Fentin hydroxide

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Fentin hydroxide

Product Name: Fentin hydroxide
CAS No.: 76-87-9
Chemical Name: Fentin hydroxide
Synonyms: k19;K 19;TPTH;KRT19;duter;TPTOH;Du-Ter;Haitin;fentin;SUZU-H
CBNumber: CB5760970
Molecular Formula: C18H16OSn
Formula Weight: 367.03
MOL File: 76-87-9.mol

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Fentin hydroxide Property

Melting point:: 124-126 °C (lit.)
Boiling point:: 428.5±28.0 °C(Predicted)
Density: 1.54
storage temp.: -20°C
solubility: Slightly soluble in alcohol, toluene
pka: 3.98±0.70(Predicted)
form: Powder
color: Off-white
Water Solubility: <0.1 g/100 mL at 21 ºC
Merck: 14,9745
BRN: 4139186
Exposure limits: ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference: 76-87-9(CAS DataBase Reference)
NIST Chemistry Reference: Stannane, hydroxytriphenyl-(76-87-9)
EPA Substance Registry System: Triphenyltin hydroxide (76-87-9)

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Safety

Hazard Codes: T+,N
Risk Statements: 24/25-26-37/38-40-41-48/23-50/53-63-36/37/38
Safety Statements: 26-28-36/37/39-45-60-61
RIDADR: UN 3146 6.1/PG 2
WGK Germany: 3
RTECS: WH8575000
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29319090
Hazardous Substances Data: 76-87-9(Hazardous Substances Data)
Toxicity: LD50 oral in rat: 46mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H311Toxic in contact with skin

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: SAB4501670
Product name: Anti-Keratin 19 antibody produced in rabbit
Purity: affinity isolated antibody
Packaging: 100μg
Price: $506
Updated: 2024/03/01

Sigma-Aldrich

Product number: HPA002465
Product name: Anti-KRT19 antibody produced in rabbit
Purity: Prestige Antibodies? Powered by Atlas Antibodies, affinity isolated antibody, buffered aqueous glycerol solution
Packaging: 100μL
Price: $514
Updated: 2024/03/01

Sigma-Aldrich

Product number: 45493
Product name: Fentin hydroxide
Purity: PESTANAL
Packaging: 250mg
Price: $68.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 348104
Product name: Triphenyltin hydroxide
Packaging: 25g
Price: $26.28
Updated: 2024/03/01

Sigma-Aldrich

Product number: HPA002465
Product name: Anti-KRT19 antibody produced in rabbit
Purity: Prestige Antibodies? Powered by Atlas Antibodies, affinity isolated antibody, buffered aqueous glycerol solution
Packaging: 25μL
Price: $282
Updated: 2023/06/20

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Fentin hydroxide Chemical Properties,Usage,Production

Chemical Properties

White to Off-White Solid. Insoluble in water; soluble in ether, benzene, and alcohol.

Uses

Reactant involved in transmetalation reactions with Ir clusters. Reactant involved in synthesis of (E)-(Nitrophenyl)propenoic acid organotin(IV) carboxylates with antitumor activity, triorganotin chrysanthemumates for larvicidal studies, polynuclear organotin(IV) carboxylates containing ferrocenyl moieties for antitumor investigation, organotin(IV) aminophenylacrylate complexes, 4-Biphenylcarboxylic acid derivatives for in vitro cytotoxicity studies.

Uses

Triphenyltin Hydroxide is an organotin compound. Triphenyltin Hydroxide is used as a fungicide and antifeeding compound for insect control. Recent studies show that Triphenyltin Hydroxide may have adv erse effects on the reproductive and immune systems and may disrupt the endocrine system.

Definition

ChEBI: An organotin compound that is triphenylstannane in which the hydrogen attached to tin is replaced by a hydroxy group. A fungicide used to control a variety of infections including blight on potatoes, leaf spot on sugar beet and alternaria blight on carrots

General Description

Odorless white powder. Stable at room temperature. Melting point 121-123°C. Moderately soluble in most organic solvents (Farm Chemical Handbook). Insoluble in water. Non corrosive. Used as a fungicide.

Reactivity Profile

Fentin hydroxide is sensitive to temperatures above 113°F and prolonged exposure to light. Incompatible with strongly acidic compounds. Also incompatible with oils used in oil spray formulations .

Fire Hazard

Flash point data for Fentin hydroxide are not available; however, Fentin hydroxide is probably combustible.

Biochem/physiol Actions

Keratin 19 (KRT19) is a type I cytokeratin involved in the formation of intermediate filaments in other cells. It is also involved in the myofiber organization. It is localized at the costameres of striated muscle. KRT19 serves as a connector between contractile apparatus and dystrophin at the costamere of striated muscle. It has been postulated that KRT19 can bind directly with the N-terminal actin-binding domain of dystrophin, neurofilaments, vimentin and plectin. It also functions as a biomarker for the diagnosis of endometriosis.

Purification Methods

West, Baney and Powell [J Am Chem Soc 82 6269 1960] purified a sample which was grossly contaminated with tetraphenyltin and diphenyltin oxide by dissolving it in EtOH, most of the impurities remaining behind as an insoluble residue. Evaporation of the EtOH extract gave the crude hydroxide which was converted to triphenyltin chloride (above) by grinding in a mortar under 12M HCl, then evaporating the acidic solution. The chloride, after crystallisation from EtOH, had m 104-105o. It was dissolved in Et2O and converted to the hydroxide by stirring with excess aqueous ammonia. The ether layer was separated, dried, and evaporated to give triphenyltin hydroxide which, after crystallisation from EtOH (or MeCN) and drying under vacuum, was in the form of white crystals (m 119-120o), which retained some cloudiness in the melt above 120o. The hydroxide retains water (0.1-0.5 moles of water per mole) tenaciously. [Glidewell & Liles Acta Cryst (B) 34 129 1978, Beilstein 16 H 914, 16 I 540, 16 II 625, 16 III 1240, 16 IV 1606.]

Fentin hydroxide Preparation Products And Raw materials

Raw materials

Preparation Products

Triphenyltin acetate

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Fentin hydroxide Suppliers

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View Lastest Price from Fentin hydroxide manufacturers

Career Henan Chemical Co

Product: Fentin hydroxide 76-87-9
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-24

76-87-9, Fentin hydroxideRelated Search:

Stannic oxide TRIPHENYLTIN HYDRIDE Triphenyltin acetate Sodium hydroxide Aluminum hydroxide TRIPHENYLBORANE Triphenylphosphine oxide Lactulose (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE Triphenylphosphine Ammonium hydroxide Triphenylantimony Triphenylmethyl Chloride VANADIUM(III) ACETYLACETONATE Dibutyltin oxide BIS(TRIPHENYLTIN) OXIDE ACRYLOXYTRIPHENYLTIN triphenyltin 3,5-diisopropylsalicylate

BRESTAN FLOW

FENTIN HYDROXIDE

Hydroxytriphenylstannane

DU-TER(R)

Keratin type I cytoskeletal 19

KRT19

triphenylstannanylium:hydroxide

Fentin Hydroxide Solution, 1000ppm

Fentin-hydr

Ashlade flotin

brestanh47.5wpfungicide.

Dowco 186

dowco186

duter

Du-Ter

Duter extra

Du-Ter W-50

fentinhydroxide(BSI,ISO-E),fentinhydroxide(ISO-E)triphenyltinhydroxide,(US.,SO,Africa)

fentinhydroxide(tpth)

Fintin hydroxid

Fintin hydroxyde

Fintin idrossido

Fintine hydroxyde

fintinehydroxide(french)

fintinehydroxyde

fintinehydroxyde(french)

fintinhydroxid

fintinhydroxyde

fintinidrossido

Flo-tin 4L

flotin4l

flo-tin4l

Haitin

haitinwp20(fentinhydroxide20%)

haitinwp60(fentinhydroxide60%)

Hydroxyde de triphenyl-etain

hydroxydedetriphenyl-etain

hydroxydedetriphenyl-etain(french)

hydroxytriphenyl-stannan

hydroxytriphenyl-ti

Hydroxytriphenyltin

ida,imcflo-tin4l.

Idrossido di stagno trifenile

idrossidodistagnotrifenile

K 19

k19

NCI-C00260

OMS 1017

triphenyltinoxide

Triphenyl-zinnhydroxid

Triphenytin hydroxide

tripletin4l

Vancide ks

vancideks

vitospotfungicide.

wesleytechnicaltriphenyltinhydroxide.

du-terfungicide.

du-terfungicidewettablepowder.