ChemicalBook > CAS DataBase List > 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER

3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER

Product Name
3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER
CAS No.
941714-57-4
Chemical Name
3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER
Synonyms
methyl 3-bromo-1H-pyrrole-2-carboxylate;Methyl 3-BroMopyrrole-2-carboxylate;SW-83;SWF-83;3-BroMo-1H-pyrrole-carboxylate Methyl;3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER;1H-Pyrrole-2-carboxylic acid, 3-bromo-, methyl ester
CBNumber
CB62665281
Molecular Formula
C6H6BrNO2
Formula Weight
204.02
MOL File
941714-57-4.mol
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3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Property

Boiling point:
286.2±20.0 °C(Predicted)
Density 
1.674±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
pka
13.49±0.50(Predicted)
Appearance
White to yellow Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M293830
Product name
Methyl3-Bromo-1H-pyrrole-2-carboxylate
Packaging
50mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
4H23-9-15
Product name
Methyl 3-bromo-1H-pyrrole-2-carboxylate
Packaging
1g
Price
$225
Updated
2021/12/16
AK Scientific
Product number
7019AJ
Product name
Methyl3-bromopyrrole-2-carboxylate
Packaging
5g
Price
$290
Updated
2021/12/16
SynQuest Laboratories
Product number
4H23-9-15
Product name
Methyl 3-bromo-1H-pyrrole-2-carboxylate
Packaging
5G
Price
$800
Updated
2021/12/16
Matrix Scientific
Product number
113439
Product name
3-Bromo-1H-pyrrole-2-carboxylic acid methyl ester
Packaging
1g
Price
$662
Updated
2021/12/16
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3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Usage,Production

Synthesis

1192217-76-7

941714-57-4

a) Synthesis of methyl 3-bromo-1H-pyrrole-2-carboxylate: methyl 3-bromo-1-(phenylsulfonyl)-1H-pyrrole-2-carboxylate (6.59 g, 19.2 mmol) was dissolved in 132 mL of methanol. Sodium methanolate (1.55 g, 28.7 mmol) was added and the reaction mixture was stirred for 4 hours at room temperature. After completion of the reaction, the solvent was removed by evaporation and the residue was extracted by partitioning with saturated aqueous ammonium chloride solution and ethyl acetate. The organic layer was washed sequentially with water and brine, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure. Purification by fast column chromatography (eluent: 0% to 30% hexane/ethyl acetate gradient) afforded 3.32 g (85% yield) of the target product methyl 3-bromopyrrole-2-carboxylate. Low resolution mass spectrometry (LRMS) showed m/z: 203,205 ([M+1]+).

References

[1] Patent: WO2012/146666, 2012, A1. Location in patent: Page/Page column 188-189
[2] Patent: WO2014/60432, 2014, A1. Location in patent: Page/Page column 132

3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER Suppliers

China 74 India 2 United Kingdom 1 United States 6 Global 83
Accela ChemBio Inc.
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+1-858-6993322
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Synthonix Inc
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Combi-Blocks Inc.
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SynQuest Laboratories, Inc.
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United States
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Matrix Scientific
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United States
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6632
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View Lastest Price from 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER 941714-57-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-09-04
Career Henan Chemical Co
Product
3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER 941714-57-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-30

941714-57-4, 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTERRelated Search:

(1s,3r,4r)-3-[(tert-butoxycarbonyl)amino]-4-[(methylsulfonyl)oxy]cyclohexanecarboxylic acid ethyl ester LY-2484595 methyl exo-3-azabicyclo[3.1.0]hexane-6-carboxylate hydrochloride SW-80 2-iodo-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridine 7-bromo-4-(trifluoromethyl)-1H-indole 6-Bromoisatin 3-Trifluoromethyl-1H-pyrrolo[2,3-b]pyridine 1H-Pyrrole-2-acetic acid, 3-(methoxycarbonyl)-1-methyl-, methyl ester Pyrido[4,3-d]pyrimidin-4(1H)-one (9CI) 1H-PYRROLO[2,3-B]PYRIDINE, 2-METHYL- BOC,BZL-L-ALA-OH

  • 3-BROMO-1H-PYRROLE-2-CARBOXYLIC ACID METHYL ESTER
  • methyl 3-bromo-1H-pyrrole-2-carboxylate
  • Methyl 3-BroMopyrrole-2-carboxylate
  • 3-BroMo-1H-pyrrole-carboxylate Methyl
  • 1H-Pyrrole-2-carboxylic acid, 3-bromo-, methyl ester
  • SWF-83
  • SW-83
  • 941714-57-4