ChemicalBook > CAS DataBase List > 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- Product Name
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- CAS No.
- 39085-59-1
- Chemical Name
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- Synonyms
- TPSH;TRISYLHYDRAZIDE;TPSH, Trisylhydrazide;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE;2,4,6-Triisopropylphenylsulfonyl hydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-Triisopropyl benzenesulphonohydrazine
- CBNumber
- CB5753387
- Molecular Formula
- C15H26N2O2S
- Formula Weight
- 298.44
- MOL File
- 39085-59-1.mol
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Property
- Melting point:
- 110-112 °C (dec.) (lit.)
- Boiling point:
- 396.6±52.0 °C(Predicted)
- Density
- 1.075
- storage temp.
- -20°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- pka
- 9.51±0.10(Predicted)
- form
- Solid
- color
- Off-White
- Sensitive
- Moisture Sensitive
- BRN
- 2145001
- InChIKey
- GBQCDUBJTLROBV-UHFFFAOYSA-N
- CAS DataBase Reference
- 39085-59-1(CAS DataBase Reference)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 192198
- Product name
- 2,4,6-Triisopropylbenzenesulfonyl hydrazide
- Purity
- 90%
- Packaging
- 1g
- Price
- $58.4
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 192198
- Product name
- 2,4,6-Triisopropylbenzenesulfonyl hydrazide
- Purity
- 90%
- Packaging
- 5g
- Price
- $206
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1591
- Product name
- 2,4,6-Triisopropylbenzenesulfonyl Hydrazide
- Purity
- >95.0%(T)
- Packaging
- 5g
- Price
- $154
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1591
- Product name
- 2,4,6-Triisopropylbenzenesulfonyl Hydrazide
- Purity
- >95.0%(T)
- Packaging
- 25g
- Price
- $495
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 017976
- Product name
- 2,4,6-Triisopropylbenzenesulfonyl hydrazide
- Packaging
- 0.5g
- Price
- $40.65
- Updated
- 2024/03/01
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties,Usage,Production
Chemical Properties
White crystal
Uses
As a reagent for generation of diimide
Uses
2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:
- Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
- Vinyl sulfones by sulfonylation reaction of vinyl bromides.
- Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Suppliers
- Tel
- --
- Fax
- --
- brunschwig@brunschwig.nl
- Country
- The Netherlands
- ProdList
- 4996
- Advantage
- 67
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View Lastest Price from 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE manufacturers
Career Henan Chemical Co
- Product
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE 39085-59-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-07-02
39085-59-1, 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDERelated Search:
2,4,6-Trimethylbenzenesulfonyl hydrazide
4-Ethylbenzenesulfonamide
2,4-Dimethylbenzenethiol
1,3,5-Triisopropylbenzene
2,4,6-TRIISOPROPYLBENZENESULFONAMIDE
METHANESULFONYL HYDRAZIDE
2,6-DIMETHYLTHIOPHENOL
Benzenesulfonyl hydrazide
4-Methylbenzenesulfonhydrazide
1,3,5-TRIETHYLBENZENE
2,4,6-TRIMETHYLTHIOPHENOL
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
(4-Isopropyl)thiophenol
2-Methylbenzene-1-sulfonamide
antioxidant 1024
Benzenesulfonamide, 4-(1-methylethyl)- (9CI)
TRIFLUOROACETYLTRIPHENYLSILANE 2,4,6-TRIISOPROPYLBENZENESULFONYLHYDRAZONE
Benzenesulfonamide, 2,4,6-trimethyl- (9CI)