ChemicalBook > CAS DataBase List > Methyl 4-methylbenzoate

Methyl 4-methylbenzoate

Product Name
Methyl 4-methylbenzoate
CAS No.
99-75-2
Chemical Name
Methyl 4-methylbenzoate
Synonyms
MPT;NSC-24761;Methyl-p-toluat;Methylp-tolulate;p-Methyl toluate;METHYL P-TOLUATE;METHYL 4-TOLUATE;RARECHEM AL BF 0113;METHYL PARA TOLUATE;Methylp-toluate,99%
CBNumber
CB6224862
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
99-75-2.mol
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Methyl 4-methylbenzoate Property

Melting point:
32-35 °C (lit.)
Boiling point:
103-104 °C/15 mmHg (lit.)
Density 
1.06
vapor density 
4.7 (vs air)
vapor pressure 
1 mm Hg ( 39 °C)
refractive index 
1.5002 (estimate)
Flash point:
90 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Ethyl Acetate (Slightly)
form 
Solid
color 
White to Off-White
Odor
at 100.00 %. sweet anisic floral ylang
Odor Type
anisic
explosive limit
1-9.5%(V)
Water Solubility 
<0.1 g/100 mL at 22 ºC
BRN 
1100609
Dielectric constant
4.3（33℃）
Stability:
Unstable in Solution
LogP
2.7 at 25℃
CAS DataBase Reference
99-75-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 4-methyl-, methyl ester(99-75-2)
EPA Substance Registry System
Methyl-p-toluate (99-75-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36
WGK Germany 
2
RTECS 
XU2150000
Autoignition Temperature
932 °F
TSCA 
Yes
HS Code 
29163900
Hazardous Substances Data
99-75-2(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 3300mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
259667
Product name
Methyl p-toluate
Purity
≥99%
Packaging
250g
Price
$89
Updated
2024/03/01
TCI Chemical
Product number
T0297
Product name
Methyl p-Toluate
Purity
>98.0%(GC)
Packaging
25g
Price
$16
Updated
2024/03/01
TCI Chemical
Product number
T0297
Product name
Methyl p-Toluate
Purity
>98.0%(GC)
Packaging
500g
Price
$117
Updated
2024/03/01
Alfa Aesar
Product number
B23111
Product name
Methyl p-toluate, 99%
Packaging
100g
Price
$31.65
Updated
2024/03/01
Alfa Aesar
Product number
B23111
Product name
Methyl p-toluate, 99%
Packaging
500g
Price
$96.65
Updated
2024/03/01
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Methyl 4-methylbenzoate Chemical Properties,Usage,Production

Chemical Properties

white low melting crystalline solid and/or

Uses

Organic synthesis.

Uses

Methyl p-toluate has been employesd as catalyst to investigate the effect of internal/external donor pair in high-yield catalysts for propylene polymerization.

Synthesis Reference(s)

The Journal of Organic Chemistry, 54, p. 1144, 1989 DOI: 10.1021/jo00266a028
Synthetic Communications, 20, p. 3273, 1990

General Description

Opaque colorless to white shiny crystalline solid. Intense unpleasant odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Methyl 4-methylbenzoate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Methyl 4-methylbenzoate is combustible.

Methyl 4-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

Methyl 4-formylbenzoate Procarbazine hydrochloride Dimethyl terephthalate
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Methyl 4-methylbenzoate Suppliers

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View Lastest Price from Methyl 4-methylbenzoate manufacturers

airuikechemical co., ltd.
Product
Methyl 4-methylbenzoate 99-75-2
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.99%
Supply Ability
2000 tons
Release date
2024-04-10
Hebei Yanxi Chemical Co., Ltd.
Product
Methyl 4-methylbenzoate 99-75-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50tons
Release date
2023-08-07
Hebei Mojin Biotechnology Co., Ltd
Product
Methyl 4-methylbenzoate 99-75-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000000kg
Release date
2023-08-18

99-75-2, Methyl 4-methylbenzoateRelated Search:

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  • P-TOLUIC ACID METHYL ESTER
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  • Methyl 4-Toluate (Methyl 4-Methylbenzoate)
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