ChemicalBook > CAS DataBase List > 1-BROMO-2,4,6-TRIMETHOXYBENZENE

1-BROMO-2,4,6-TRIMETHOXYBENZENE

Product Name
1-BROMO-2,4,6-TRIMETHOXYBENZENE
CAS No.
1131-40-4
Chemical Name
1-BROMO-2,4,6-TRIMETHOXYBENZENE
Synonyms
RARECHEM AH CK 0052;2,4,6-TRIMETHOXYBROMOBENZENE;BROMO-2,4,6-TRIMETHOXYBENZENE;2,4,6-Trimethoxyphenyl bromide;2-BROMO-1,3,5-TRIMETHOXYBENZENE;1-BROMO-2,4,6-TRIMETHOXYBENZENE;Benzene, 2-bromo-1,3,5-trimethoxy-;2-Bromo-1,3,5-trimethoxybenzene 98%;1-Bromo-2,4,6-trimethoxybenzene 98%;N-methylcarbamic acid [(5-methyl-1,3-benzoxazol-2-yl)-(2-methylphenyl)methyl] ester
CBNumber
CB6117225
Molecular Formula
C9H11BrO3
Formula Weight
247.09
MOL File
1131-40-4.mol
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1-BROMO-2,4,6-TRIMETHOXYBENZENE Property

Melting point:
97-99°C
Boiling point:
303.5±37.0 °C(Predicted)
Density 
1.391±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
solid
color 
White
InChI
InChI=1S/C9H11BrO3/c1-11-6-4-7(12-2)9(10)8(5-6)13-3/h4-5H,1-3H3
InChIKey
BPWYNWSOQOXOPI-UHFFFAOYSA-N
SMILES
C1(OC)=CC(OC)=CC(OC)=C1Br
CAS DataBase Reference
1131-40-4(CAS DataBase Reference)
EPA Substance Registry System
2-Bromo-1,3,5-trimethoxybenzene (1131-40-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22
Safety Statements 
22-36/37/39
Hazard Note 
Irritant
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B6448
Product name
2-Bromo-1,3,5-trimethoxybenzene
Purity
min. 98.0 %
Packaging
1G
Price
$57
Updated
2025/07/31
TCI Chemical
Product number
B6448
Product name
2-Bromo-1,3,5-trimethoxybenzene
Purity
min. 98.0 %
Packaging
5G
Price
$171
Updated
2025/07/31
AK Scientific
Product number
2200BA
Product name
2-Bromo-1,3,5-trimethoxybenzene
Packaging
10g
Price
$185
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB68031
Product name
1-Bromo-2,4,6-trimethoxybenzene
Packaging
25g
Price
$200
Updated
2021/12/16
Matrix Scientific
Product number
126932
Product name
2-Bromo-1,3,5-trimethoxybenzene
Purity
>95%
Packaging
5g
Price
$252
Updated
2021/12/16
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1-BROMO-2,4,6-TRIMETHOXYBENZENE Chemical Properties,Usage,Production

Synthesis

570-02-5

1131-40-4

General procedure for the synthesis of 1-bromo-2,4,6-trimethoxybenzene from 2,4,6-trimethoxybenzoic acid: a mixture of 2,4,6-trimethoxybenzoic acid (1 eq., 0.5 mmol), CuBr2 or CuCl2 (2 eq., 1 mmol), Ag2CO3 (1 eq., 0.5 mmol), and PdCl2 (0.1 eq.) was dissolved in THF (3 mL) and the reaction was refluxed at 110 °C for 24 hours. Upon completion of the reaction, the reaction mixture was concentrated under reduced pressure and purified by column chromatography to afford the target product 1-bromo-2,4,6-trimethoxybenzene.

References

[1] Tetrahedron Letters, 2013, vol. 54, # 24, p. 3079 - 3081
[2] Journal of Organic Chemistry, 2016, vol. 81, # 7, p. 2794 - 2803

1-BROMO-2,4,6-TRIMETHOXYBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-2,4,6-TRIMETHOXYBENZENE Suppliers

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View Lastest Price from 1-BROMO-2,4,6-TRIMETHOXYBENZENE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
1-BROMO-2,4,6-TRIMETHOXYBENZENE 1131-40-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
5000KG
Release date
2024-07-18
Shaanxi Dideu Medichem Co. Ltd
Product
1-BROMO-2,4,6-TRIMETHOXYBENZENE 1131-40-4
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10
Release date
2024-07-14

1131-40-4, 1-BROMO-2,4,6-TRIMETHOXYBENZENERelated Search:

1-Bromo-3,4,5-trimethoxybenzene 2-BROMO-5-METHOXYPHENOL 2-Bromoanisole 4-Bromoresorcinol 4-Bromo-3-methoxyphenol 2-Bromoresorcinol 1-BROMO-2,6-DIMETHOXYBENZENE 1-Bromo-2,4-dimethoxybenzene 8-BROMO-5,7-DIMETHOXY-2-METHYLCHROMANE 8-BROMO-5,7-DIMETHOXY-CHROMEN-2-ONE 2-BROMO-3-METHOXYPHENOL 1-BROMO-2,4,6-TRIMETHOXYBENZENE

  • RARECHEM AH CK 0052
  • 1-BROMO-2,4,6-TRIMETHOXYBENZENE
  • 2-BROMO-1,3,5-TRIMETHOXYBENZENE
  • 2,4,6-TRIMETHOXYBROMOBENZENE
  • BROMO-2,4,6-TRIMETHOXYBENZENE
  • 1-Bromo-2,4,6-trimethoxybenzene 98%
  • 2,4,6-Trimethoxyphenyl bromide
  • 2-Bromo-1,3,5-trimethoxybenzene 98%
  • N-methylcarbamic acid [(5-methyl-1,3-benzoxazol-2-yl)-(2-methylphenyl)methyl] ester
  • Benzene, 2-bromo-1,3,5-trimethoxy-
  • 1131-40-4
  • Aromatic Ethers