6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
- Product Name
- 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
- CAS No.
- 69950-65-8
- Chemical Name
- 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER
- Synonyms
- Methyl 6-formylpicolinate;6-formyl-2-pyridinecarboxylate;Methyl 6-formyl-2-pyridinecarboxylate;Methyl 6-formylpyridine-2-carboxylate;Methyl 6-formylpyridine-2-carboxylate 96%;6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER;2-Pyridinecarboxylic acid, 6-formyl-, methyl ester;methyl 6-formyl-2-pyridinecarboxylate(SALTDATA: FREE);2-Formyl-6-(methoxycarbonyl)pyridine, Methyl 6-formylpicolinate
- CBNumber
- CB6205313
- Molecular Formula
- C8H7NO3
- Formula Weight
- 165.15
- MOL File
- 69950-65-8.mol
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Property
- Melting point:
- 94-98 °C
- Boiling point:
- 296.6±25.0 °C(Predicted)
- Density
- 1.249±0.06 g/cm3(Predicted)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- pka
- 1.57±0.10(Predicted)
- Appearance
- White to light yellow Solid
- InChI
- InChI=1S/C8H7NO3/c1-12-8(11)7-4-2-3-6(5-10)9-7/h2-5H,1H3
- InChIKey
- CERBENZCBVYKEF-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)=NC(C=O)=CC=C1
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M305503
- Product name
- Methyl6-formylpicolinate
- Packaging
- 25mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M305503
- Product name
- Methyl6-formylpicolinate
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 119184
- Product name
- Methyl 6-formyl-2-pyridinecarboxylate
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $144
- Updated
- 2021/12/16
- Product number
- Y9861
- Product name
- Methyl6-formylpyridine-2-carboxylate
- Packaging
- 1g
- Price
- $66
- Updated
- 2021/12/16
- Product number
- OR16637
- Product name
- Methyl6-formylpyridine-2-carboxylate
- Purity
- 96%
- Packaging
- 1g
- Price
- $66
- Updated
- 2021/12/16
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production
Synthesis
39977-44-1
69950-65-8
General procedure for the synthesis of methyl 6-formyl-2-pyridinecarboxylate from methyl 6-hydroxymethyl-2-pyridinecarboxylate: the product of Example 17A (8 g, 48 mmol) was dissolved in dichloromethane (200 mL) and electrolytic manganese dioxide (41.67 g, 0.48 mol) was added. The reaction mixture was stirred at 25 °C for 4 days and filtered through diatomaceous earth after completion of the reaction. The filtrate was concentrated under reduced pressure and the residue was purified by silica gel column chromatography to afford methyl 6-formyl-2-pyridinecarboxylate as a white solid (6.9 g, 87% yield) using a 5% dichloromethane solution of methanol as eluent.
References
[1] Patent: US2005/131017, 2005, A1. Location in patent: Page/Page column 106
[2] Patent: US6020345, 2000, A
[3] Bioorganic and Medicinal Chemistry Letters, 2003, vol. 13, # 4, p. 609 - 612
[4] Patent: WO2004/37808, 2004, A1. Location in patent: Page 9-10
[5] Chemistry of Heterocyclic Compounds, 2009, vol. 45, # 2, p. 161 - 168
6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER manufacturers
- Product
- 6-FORMYL-2-PYRIDINE CARBOXYLIC ACID METHYL ESTER 69950-65-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98
- Supply Ability
- 10t
- Release date
- 2019-12-18