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Crotonic acid

Product Name
Crotonic acid
CAS No.
107-93-7
Chemical Name
Crotonic acid
Synonyms
(E)-But-2-enoic acid;Crotonate;BUT-2-ENOIC ACID;2-Butenoic acid, (E)-;BUTENOIC ACID;(E)-2-BUTENOIC ACID;TRANS-CROTONIC ACID;NSC 8751;(e)-2-butenoicaci;(2E)-2-Butenoic acid
CBNumber
CB6145402
Molecular Formula
C4H6O2
Formula Weight
86.09
MOL File
107-93-7.mol
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Crotonic acid Property

Melting point:
70-72 °C (lit.)
Boiling point:
180-181 °C (lit.)
Density 
1.027 g/mL at 25 °C (lit.)
vapor density 
2.97 (vs air)
vapor pressure 
0.19 mm Hg ( 20 °C)
refractive index 
1.4228
FEMA 
3908 | (E)-2-BUTENOIC ACID
Flash point:
190 °F
storage temp. 
Store below +30°C.
solubility 
H2O: soluble
pka
4.69(at 25℃)
form 
Crystalline Flakes
color 
White to light yellow
PH
3 (10g/l, H2O, 20℃)
Odor
at 1.00 %. milky
Odor Type
milky
explosive limit
15.1%, 171°F
Water Solubility 
94 g/L (25 ºC)
Merck 
14,2597
JECFA Number
1371
BRN 
1719943
InChIKey
LDHQCZJRKDOVOX-NSCUHMNNSA-N
LogP
0.85 at 25℃
CAS DataBase Reference
107-93-7(CAS DataBase Reference)
NIST Chemistry Reference
Crotonic acid(107-93-7)
EPA Substance Registry System
2-Butenoic acid, (2E)- (107-93-7)
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Safety

Hazard Codes 
C,N,Xi
Risk Statements 
21/22-34-50/53-36/37/38
Safety Statements 
26-36/37/39-45-61-37/39
RIDADR 
UN 2823 8/PG 3
WGK Germany 
3
RTECS 
GQ2900000
Autoignition Temperature
744 °F
HazardClass 
8
PackingGroup 
III
HS Code 
29161940
Toxicity
LD50 orally in rats: 1.0 g/kg (Smyth, Carpenter)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
113018
Product name
Crotonic acid
Purity
98%
Packaging
500g
Price
$57.8
Updated
2024/03/01
Sigma-Aldrich
Product number
113018
Product name
Crotonic acid
Purity
98%
Packaging
3kg
Price
$309
Updated
2024/03/01
TCI Chemical
Product number
C0416
Product name
Crotonic Acid
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$51
Updated
2024/03/01
TCI Chemical
Product number
C0416
Product name
Crotonic Acid
Purity
>98.0%(GC)(T)
Packaging
100g
Price
$116
Updated
2024/03/01
Alfa Aesar
Product number
A15765
Product name
trans-Crotonic acid
Purity
98%
Packaging
25g
Price
$21.8
Updated
2024/03/01
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Crotonic acid Chemical Properties,Usage,Production

Chemical Properties

White to light yellow crystalline flakes

Chemical Properties

2-Butenoic acid is a crystalline compound with a pungent odor.

Uses

trans-Crotonic acid is used in the copolymerization of crotonic acid hydrogel systems by using gamma-rays. The crosslinked copolymeric crotonic acid hydrogels release fertilizers and drugs that help to prevent environmental pollution.

Definition

ChEBI: Crotonic acid is a but-2-enoic acid with a trans- double bond at C-2. It has been isolated from Daucus carota. It has a role as a plant metabolite. It is a conjugate acid of a crotonate.

Preparation

(E)-2-Butenoic acid may be formed by oxidation of crotonaldehyde, 2-butenal. If (Z)-butenoic acid is heated at 180°C, it is converted to (E)-2-butenoid acid.

General Description

Crotonic acid undergoes esterification with butan-2-ol by following second order reaction kinetics.

Flammability and Explosibility

Not classified

storage

Store at RT

Purification Methods

Distil the acid under reduced pressure and/or recrystallise it from pet ether (b 60-80o) or water, or by partial freezing of the melt. [Beilstein 2 IV 1498.]

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Crotonic acid Suppliers

Yangzhou juhechang Technology Co., Ltd
Tel
0514-0514-83662002 13073488988
Fax
0514-83662002
Email
13073488988@163.com
Country
China
ProdList
37
Advantage
58
Hefei Qianhang Pharmaceutical Technology Co., Ltd.
Tel
13346199520
Email
1356223173@qq.com
Country
China
ProdList
61
Advantage
58
Kono Chem Co.,Ltd
Tel
15829389671
Fax
029-86107037
Email
info@konochemical.com
Country
China
ProdList
554
Advantage
55
Shanghai Rong Tang Polymer Material Co. , Ltd.
Tel
18701991744
Email
18701991744@163.com
Country
China
ProdList
62
Advantage
58
Qingdao Baiyi Chemical Co., Ltd
Tel
13053388919
Email
1454485610@qq.com
Country
China
ProdList
410
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
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View Lastest Price from Crotonic acid manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Crotonic acid 107-93-7
Price
US $40.00-40.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-08
Hebei Guanlang Biotechnology Co., Ltd.
Product
Crotonic acid 107-93-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-08-09
Henan Aochuang Chemical Co.,Ltd.
Product
Crotonic acid 107-93-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-30

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