ChemicalBook > CAS DataBase List > 4-Amino-2,6-dichloropyridine

4-Amino-2,6-dichloropyridine

Product Name
4-Amino-2,6-dichloropyridine
CAS No.
2587-02-2
Chemical Name
4-Amino-2,6-dichloropyridine
Synonyms
2,6-DICHLOROPYRIDIN-4-AMINE;2,6-DICHLORO-PYRIDIN-4-YLAMINE;2,6-dichloro-4-pyridinamine;2,6-DICHLORO-4-AMINOPYRIDINE;0/2/87;NSC 136573;AURORA KA-3022;4-Amino-2,6-dichL;6-Dichloro-4-pyridinamine;4-Ami-2,6-dichloropyridine
CBNumber
CB6151104
Molecular Formula
C5H4Cl2N2
Formula Weight
163
MOL File
2587-02-2.mol
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4-Amino-2,6-dichloropyridine Property

Melting point:
169-173 °C (lit.)
Boiling point:
336.7±37.0 °C(Predicted)
Density 
1.497±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
pka
0.49±0.50(Predicted)
color 
White to buff
BRN 
114351
InChI
InChI=1S/C5H4Cl2N2/c6-4-1-3(8)2-5(7)9-4/h1-2H,(H2,8,9)
InChIKey
WAEZOSSWRXDWAX-UHFFFAOYSA-N
SMILES
C1(Cl)=NC(Cl)=CC(N)=C1
CAS DataBase Reference
2587-02-2(CAS DataBase Reference)
NIST Chemistry Reference
Pyridine, 4-amino-2,6-dichloro-(2587-02-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29333990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
565342
Product name
4-Amino-2,6-dichloropyridine
Purity
97%
Packaging
5g
Price
$65.4
Updated
2025/07/31
TCI Chemical
Product number
A2369
Product name
4-Amino-2,6-dichloropyridine
Purity
>97.0%(GC)(N)
Packaging
1g
Price
$40
Updated
2025/07/31
TCI Chemical
Product number
A2369
Product name
4-Amino-2,6-dichloropyridine
Purity
>97.0%(GC)(N)
Packaging
5g
Price
$122
Updated
2025/07/31
TRC
Product number
A604710
Product name
4-Amino-2,6-dichloropyridine
Packaging
5g
Price
$60
Updated
2021/12/16
TRC
Product number
A604710
Product name
4-Amino-2,6-dichloropyridine
Packaging
10g
Price
$95
Updated
2021/12/16
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4-Amino-2,6-dichloropyridine Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

4-Amino-2,6-dichloropyridine is a compound useful in organic synthesis used in the synthesis of Rho kinase inhibitors.

Synthesis

25194-01-8

2587-02-2

The general procedure for the synthesis of 4-amino-2,6-dichloropyridine from 2,6-dichloro-4-nitropyridine was as follows: to a solution of 2,6-dichloro-4-nitropyridine (14.82 g, 76.79 mmol) in ethanol (350 mL) was added sequentially iron powder (19.91 g, 356.58 mmol), water (65.8 mL, 3.6 mol), and concentrated hydrochloric acid (14.1 mL, 464.1 mmol). The reaction was carried out at 95 °C with stirring for 16 hours. After completion of the reaction, the reaction solution was cooled to room temperature and the pH was adjusted to neutral. After filtration, the filtrate was concentrated and extracted with ethyl acetate. The organic phases were combined, dried with anhydrous magnesium sulfate, and the solvent was removed by rotary evaporation to afford 11.9 g of the title product 4-amino-2,6-dichloropyridine in 95.1% yield.

References

[1] Patent: US2012/289497, 2012, A1. Location in patent: Page/Page column 51-52
[2] Patent: EP2524917, 2012, A1. Location in patent: Page/Page column 58-59
[3] Bioorganic and Medicinal Chemistry, 2008, vol. 16, # 3, p. 1511 - 1530
[4] Nucleosides, Nucleotides and Nucleic Acids, 2003, vol. 22, # 12, p. 2133 - 2144
[5] ChemCatChem, 2016, vol. 8, # 8, p. 1485 - 1489

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4-Amino-2,6-dichloropyridine Suppliers

LEWOO PHARMATECH (SHANGHAI) CO.,LTD
Tel
15800805830
Fax
021 67898603
Email
miao@lewoopharma.com.cn
Country
China
ProdList
931
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58
Wuxi Kehua Biological Technology Co., Ltd.
Tel
0510-86838766 13636419861
Email
2258830676@qq.com
Country
China
ProdList
5044
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58
Aikon International Limited
Tel
025-58851090 15955137747
Fax
(6)02557626880
Email
sales01@aikonchem.com
Country
China
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15949
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Shanghai Taijilin Industrial Co., Ltd.
Tel
021-50630626 18964684208
Fax
021-50563898
Email
kate@tajilin.com
Country
China
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Record Tech (Shanghai) Co., LTD
Tel
13761627472
Fax
86-21-64965863
Email
183009664@qq.com
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China
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Tongchuang Pharma(Suzhou). Co., Ltd.
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0512-63263366 18912765016
Fax
0512-6326 3366
Email
tongtf110@sina.com
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China
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993
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Fengcheng Meditech (Tianjin)Co., Ltd
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022-59002498-8008; 15122574756
Email
info@fcmeditech.com
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China
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Deyang haijungang Technology Co., Ltd
Tel
15883665058
Email
dyhjgkj@126.com
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China
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553
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SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166 15883665058
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
918
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J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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View Lastest Price from 4-Amino-2,6-dichloropyridine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Amino-2,6-dichloropyridine 2587-02-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-19
Shaanxi Dideu New Materials Co. Ltd
Product
4-Amino-2,6-dichloropyridine 2587-02-2
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-03-01
R&D Scientific Inc.
Product
2,6-Dichloropyridin-4-amine 2587-02-2
Price
US $2100.00/Kg
Min. Order
1Kg
Purity
98
Supply Ability
500 Kg
Release date
2024-04-11

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