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ChemicalBook > CAS DataBase List > 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos

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Product Name
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
CAS No.
1070663-78-3
Chemical Name
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms
BRETTPHOS;dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;BrettPhos 96%;Brettphos Ligand;-3,6-dimethoxybiphenyL;Dicyclohexyl(2',4',6'-tri;2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1';2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl
CBNumber
CB62129176
Molecular Formula
C35H53O2P
Formula Weight
536.77
MOL File
1070663-78-3.mol
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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Property

Melting point:
191-193℃
Boiling point:
607.7±55.0 °C(Predicted)
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Chloroform (Slightly), Methanol (Slightly, Sonicated)
form 
crystal
color 
white
InChI
InChI=1S/C35H53O2P/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28/h19-25,27-28H,9-18H2,1-8H3
InChIKey
WDVGNXKCFBOKDF-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-37-60
WGK Germany 
nwg
TSCA 
No
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
718742
Product name
BrettPhos
Purity
96%
Packaging
1g
Price
$231
Updated
2024/03/01
Sigma-Aldrich
Product number
718742
Product name
BrettPhos
Purity
96%
Packaging
5g
Price
$656.8
Updated
2024/03/01
TCI Chemical
Product number
D5664
Product name
Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine
Packaging
250MG
Price
$66
Updated
2024/03/01
Strem Chemicals
Product number
15-1152
Product name
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Packaging
250mg
Price
$49
Updated
2024/03/01
Strem Chemicals
Product number
15-1152
Product name
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Packaging
1g
Price
$162
Updated
2024/03/01
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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Chemical Properties,Usage,Production

Reactions

  1. Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
  2. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
  3. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
  4. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
  5. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
  6. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
  7. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
  8. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.

Uses

Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.

Uses

Buchwald Phosphine Ligands for chemical Synthesis

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos manufacturers

Speranza Chemical Co., Ltd.
Product
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos 1070663-78-3
Price
US $0.00-0.00/KG
Min. Order
5KG
Purity
98%
Supply Ability
25KG
Release date
2024-01-05
Shanghai UCHEM Inc.
Product
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl 1070663-78-3
Price
US $130.00-1185.00/g
Min. Order
5g
Purity
0.98
Supply Ability
1kg
Release date
2023-12-14
XINXIANG RUNYU MATERIAL CO., LTD.
Product
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, BrettPhos 1070663-78-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
500kg
Release date
2023-11-01

1070663-78-3, 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhosRelated Search:


  • 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl
  • 2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%
  • 2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos)
  • BrettPhos 96%
  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
  • 2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl
  • BRETTPHOS
  • Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
  • Dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine
  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl(BrettPhos)
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  • dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(propan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
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  • Dicyclohexyl(2',4',6'-tri
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  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos ISO 9001:2015 REACH
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  • high purity 1070663-78-3 in China /2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl good supplier
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  • Dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl) phenyl]phenyl]phosphane (Brettphos)
  • Brettphos Ligand
  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl (BRETTPHOS)Brettphos
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  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
  • Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine
  • Dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine
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  • dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(propan-2-yl)-[1,1'-biphenyl]-2-yl]phosphane
  • 1070663-78-3
  • C35H53O2P
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts