3-(Aminomethyl)pyridine

Product Name: 3-(Aminomethyl)pyridine
CAS No.: 3731-52-0
Chemical Name: 3-(Aminomethyl)pyridine
Synonyms: pyridin-3-ylmethanamine;Picolamine;3AMPY;NSC 59706;Picolamin;-Aminomethyl;3-PICOLYLAMINE;AKOS BBS-00003679;3-Picolylamine>TIMTEC-BB SBB004351
CBNumber: CB2284635
Molecular Formula: C6H8N2
Formula Weight: 108.14
MOL File: 3731-52-0.mol

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3-(Aminomethyl)pyridine Property

Melting point:: −21 °C(lit.)
Boiling point:: 73-74 °C1 mm Hg(lit.)
Density: 1.062 g/mL at 25 °C(lit.)
refractive index: n20/D 1.551(lit.)
Flash point:: 213 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Chloroform, Ethyl Acetate, Methanol
pka: 8.34±0.29(Predicted)
form: clear liquid
color: Colorless to Light yellow
PH: 11-12 (100g/l, H2O, 20℃)
Water Solubility: FREELY SOLUBLE
Sensitive: Air Sensitive
BRN: 108056
CAS DataBase Reference: 3731-52-0(CAS DataBase Reference)
NIST Chemistry Reference: Picolamine(3731-52-0)
EPA Substance Registry System: 3-Pyridinemethanamine (3731-52-0)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-37-36/37/38
Safety Statements: 26-36/37/39-45-25-36
RIDADR: UN 2735 8/PG 2
WGK Germany: 3
Hazard Note: Irritant
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29333999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: A65409
Product name: 3-Picolylamine
Purity: ≥99%
Packaging: 5g
Price: $31.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: A65409
Product name: 3-Picolylamine
Purity: ≥99%
Packaging: 100g
Price: $76
Updated: 2024/03/01

TCI Chemical

Product number: P0762
Product name: 3-Picolylamine
Purity: >99.0%(GC)
Packaging: 25mL
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: P0762
Product name: 3-Picolylamine
Purity: >99.0%(GC)
Packaging: 100mL
Price: $50
Updated: 2024/03/01

Alfa Aesar

Product number: B23634
Product name: 3-(Aminomethyl)pyridine, 98+%
Packaging: 25g
Price: $45.2
Updated: 2024/03/01

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3-(Aminomethyl)pyridine Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS TO SLIGHLY YELLOW LIQUID

Uses

It finds its application as a rubefacient.

Application

3-(Aminomethyl)pyridine can be used to prepare metal complexes. A number of complexes of cobalt(II), nickel(II) and copper(II) thiocyanates, chlorides and bromides with 3-pyridine amine were prepared and the stereochemical configurations of these complexes were deduced using spectroscopy and magnetism, and the decomposition of the complexes was studied by thermogravimetry and differential thermal analysis^[2].

Synthesis

Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?. A natural product inspired rapid access of 3-(aminomethyl)pyridine by one-pot reaction of 1-amidopyridin-1-ium salt with aminal followed by reductive cleavage of the N–N bond is developed. This C3-selective formal C–H activation of pyridine features a traceless umpolung of the 1-amidopyridin-1-ium salt toward a Mannich type C–C bond formation of the in situ generated 1-amido-2-dialkylamino-1,2-dihydropyridine intermediate^[1].

References

[1] TANG P, XIAO D, WANG B. Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?[J]. Chemical Communications, 2017. DOI:10.1039/C6CC09582H.
[2] J. R. ALLAN M. J P A D Paton. The preparation, characterisation and thermal analysis studies on complexes of cobalt(II), nickel(II), and copper(II) with 3-picolylamine[J]. Journal of Thermal Analysis and Calorimetry, 1985. DOI:10.1007/BF01913603.

3-(Aminomethyl)pyridine Preparation Products And Raw materials

Raw materials

Lithium Aluminum Hydride 3-Cyanopyridine

Preparation Products

VACOR

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3-(Aminomethyl)pyridine Suppliers

Americas 1 Belgium 2 Canada 3 China 227 Czech Republic 1 Europe 4 France 3 Germany 12 India 27 Ireland 1 Italy 1 Japan 12 Russia 1 Slovakia 1 Switzerland 4 Ukraine 3 United Kingdom 16 United States 55 Global 374

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Alfa Aesar

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TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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View Lastest Price from 3-(Aminomethyl)pyridine manufacturers

Henan Fengda Chemical Co., Ltd

Product: Picolamine 3731-52-0
Price: US $122.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-11

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-(Aminomethyl)pyridine 3731-52-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-10

Zhuozhou Wenxi import and Export Co., Ltd

Product: 3-(Aminomethyl)pyridine 3731-52-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-07-09

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TIMTEC-BB SBB004351

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-(Aminomethyl)pyridine

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3-Pyridinylmethanamine

-Aminomethyl

Pyridine, 3-(aminomethyl)-

3-(AMINOMETHYL)PYRIDINE, 99+%

3-(aminomehtyl)pyridine

(Pyridin-3-yl)methylamine

3-(AMINOMETHYL)PYRIDINE:3-PICOLYLAMINE

pyridin-3-ylmethanamine

3-(AMINOMETHYL)PYRIDINE, 97+%

3-AMINOMETHYL PYRIDINE C-PYRIDIN-3-YL-METHYLAMINE

3-pyridinylmethylammonium

3-(Aminomethyl)pyridine, 99%, for synthesis

3-Picolylamine&gt

3-(Aminomethyl)pyridine 3731-52-0

Picolamin

3731-52-0

C6

Building Blocks

Heterocyclic Building Blocks

Pyridines

AMINE

Building Blocks

C6

Chemical Synthesis

Heterocyclic Building Blocks

Pyridines

Aromatics

Heterocycles

Miscellaneous Reagents

Nitrogen cyclic compounds

Pyridines derivates

Amines