 
White to almost white
Water Solubility 
SOLUBLE
Sensitive 
Hygroscopic
BRN 
3599868
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
USFRYJRPHFMVBZ-UHFFFAOYSA-M
LogP
-0.7 at 20℃
CAS DataBase Reference
1100-88-5(CAS DataBase Reference)
EPA Substance Registry System
Phosphonium, triphenyl(phenylmethyl)-, chloride (1100-88-5)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
25-36/37/38-24/25
Safety Statements 
26-36/37/39-45-36
RIDADR 
UN 2811 6.1/PG 2
WGK Germany 
3
RTECS 
TA2416500
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29310095
Toxicity
LD50 orally in Rabbit: 43 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

H335May cause respiratory irritation

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B32807
Product name
Benzyltriphenylphosphonium chloride
Purity
99%
Packaging
25g
Price
$32.52
Updated
2024/03/01
Sigma-Aldrich
Product number
B32807
Product name
Benzyltriphenylphosphonium chloride
Purity
99%
Packaging
100g
Price
$95.4
Updated
2024/03/01
TCI Chemical
Product number
B0824
Product name
Benzyltriphenylphosphonium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
B0824
Product name
Benzyltriphenylphosphonium Chloride
Purity
>98.0%(HPLC)(T)
Packaging
500g
Price
$391
Updated
2024/03/01
Alfa Aesar
Product number
A14034
Product name
Benzyltriphenylphosphonium chloride, 99%
Packaging
100g
Price
$77
Updated
2024/03/01
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Benzyltriphenylphosphonium chloride Chemical Properties,Usage,Production

Chemical Properties

Benzyltriphenylphosphonium Chloride is a white to off white powder, It is highly soluble in water and polarizable solvents. It is a quaternary phosphonium salt mainly used in organic synthesis as a wittig reagent and as a phase transfer catalyst in the production of fluoroelastomers and printing inks.

Uses

Benzyltriphenylphosphonium Chloride was used as a reagent in the organic synthesis of several compounds including that of stabilised phosphonium ylides containing saturated oxygen heterocycles. Also used in the synthesis of novel substituted cis-stilbene derivatives which display antimicrobial activity.

Application

Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:
Platinum chloro-tetrazole complexes via azidation.
Trans-stilbenes and cinnamates via Wittig olefination.
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
Pentiptycenes for use as light-driven molecular brakes.
Archipelago structures for formation of petroleum asphaltenes.
It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.
Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites

Reactant for synthesis of:
Platinum chloro tetrazole complexes via azidation
Trans-stilbenes and cinnamates via Wittig olefination
Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
Pentiptycenes for use as light-driven molecular brakes
Reactant for formation of archipelago structures for formation of petroleum asphaltenes

Flammability and Explosibility

Not classified

Purification Methods

Wash it with Et2O and crystallise it from EtOH (six-sided plates). It is hygroscopic and forms crystals with one molecule of H2O. [Michaelis & Soden Justus Liebigs Ann Chem 229 320 1885, Kr.hnke Chem Ber 83 291 1950, Beilstein 16 IV 994.]

Benzyltriphenylphosphonium chloride Preparation Products And Raw materials

Raw materials

3-Cyanopyridine

Preparation Products

Sulindac
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Benzyltriphenylphosphonium chloride Suppliers

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View Lastest Price from Benzyltriphenylphosphonium chloride manufacturers

Henan Fengda Chemical Co., Ltd
Product
Benzyltriphenylphosphonium chloride 1100-88-5
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Benzyltriphenylphosphonium chloride 1100-88-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%min
Supply Ability
30tons/month
Release date
2023-02-23
Hebei Mojin Biotechnology Co., Ltd
Product
Benzyltriphenylphosphonium chloride 1100-88-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-28

1100-88-5, Benzyltriphenylphosphonium chlorideRelated Search:

Benzyltriethylammonium chloride Triphenylphosphine Calcium chloride Ammonium chloride Choline chloride 2,3,5-Triphenyltetrazolium chloride Thionyl chloride Potassium chloride Polyvinyl chloride DICHLOROTRIPHENYLPHOSPHORANE Benzyltrimethylammonium chloride Sodium chloride Methyltriphenylphosphonium iodide Chlorodiphenylphosphine Triphenylphosphine hydrobromide Benzyltriphenylphosphonium bromide P-XYLYLENEBIS(TRIPHENYLPHOSPHONIUM CHLORIDE) (1-NAPHTHYLMETHYL)TRIPHENYLPHOSPHONIUM CHLORIDE

  • (phenylmethyl)triphenyl-phosphoniuchloride
  • (phenylmethyl)triphenylphosphoniumchloride
  • Benzyltriphenylchlorophosphine
  • benzyltriphenylphosphonidechloride
  • benzyltriphenyl-phosphoniuchloride
  • Phosphonium,triphenyl(phenylmethyl)-,chloride
  • triphenyl(phenylmethyl)-phosphoniuchloride
  • triphenyl(phenylmethyl)phosphoniumchloride
  • Triphenyl(phenylmethyl)-phosphoniumchloride
  • BPP
  • BENZYLIDENE(TRIPHENYL)PHOSPHORANE
  • AURORA KA-1173
  • Benzyltriphenylphosphoniumchloride,99%
  • BTPPCl: Benzyltriphenylphosphonium Chloride
  • Benzyltriphenylphosphonium chloride
  • BENZYL TRIPHENYL PHOSPHONIUM CHLORIDE(BTTPC)
  • Phosphonium, benzyltriphenyl, chloride
  • Triphenylbenzylidenephosphorane
  • benzyltriphenilphosphonium chloride
  • Benzyltriphenylphosp
  • Benzyl triphenyl phosphorus chloride
  • BenzyltriphenylphosphoniuM chloride (BPP)
  • Three phenylphosphine dichloridebenzyl
  • BTPPC
  • NSC 116712
  • Benzyltriphenylphosphonium chloride 99%
  • BTPPCl
  • Phosphonium, triphenyl(phenylmethyl)-, chloride (1:1)
  • Benzyltriphenylphosphonium Chloride &gt
  • BENZYLTRIPHENYLPHOSPHONIUM CHLORIDE FOR
  • Benzyl triphenyl phosphonium Chloride Solid
  • Triphenyl(phenylmethyl)phosphonium Chloride(BTPPC)
  • 1100-88-5
  • C6H5CH2PClC6H53
  • C6H5CH2PC6H53Cl
  • C25H21P
  • C25H22ClP
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents
  • organophosphorus compound
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents
  • Pharmaceutical Intermediates
  • Miscellaneous Compounds
  • Phosphonium Compounds
  • Synthetic Organic Chemistry
  • Wittig & Horner-Emmons Reaction
  • Wittig Reaction