2,5-Furandicarboxylic acid

Product Name: 2,5-Furandicarboxylic acid
CAS No.: 3238-40-2
Chemical Name: 2,5-Furandicarboxylic acid
Synonyms: FURAN-2,5-DICARBOXYLIC ACID;2,5-furandicarboxylate;2,5-Furandicarboxylic;2,3-furandicarboxylic acid;2,5-Furandicarboxylic acid (FDCA);FDCA;NSC 40740;5-Furandic;5-Furandicar;DEHYDROMUCIC ACID
CBNumber: CB6264091
Molecular Formula: C6H4O5
Formula Weight: 156.09
MOL File: 3238-40-2.mol

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2,5-Furandicarboxylic acid Property

Melting point:: >300 °C
Boiling point:: 240.29°C (rough estimate)
Density: 1.7400
refractive index: 1.6400 (estimate)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly Sonicated)
form: Solid
pka: 2.28±0.10(Predicted)
color: White to Dark Brown
Water Solubility: 1g/L(18 ºC)
Stability:: Light Sensitive, Very Hygroscopic
InChIKey: CHTHALBTIRVDBM-UHFFFAOYSA-N
LogP: -1.43 at 20℃
CAS DataBase Reference: 3238-40-2(CAS DataBase Reference)
NIST Chemistry Reference: Furan-2,5-dicarboxylic acid(3238-40-2)
EPA Substance Registry System: 2,5-Furandicarboxylic acid (3238-40-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-36
Safety Statements: 26-36/37/39-36/37
WGK Germany: 1
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 722081
Product name: 2,5-Furandicarboxylic acid
Purity: 97%
Packaging: 5g
Price: $280
Updated: 2024/03/01

TCI Chemical

Product number: F0710
Product name: 2,5-Furandicarboxylic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 5g
Price: $72
Updated: 2024/03/01

TCI Chemical

Product number: F0710
Product name: 2,5-Furandicarboxylic Acid
Purity: >98.0%(HPLC)(T)
Packaging: 25g
Price: $236
Updated: 2024/03/01

Alfa Aesar

Product number: H28718
Product name: Furan-2,5-dicarboxylic acid, 98%
Packaging: 1g
Price: $94.5
Updated: 2024/03/01

Alfa Aesar

Product number: H28718
Product name: Furan-2,5-dicarboxylic acid, 98%
Packaging: 5g
Price: $254
Updated: 2024/03/01

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2,5-Furandicarboxylic acid Chemical Properties,Usage,Production

Description

2,5-Furandicarboxylic acid (FDCA) is an organic chemical compound consisting of two carboxylic acid groups attached to a central furan ring. It was first reported as dehydromucic acid by Rudolph Fittig and Heinzelmann in 1876, who produced it via the action of concentrated hydrobromic acid upon mucic acid. It can be produced from certain carbohydrates and as such is a renewable resource, it was identified by the US Department of Energy as one of 12 priority chemicals for establishing the “green” chemistry industry of the future.Furan-2,5-dicarboxylic acid (FDCA) has been suggested as an important renewable building block because it can substitute for terephthalic acid (PTA) in the production of polyesters and other current polymers containing an aromatic moiety.
wikipedia

Chemical Properties

2,5-Furandicarboxylic acid is a chemical intermediate with high sensitivity and good stability. It is soluble in water under alkaline conditions and is a white powder solid under acidic conditions, and is an important monomer for the preparation of corrosion-resistant plastics. It is irritating to eyes, respiratory tract and skin.

History

2,5-Furandicarboxylic acid, also known as dehydromucic acid, is a furan derivative. This organic compound was first obtained by Fittig and Heinzelmann in 1876. More than 125 years later, FDCA was identified by the US Department of Energy as one of 12 priority chemicals for establishing the "green" chemistry industry of the future. On a laboratory scale, it is often synthesized from 5- hydroxymethylfurfural (HMF), which in turn can be obtained from carbohydrate-containing sources such as glucose, fructose, sucrose, and starch. From fructose and glucose, HMF is obtained by acidic eliminating three moles of water.

Uses

Interest in renewable based polymers has led to 2,5-furandicarboxylic acid being proposed as a green, sustainable alternative to the widely used petroleum-based terephthalic acid in the synthesis of polyesters. 2,5-Furandicarboxylic acid is produced from oxidation of 5-hydroxymethylfurfural (HMF) which is obtained from the dehydration of bio-based sugars such as fructose.

Uses

2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.

Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported.

Preparation

2,5-Furandicarboxylic acid (FDCA) can be produced from biomass or its derived sugars or platform chemicals, and has demonstrated to be a very promising substitute for petroleum-derived polymer products.
Chapter 5 - Advances in the synthesis and application of 2,5-furandicarboxylic acid

Definition

ChEBI: A member of the class of furans carrying two carboxy substituents at positions 2 and 5.

Application

2,5-Furandicarboxylic acid (FDCA) is a renewable, greener substitute for terephthalate in the production of polyesters. It is widely used as a precursor for the synthesis of bio-based polyesters and various other polymers.
Applications of FDCA in the synthesis of several metal-organic frameworks (MOFs) have also been reported.

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 1777, 1985 DOI: 10.1016/S0040-4039(00)98336-9

Flammability and Explosibility

Not classified

Solubility in organics

2,5-Furandicarboxylic acid (FDCA) serves as a monomer in various polyesters and is often obtained through the oxidation of 5-hydroxymethylfurfural. In pure solvents and binary mixtures, the solubility of FDCA increased with the increasing temperature. The order from largest to smallest solubility in pure solvents was as follows: methanol, 1-butanol, isobutanol, acetic acid, water, MIBK, ethyl acetate, and acetonitrile.
https://doi.org/10.1021/acs.jced.7b00927

2,5-Furandicarboxylic acid Preparation Products And Raw materials

Raw materials

5-Hydroxymethylfurfural Hydrochloric acid Nitric acid Potassium permanganate Sodium hydroxide

Preparation Products

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View Lastest Price from 2,5-Furandicarboxylic acid manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: 2,5-Furandicarboxylic acid 3238-40-2
Price: US $100.00-75.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000Ton
Release date: 2024-08-13

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 2,5-Furandicarboxylic acid 3238-40-2
Price: US $60.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-10

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 2,5-Furandicarboxylic acid 3238-40-2
Price: US $120.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-04-25

3238-40-2, 2,5-Furandicarboxylic acidRelated Search:

Isophthalic acid Phthalic acid OXALIC ACID Bis(2-ethylhexyl) phthalate EPA 2-Furoic acid Potassium hydrogen phthalate Diethyl phthalate Diethyl azodicarboxylate Dimethyl phthalate Furan Ascoric Acid DIETHYL 3,4-DIHYDROXYFURAN-2,5-DICARBOXYLATE 3,4-Furandicarboxylic acid dimethyl ester 2,3-Furandicarboxylic acid, tetrahydro-5-oxo- 2,3-furandicarboxylic acid dimethyl ester 3,4-Furandicarboxylic acid DIETHYL 3,4-FURANDICARBOXYLATE

Furane-alpha,alpha'-dicarboxylic acid

RARECHEM AL BO 0910

FURAN-2,5-DICARBOXYLIC ACID

DEHYDROMUCIC ACID

2,5-FURANDICARBOXYLIC ACID

Furan-2,5-dicarboxylic acid 97%

2,3-furandicarboxylic acid

2,5-FurandicarboxyL

5-Furandicarboxylic acid

Furane-α,α'-dicarboxylic Acid

NSC 40740

5-Furandicar

5-Furandic

2,5-Furandicarboxylic acid 97%

2, 5 - furan 2 forMic acid

2,5-Dicarboxyfuran

2,5-Furandicarboxylic acid (FDCA)

2,5-Furandicarboxylic

purity nitric acid

2,5-FurandicarboxylicAcid&gt

2,5-Furandicarboxylic acid ISO 9001：2015 REACH

2,5-furandicarboxylate

2,5-Furandicarboxylic acid (7CI, 8CI, 9CI, ACI)

2,5-Furanedicarboxylic acid

FDCA

2,5-Furandicarboxylic Acid, ≥ 98.0%

3238-40-2

221-800-8

C6H4O5

C4H2OCOOH2

aldehydes

Intermediates & Fine Chemicals

Mutagenesis Research Chemicals

Pharmaceuticals

Carboxylic Acids

Furans, Benzofurans & Dihydrobenzofurans

Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts

Carboxylic Acids

Furans, Benzofurans & Dihydrobenzofurans

Furans

3238-40-2