5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER

Product Name: 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER
CAS No.: 886365-06-6
Chemical Name: 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER
Synonyms: Methyl 5-broMo-4-Methylpicolinate;methyl 4-methyl-5-bromopyridinecarboxylate;Methyl 5-broMo-4-Methylpyridine-2-carboxylate;5-BroMo-4-Methyl-Pyridine-2-Carboxylicycid Methylester;5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER;2-Pyridinecarboxylic acid, 5-bromo-4-methyl-, methyl ester;5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER ISO 9001：2015 REACH
CBNumber: CB5794003
Molecular Formula: C8H8BrNO2
Formula Weight: 230.06
MOL File: Mol file

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5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Property

Boiling point:: 319.8±37.0 °C(Predicted)
Density: 1.503±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
pka: 0.16±0.10(Predicted)
Appearance: White to light yellow Solid

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H303May be harmfulif swallowed

H320Causes eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC

Product number: B697590
Product name: 5-Bromo-4-methyl-pyridine-2-carboxylicacidmethylester
Packaging: 50mg
Price: $65
Updated: 2021/12/16

Matrix Scientific

Product number: 074454
Product name: Methyl 5-bromo-4-methylpicolinate
Purity: 95+%
Packaging: 250mg
Price: $300
Updated: 2021/12/16

AK Scientific

Product number: J51195
Product name: Methyl5-bromo-4-methylpicolinate
Packaging: 1g
Price: $189
Updated: 2021/12/16

Matrix Scientific

Product number: 074454
Product name: Methyl 5-bromo-4-methylpicolinate
Purity: 95+%
Packaging: 1g
Price: $730
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0142732
Product name: 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLICACID METHYL ESTER
Purity: 95.00%
Packaging: 250MG
Price: $1034.88
Updated: 2021/12/16

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5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

67-56-1

886365-02-2

886365-06-6

To a solution of 5-bromo-4-methylpyridine-2-carboxylic acid (650 mg, 3.0 mmol) in methanol (2 mL) was added concentrated sulfuric acid (catalytic amount). The reaction mixture was heated to reflux for 14 hours. After completion of the reaction, the mixture was cooled to 0 °C and neutralized with saturated sodium bicarbonate solution to pH 7-8. The insoluble material was removed by filtration and the filtrate was concentrated under reduced pressure to remove the solvent. The crude product was purified by silica gel column chromatography using a suitable eluent (e.g. petroleum ether/ethyl acetate gradient elution) to afford methyl 5-bromo-4-methylpyridine-2-carboxylate (340 mg, 49% yield) as a white solid.

References

[1] Patent: US2011/71150, 2011, A1. Location in patent: Page/Page column 34
[2] Patent: US2013/158040, 2013, A1. Location in patent: Paragraph 0135
[3] Patent: US2013/158049, 2013, A1. Location in patent: Paragraph 0169
[4] Patent: US2013/158066, 2013, A1. Location in patent: Paragraph 0135

5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Suppliers

China 81 India 2 United States 6 Global 89

Pure Chemistry Scientific Inc.

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View Lastest Price from 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co

Product: 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER 886365-06-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-05-25

886365-06-6, 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTERRelated Search:

5-BROMO-4-METHYL-PYRIDINE-2-CARBONITRILE 5-broMo-4-chlorothiophene-2-carboxylic acid 5-bromo-4-trifluoromethyl-thiazole-2-ylamine 5-BroMo-4-MethoxypyriMidine 5-Bromo-4-methyl-1H-pyrrolo[2,3-b]pyridine 5-BroMo-4-chloro-6-MethoxypyriMidine 5-BROMO-4-CHLORO-6-METHYLPYRIMIDINE 5-bromo-4-chloro-2-methylpyrimidine 5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID 5-bromo-4-methylthiazole 5-Bromo-4,7-diazaindole 4-METHYL-PYRIDINE-2-CARBOXYLIC ACID

5-BroMo-4-Methyl-Pyridine-2-Carboxylicycid Methylester

Methyl 5-broMo-4-Methylpyridine-2-carboxylate

Methyl 5-broMo-4-Methylpicolinate

5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER

methyl 4-methyl-5-bromopyridinecarboxylate

2-Pyridinecarboxylic acid, 5-bromo-4-methyl-, methyl ester

5-BROMO-4-METHYL-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER ISO 9001：2015 REACH

886365-06-6

Heterocycle-Pyridine series