2,6-Diethylaniline

Product Name: 2,6-Diethylaniline
CAS No.: 579-66-8
Chemical Name: 2,6-Diethylaniline
Synonyms: DEA;2,6-diethyl-anilin;Benzenamine, 2,6-diethyl-;2.6-Diethylani;DEA) 2,6-Diethy;AKOS BBS-00003623;2,6-DIETHYLANALINE;2,6-DIETHYLANILINE;Aniline, 2,6-diethyl-;2,6- twoethyl aniline
CBNumber: CB6259518
Molecular Formula: C10H15N
Formula Weight: 149.23
MOL File: 579-66-8.mol

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2,6-Diethylaniline Property

Melting point:: 3-4 °C
Boiling point:: 243 °C (lit.)
Density: 0.906 g/mL at 25 °C (lit.)
vapor pressure: 0.02 mm Hg ( 20 °C)
refractive index: n20/D 1.545(lit.)
Flash point:: 254 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
pka: 4.13±0.10(Predicted)
form: Liquid
color: Clear yellow to reddish-brown
Water Solubility: 0.67g/L(26.7 ºC)
Sensitive: Air Sensitive
BRN: 1423626
Stability:: Air Sensitive
CAS DataBase Reference: 579-66-8(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 2,6-diethyl-(579-66-8)
EPA Substance Registry System: 2,6-Diethylaniline (579-66-8)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 23-24
RIDADR: 2810
WGK Germany: 2
RTECS: BX3500000
F: 8-9-23
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29214200
Hazardous Substances Data: 579-66-8(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H341Suspected of causing genetic defects

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 149381
Product name: 2,6-Diethylaniline
Purity: 98%
Packaging: 100ml
Price: $59.9
Updated: 2024/03/01

TCI Chemical

Product number: D0476
Product name: 2,6-Diethylaniline
Purity: >98.0%(GC)(T)
Packaging: 25mL
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: D0476
Product name: 2,6-Diethylaniline
Purity: >98.0%(GC)(T)
Packaging: 100mL
Price: $30
Updated: 2024/03/01

TRC

Product number: D443525
Product name: 2,6-Diethylaniline
Packaging: 1g
Price: $110
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD64331
Product name: 2,6-Diethylaniline
Packaging: 2g
Price: $114
Updated: 2021/12/16

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2,6-Diethylaniline Chemical Properties,Usage,Production

Chemical Properties

Clear liquid

Uses

2,6-Diethylaniline is used as a reagent in the synthesis of herbicides, for instance Butachlor (B689925); a pre-emergent chloroacetanalide herbicide commonly used for weed control in rice as well as cotton, maize, wheat and other crops.

Production Methods

2,6-Diethylaniline is obtained in high yield when aniline is heated with ethylene at 200-300°C under high pressure in the presence of aluminum anilide (Northcott 1978).

General Description

The 2,6-diethylaniline complexes with iodine, as a sigma-acceptor, were studied spectrophotometrically in chloroform, dichloromethane and carbontetrachloride solutions. It is an intermediate for the production of alachlor, butachlor, metolachlor-herbicides, tiafentiurone-insecticide, carbodiimide and RIM-PUR.

Industrial uses

2,6-Diethylaniline is used in the synthesis of herbicides such as Nevirex G and butachlor (Vertesi and Miklos 1982; Lee et al 1982).

Metabolic pathway

Incubation of 2,6-diethylaniline (DEA) with NADPH- fortified rat liver microsomal enzymes produces 4- amino-3,5-diethylphenol (ADEP) as the major oxidation product. ADEP is shown to undergo further oxidation to 3,5-diethylbenzoquinone-4-imine (DEBQI), which is isolated as a minor metabolite during DEA oxidation.

Metabolism

Incubation of 2,6-diethylaniline with NADPH-fortified microsomes produced 4-amino-3,5-diethylphenol (ADEP) as the major oxidation product (Feng and Wratten 1987). ADEP underwent further oxidation to 3,5-diethyl-benzoquinone-4-imine which is isolated as a minor metabolite during 2,6-diethylaniline metabolism. 2,6-Diethylaniline is produced under aerobic soil conditions as a minor metabolite of the herbicide butachlor (Lee et al 1982). 2,6-Diethylaniline is degraded by the soil microorganism Chaetomium globosum to 2,6-diethylacetanilide and 2,6-diethyl-p-benzoquinone (Lee and Ryu 1982). 2,6-Diethylaniline was also very persistent towards biodegradation in pond water with and without sewage sludge inoculation (Lyons et al 1985).

2,6-Diethylaniline Preparation Products And Raw materials

Raw materials

Triethylaluminum Aluminum chloride (aluminum trichloride) Aluminum Aniline DIETHYLALUMINUM CHLORIDE

Preparation Products

N-CHLOROACETYL-2,6-DIETHYLANILINE Alachlor Machette Acetochlor Pretilachlor Metolachlor Acetochlor E.C.

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2,6-Diethylaniline Suppliers

Americas 1 Belgium 3 Canada 2 China 249 Europe 2 France 2 Germany 6 India 17 Japan 4 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 8 United States 35 Global 337

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View Lastest Price from 2,6-Diethylaniline manufacturers

Anhui Royal Chemical Co., Ltd.

Product: 2,6-Diethylaniline 579-66-8
Price: US $100.00/KG
Min. Order: 200KG
Purity: 99%
Supply Ability: 20ton
Release date: 2018-10-30

Hebei Weibang Biotechnology Co., Ltd

Product: 2,6-Diethylaniline 579-66-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

Hebei Yanxi Chemical Co., Ltd.

Product: 2,6-Diethylaniline 579-66-8
Price: US $20.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-09-15

579-66-8, 2,6-DiethylanilineRelated Search:

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579-66-8

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579668

Amines

Building Blocks

C9 to C10

Nitrogen Compounds

Organic Building Blocks

Organics

Aniline Derivatives

o-alkylated Anilines

Intermediates of Dyes and Pigments