1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

Reaction

Product Name: 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
CAS No.: 29964-62-3
Chemical Name: 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyms: PDCI2(DPPB);PdCl2(dppb);adium(II) DichL;[1,4-Bis(diphenyL;phosphino)butane]paL;Palladium(ii) chloride 1,4-b;[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2;Bisdiphenylphosphinobutanepalladiumdichloride;[1,4-bis(diphenylphosphino)butane] palladium(II);4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
CBNumber: CB6185262
Molecular Formula: C28H28P2.Cl2Pd
Formula Weight: 603.8
MOL File: 29964-62-3.mol

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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Property

Melting point:: 285-305 °C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Soluble in ethanol, benzene, and ethereal solvents.
form: Powder
color: light-yellow
InChIKey: JQXJBXVWVPVTOO-UHFFFAOYSA-L

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38
Safety Statements: 24/25-36-27
WGK Germany: 3
F: 1-10
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2031
Product name: [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride
Purity: >96.0%(T)
Packaging: 1g
Price: $125
Updated: 2024/03/01

TCI Chemical

Product number: B2031
Product name: [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride
Purity: >96.0%(T)
Packaging: 5g
Price: $401
Updated: 2024/03/01

Alfa Aesar

Product number: 044971
Product name: Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
Packaging: 1g
Price: $197
Updated: 2024/03/01

Alfa Aesar

Product number: 044971
Product name: Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
Packaging: 5g
Price: $709.65
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0468
Product name: Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II), 99%
Packaging: 1g
Price: $120
Updated: 2024/03/01

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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemical Properties,Usage,Production

Reaction

Catalyst for the Grignard coupling for regioand stereoselective monoalkylation and arylation of 1,1-dichloro-1-alkenes
Synthetic pyrethriods: catalyst for the Negishi coupling of (2,2-dihaloethenyl)cyclopropanecarboxylates

Chemical Properties

yellow solid

Uses

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

Preparation

Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) (1,4-Bis(diphenylphosphino)butane-palladium(II) chloride) can be prepared conveniently in situ by mixing the bidentate phosphine ligand and (PhCN)2PdCl2 in either benzene or chloroform.^[1] The preparation of (dppb)PdCl2 is also possible through the reaction of PdCl2 with dppb in acetone, a process that slowly forms the catalyst as a white precipitate which can be isolated in 51% yield.^[2] Preparation of the hydrate complex is possible via the reaction of Na2[PdCl4] with dppb in a mixture of CH2Cl2 and water.

References

1. Sugi, Y.; Bando, K.-I. CL 1976, 727.
2. Sanger, A. R. JCS(D) 1977, 1971.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Suppliers

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View Lastest Price from 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride manufacturers

Wuhan LPBchem Technology Co.,Ltd

Product: Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) 29964-62-3
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-12-01

Longyan Tianhua Biological Technology Co., Ltd

Product: 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride 29964-62-3
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride 29964-62-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100
Release date: 2019-06-28

29964-62-3, 1,4-Bis(diphenylphosphino)butane-palladium(II) chlorideRelated Search:

Sodium chloride Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, Diphenylphosphine Chlorodiphenylphosphine tert-Butylchlorodiphenylsilane Palladium Palladium chloride N-(Carboxymethyl)-N-(phosphonomethyl)-glycine Methylene Chloride 1,4-Bis(diphenylphosphino)butane (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE Phenyl phosphine N-BUTANE DICHLOROBIS(METHYLDIPHENYLPHOSPHINE)PALLADIUM(II) 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride CIS-DICHLOROBIS(DIMETHYLPHENYLPHOSPHINE)PALLADIUM(II) 2-[[(2-ethylphenyl)(2-hydroxyethyl)amino]methyl]-3,3-difluoro-Propanenitrile

Palladium(ii) chloride 1,4-b

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%

Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%

1,4-Butylenebis(diphenylphosphine)-palladium dichloride

Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%

4-Bis(diphenylphosphino)butane-palladiuM(II) chloride

PDCI2(DPPB)

1,4- double(twophenyl phosphinebutane)twopalladiuM chloride

[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2

1,4-bis (diphenylphosphino butane) palladiuM dichloride

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II)

[1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride

[1,4-Bis(diphenylphosphino) butane]dichloropalladium(II)

PdCl2(dppb) / dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane

4-diphenylphosphiniumylbutyl(diphenyl)phosphonium

PdCl2(dppb)

dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane

DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II)

1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II) CHLORIDE

1,4-BIS(DIPHENYLPHOSPHINO)BUTANE-PALLADIUM(II) CHLORIDE

[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II) DICHLORIDE

PALLADIUM(II) CHLORIDE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE COMPLEX

Bisdiphenylphosphinobutanepalladiumdichloride

PDCL2(DPPB)/ 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II)CHLORIDE

Palladium(II)chloride-1,4-bis(diphenylphosphine)butane

Dichloro 1,4-bis(diphenylphosphino)butane palladium (II) For use in coupling reactions

Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II),PdCl2(DPPB)

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)

[1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride &gt

[1,4-Bis(diphenylphosphino)butane]dichloropalladium(Ⅱ)

[1,4-bis(diphenylphosphino)butane] palladium(II)

[1,4-Bis(diphenyL

adium(II) DichL

phosphino)butane]paL

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride ISO 9001：2015 REACH

TIANFU-CHEM --1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

ichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane

29964-62-3

C28H28Cl2P2Pd

C28H28Cl2P2Pd2

C28H28P2Cl2Pd

Homogeneous Pd Catalysts

Catalysis and Inorganic Chemistry

Homogeneous Catalysts

Pd (Palladium) Compounds

Metal Complexes

Classes of Metal Compounds

Catalysts for Organic Synthesis

Transition Metal Compounds

Pd (Palladium) Compounds

Synthetic Organic Chemistry

Transition Metal Compounds

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Metal Complexes

Metal Compounds