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N-Carbobenzyloxy-L-valine

Product Name
N-Carbobenzyloxy-L-valine
CAS No.
1149-26-4
Chemical Name
N-Carbobenzyloxy-L-valine
Synonyms
Z-VAL;Z-VAL-OH;CBZ-VAL-OH;CBZ-L-VALINE;Cbz-L-Val;Z-L-VALINE;N-CBZ-valine;(S)-2-(((benzyloxy)carbonyl)aMino)-3-Methylbutanoic acid;Z-L-VAL-OH;N-CBZ-L-VALINE
CBNumber
CB6320272
Molecular Formula
C13H17NO4
Formula Weight
251.28
MOL File
1149-26-4.mol
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N-Carbobenzyloxy-L-valine Property

Melting point:
62-64 °C(lit.)
alpha 
-4 º (c=2,acetic acid)
Boiling point:
394.43°C (rough estimate)
Density 
0,926g/cm
refractive index 
-4.3 ° (C=2, AcOH)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Acetic Acid, DMSO (Slightly), Ethanol (Slightly)
pka
4.00±0.10(Predicted)
form 
Crystalline Powder
color 
White to off-white
optical activity
[α]20/D 4.2±0.5°, c = 2 in chloroform
BRN 
2056617
InChI
InChI=1S/C13H17NO4/c1-9(2)11(12(15)16)14-13(17)18-8-10-6-4-3-5-7-10/h3-7,9,11H,8H2,1-2H3,(H,14,17)(H,15,16)/t11-/m0/s1
InChIKey
CANZBRDGRHNSGZ-NSHDSACASA-N
SMILES
C(O)(=O)[C@H](C(C)C)NC(OCC1=CC=CC=C1)=O
CAS DataBase Reference
1149-26-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
38-43-36/37/38-20/21/22
Safety Statements 
36/37-36-26
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29242990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
293520
Product name
Carbobenzyloxy-L-valine
Purity
99%
Packaging
5g
Price
$30.3
Updated
2024/03/01
TCI Chemical
Product number
C0761
Product name
N-Carbobenzoxy-L-valine
Purity
>99.0%(HPLC)(T)
Packaging
5g
Price
$23
Updated
2024/03/01
TCI Chemical
Product number
C0761
Product name
N-Carbobenzoxy-L-valine
Purity
>99.0%(HPLC)(T)
Packaging
25g
Price
$63
Updated
2024/03/01
Alfa Aesar
Product number
A13583
Product name
N-Benzyloxycarbonyl-L-valine, 99%
Packaging
25g
Price
$64.65
Updated
2024/03/01
Alfa Aesar
Product number
A13583
Product name
N-Benzyloxycarbonyl-L-valine, 99%
Packaging
5g
Price
$19.1
Updated
2021/12/16
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N-Carbobenzyloxy-L-valine Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Imatinib intermediate

Uses

Valaciclovir intermediate

Uses

N-Cbz-L-valine is an N-Cbz-protected form of L-Valine (V094205). L-Valine is an essential amino acid that is used as an ingredient in cosmetic formulations, pharmaceuticals, and animal feed products. L-valine is also important for growth and ammonia detoxification in humans.

Synthesis Reference(s)

Synthesis, p. 738, 1985 DOI: 10.1055/s-1985-31329

N-Carbobenzyloxy-L-valine Preparation Products And Raw materials

Raw materials

Preparation Products

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N-Carbobenzyloxy-L-valine Suppliers

GenChem & GenPharm (Changzhou) Co., Ltd.
Tel
0519-85720003 18861157602
Fax
0519-85720007
Email
sales03@genchem.cn
Country
China
ProdList
111
Advantage
58
GL Biochem (Shanghai) Ltd
Tel
21-61263452 13641803416
Fax
86-21-61263399
Email
ymbetter@glbiochem.com
Country
China
ProdList
9981
Advantage
64
Changzhou Huaren Chemical Co., Ltd
Tel
0519-88103998 13646148298
Fax
0519-88104456
Email
amy.zhou@huarenchem.com
Country
China
ProdList
56
Advantage
63
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
PharmaBlock Sciences (Nanjing),Inc.
Tel
025-86918202 4000255188
Fax
86-025-86918232
Email
sales@pharmablock.com
Country
China
ProdList
4986
Advantage
55
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
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View Lastest Price from N-Carbobenzyloxy-L-valine manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
N-Carbobenzyloxy-L-valine 1149-26-4
Price
US $0.00/Kg/Drum
Min. Order
1KG
Purity
98%min
Supply Ability
500kgs
Release date
2021-09-24
Sichuan HongRi Pharma-Tech Co.,Ltd
Product
Cbz-L-Val-OH 1149-26-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1T+
Release date
2024-01-15
Shaanxi Dideu Medichem Co. Ltd
Product
N-Carbobenzyloxy-L-valine 1149-26-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10 tons
Release date
2024-08-17

1149-26-4, N-Carbobenzyloxy-L-valineRelated Search:


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  • Z-VALINE
  • Z-VAL-OH
  • N-Carbobenzyloxy-L-valine Cbz-L-Valine
  • CBZ-L-Valine (Z-Val-OH)
  • Z-L-VALINE
  • Z-L-VAL-OH
  • N-Cbz-L-valine Z-Val-OH
  • N-CBZ-L-Val-OH
  • (S)-2-(((benzyloxy)carbonyl)aMino)-3-Methylbutanoic acid
  • Carbobenzyloxy-L-valine 99%
  • Carbobenzyloxy-L-valine, >=99%
  • Cbz-L-Val
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  • N-[(Benzyloxy)(carbonyl)]-L-va
  • N-BENZYLOXYCARBONYL-L-VALINE(N-CBZ-L-VLA-OH)
  • (S)-N-(BENZYLOXYCARBONYL)VALINE
  • 2-{[(Benzyloxy)carbonyl]amino}-3-methylbutanoic acid
  • Z-L-TYROSYL-L-THREONINE
  • N-BOC-PIPERIDINEAMINE
  • N-Benzyloxycarbonyl-L-Valine*(Intermediate of Valaciclovir)
  • 3-Methyl-2-(phenylmethoxycarbonylamino)butanoic acid
  • (2S)-2-(Benzyloxycarbonylamino)-3-methylbutanoic acid
  • Carbobenzoxy-L-valine
  • 2-{[(Benzyloxy)carbonyl]amino}-3-methylbutanoic
  • N-Z-L-Valine
  • Z-Val-OH ,≥99.0%
  • Benzyloxycarbonyl-L-valine (Z-Val-OH)
  • N-CBZ-valine
  • L-VALINE, N-[(PHENYLMETHOXY)CARBONYL]-
  • N-Carbobenzyloxy-L-v
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  • Z-L-VALINE extrapure
  • Carbobenzyloxy-L-valine, Z-L-Valine
  • CBZ-L-VAL-OH
  • CARBOBENZYLOXY-L-VALINE
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  • N-ALPHA-CBZ-L-VALINE
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  • N-ALPHA-BENZYLOXYCARBONYL-L-VALINE
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  • L-Valine CBZ