3-Cyanopyridine
- Product Name
- 3-Cyanopyridine
- CAS No.
- 100-54-9
- Chemical Name
- 3-Cyanopyridine
- Synonyms
- NICOTINONITRILE;3-PYRIDINECARBONITRILE;Pyridine-3-carbonitrile;3-Azabenzonitrile;BETA-CYANOPYRIDINE;NICOTINIC ACID NITRILE;3-CYANOPYRIDINE;b-Cyanopyridine;3-Cyjanopirydyna;AKOS BBS-00004487
- CBNumber
- CB9852589
- Molecular Formula
- C6H4N2
- Formula Weight
- 104.11
- MOL File
- 100-54-9.mol
3-Cyanopyridine Property
- Melting point:
- 48-52 °C(lit.)
- Boiling point:
- 201 °C(lit.)
- Density
- 1.159
- refractive index
- 1.5242 (estimate)
- Flash point:
- 184 °F
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- 140g/l
- form
- Crystalline Mass, Crystals or Chunks
- pka
- pK1:1.45(+1) (25°C)
- color
- Colorless or white to yellow
- Water Solubility
- 140 g/L (20 ºC)
- BRN
- 107711
- Exposure limits
- NIOSH: IDLH 25 mg/m3
- Stability:
- Incompatible with strong oxidizing agents, strong reducing agents, strong acids, strong bases.
- InChIKey
- GZPHSAQLYPIAIN-UHFFFAOYSA-N
- CAS DataBase Reference
- 100-54-9(CAS DataBase Reference)
- NIST Chemistry Reference
- 3-Pyridinecarbonitrile(100-54-9)
- EPA Substance Registry System
- 3-Pyridinecarbonitrile (100-54-9)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 22-24/25-36/37/39-26
- WGK Germany
- 3
- RTECS
- QT3030000
- TSCA
- Yes
- HS Code
- 29333999
- Hazardous Substances Data
- 100-54-9(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C94807
- Product name
- 3-Pyridinecarbonitrile
- Purity
- 98%
- Packaging
- 5g
- Price
- $50.8
- Updated
- 2024/03/01
- Product number
- C94807
- Product name
- 3-Pyridinecarbonitrile
- Purity
- 98%
- Packaging
- 100g
- Price
- $55.3
- Updated
- 2024/03/01
- Product number
- C0456
- Product name
- 3-Cyanopyridine
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $20
- Updated
- 2024/03/01
- Product number
- C0456
- Product name
- 3-Cyanopyridine
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $69
- Updated
- 2024/03/01
- Product number
- A14850
- Product name
- 3-Cyanopyridine, 98%
- Packaging
- 100g
- Price
- $33.8
- Updated
- 2024/03/01
3-Cyanopyridine Chemical Properties,Usage,Production
Chemical Properties
white to beige solid
Chemical Properties
The cyanopyridines are as follows: 2-cyano-: A white to tan liquid or solid. Almond odor. Boiling point=2213℃ ; freezing/melting point=27℃ ; flash point=89℃ . 3-cyano-: a colorless liquid or gray crystal- line solid.
Uses
3-Cyanopyridine is used in the preparation of arylthiazolines and arylimidazolines via dibromodimethylhydantoin-catalyzed condensation of aryl nitriles with ethylene diamine or aminoethanethiol.
Definition
ChEBI: A nitrile that is pyridine substituted by a cyano group at position 3.
Synthesis Reference(s)
Tetrahedron Letters, 29, p. 2155, 1988 DOI: 10.1016/S0040-4039(00)86697-6
Potential Exposure
Limits in Air NIOSH IDLH525 mg/m3 NIOSH REL: (nitriles) 2 ppm, Ceiling Concentration, not to be exceeded in any 15-minute work period.
Shipping
UN3276 Nitriles, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required, Potential Inhalation Hazard (Special Provision 5).
Purification Methods
It is recrystallised to constant melting point from o-xylene/hexane. [Beilstein 22/2 V 115.]
Incompatibilities
Oxidizing agents, such as perchlorates, peroxides, and permanganates. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give car- boxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids .
3-Cyanopyridine Preparation Products And Raw materials
Raw materials
Preparation Products
3-Cyanopyridine Suppliers
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View Lastest Price from 3-Cyanopyridine manufacturers
- Product
- 3-Cyanopyridine 100-54-9
- Price
- US $68.00-50.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 8000kg
- Release date
- 2023-09-19
- Product
- 3-Cyanopyridine 100-54-9
- Price
- US $3.00/kg
- Min. Order
- 1kg
- Purity
- 99.92%
- Supply Ability
- 50000tons
- Release date
- 2024-04-19
- Product
- 3-Cyanopyridine 100-54-9
- Price
- US $5.00-0.10/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-09