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Hexamethylphosphorous triamide

Product Name
Hexamethylphosphorous triamide
CAS No.
1608-26-0
Chemical Name
Hexamethylphosphorous triamide
Synonyms
HMPT;TRIS(DIMETHYLAMINO)PHOSPHINE;Hexamethylphosphorous;(Me2N)3P;Tri(dimethylamino)phosphine;HEXAMETHYL PHOSPHORUS TRIAMIDE;Hexamethylphosphorous triamide ,98%;[bis(dimethylamino)phosphanyl]dimethylamine;NSC 102707;((CH3)2N)3P
CBNumber
CB6140896
Molecular Formula
C6H18N3P
Formula Weight
163.2
MOL File
1608-26-0.mol
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Hexamethylphosphorous triamide Property

Melting point:
-44 °C
Boiling point:
48-50 °C/12 mmHg (lit.)
Density 
0.898 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.463(lit.)
Flash point:
73 °F
storage temp. 
Inert atmosphere,2-8°C
form 
Liquid
pka
8.03±0.70(Predicted)
Specific Gravity
0.8980
color 
Clear colorless to slightly yellow
Water Solubility 
REACTS
Sensitive 
Moisture Sensitive
BRN 
906778
Stability:
Stable. Highly flammable - note low flash point. Incompatible with oxidizing agents.
InChIKey
XVDBWWRIXBMVJV-UHFFFAOYSA-N
CAS DataBase Reference
1608-26-0(CAS DataBase Reference)
NIST Chemistry Reference
Phosphorous triamide, hexamethyl-(1608-26-0)
EPA Substance Registry System
Phosphorous triamide, hexamethyl- (1608-26-0)
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Safety

Hazard Codes 
T,Xi,Xn,F
Risk Statements 
45-46-10-40-36/37/38
Safety Statements 
53-45-36/37/39-26-16-37/39-36
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
RTECS 
TH3390000
10
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29299000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H340May cause genetic defects

H350May cause cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
393290
Product name
Tris(dimethylamino)phosphine
Purity
97%
Packaging
5ml
Price
$70.4
Updated
2024/03/01
Sigma-Aldrich
Product number
393290
Product name
Tris(dimethylamino)phosphine
Purity
97%
Packaging
25ml
Price
$288
Updated
2024/03/01
TCI Chemical
Product number
T1317
Product name
Tris(dimethylamino)phosphine (may contain precipitate)
Purity
>96.0%(GC)
Packaging
25mL
Price
$302
Updated
2024/03/01
TCI Chemical
Product number
T1317
Product name
Tris(dimethylamino)phosphine (may contain precipitate)
Purity
>96.0%(GC)
Packaging
250mL
Price
$1721
Updated
2024/03/01
Alfa Aesar
Product number
A12571
Product name
Hexamethylphosphorous triamide, 97%
Packaging
5g
Price
$52.65
Updated
2024/03/01
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Hexamethylphosphorous triamide Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Hexamethylphosphorous triamide can be combination with CCl4 for the conversion of hydroxyl groups to the corresponding chlorides; hydroxyl group activation; dehydrations.

Uses

Hexamethylphosphorous triamide can be uesd in suzuki reaction.

Uses

Hexamethylphosphorous triamide can be widely used in industry, with applications such as being a flame retardant for building materials to a phosphorylating agent in synthetic chemistry. It is a classified carcinogen.

Purification Methods

It may contain more than 1% of phosphoric triamide. The yellow oil is first distilled at atmospheric pressure, then under reduced pressure and stored under N2. It is air sensitive, TOXIC, and should not be inhaled. It is absorbed through the skin. [Mark Org Synth Coll Vol V 602 1973, Beilstein 4 IV 274.]

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Hexamethylphosphorous triamide Suppliers

Buchem B.V./ Arc Technologies
Tel
--
Fax
--
Email
info@buchem.com
Country
The Netherlands
ProdList
76
Advantage
58
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View Lastest Price from Hexamethylphosphorous triamide manufacturers

R&D Scientific Inc.
Product
Tris(dimethylamino)phosphine 1608-26-0
Price
US $3600.00/Kg
Min. Order
1Kg
Purity
98
Supply Ability
500 Kg
Release date
2024-07-11
XINXIANG RUNYU MATERIAL CO., LTD.
Product
Hexamethylphosphorous triamide 1608-26-0
Price
US $0.00-0.00/g
Min. Order
100g
Purity
98%
Supply Ability
25KG
Release date
2024-03-26
XINGTAI XINGJIU NEW MATERIAL TECHNOLOGY CO., LTD
Product
Hexamethylphosphorous triamide 1608-26-0
Price
US $25.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
50000kg/month
Release date
2022-01-24

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  • organophosphorus ligand
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