(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole

Reaction

Product Name: (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole
CAS No.: 1884680-45-8
Chemical Name: (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole
Synonyms: ZJ-0031;(2R,2'R,3R,3'R)-WingPhos;(2R,2R’,3R,3R’)-WingPhos;90% ee), [(2R,2'R,3R,3'R)-WingPhos];(2R,2'R,3R,3'R)-4,4'-Di-9-anthracenyl-3,3'-bis(tert-butyl)-2,2',3,3'-tetrahydro-2,2'-bi-1,3-benzoxaphosphole;(2R,2'R,3R,3'R)-4,4'-Di-9-anthracenyl-3,3'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-2,2'-bi-1,3-benzoxaphosphole;(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole;(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole;2,2'-Bi-1,3-benzoxaphosphole, 4,4'-di-9-anthracenyl-3,3'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (2R,2'R,3R,3'R)-;(2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-t-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, min 98% (>
CBNumber: CB63340354
Molecular Formula: C50H44O2P2
Formula Weight: 738.83
MOL File: 1884680-45-8.mol

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(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole Property

storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: light yellow
Sensitive: air sensitive, store cold

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Safety

HS Code: 2931499090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-1970
Product name: (2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-t-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, min 98% (>90% ee), [(2R,2'R,3R,3'R)-WingPhos]
Packaging: 25mg
Price: $77
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1970
Product name: (2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-t-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, min 98% (>90% ee), [(2R,2'R,3R,3'R)-WingPhos]
Packaging: 100mg
Price: $231
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1970
Product name: (2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-t-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, min 98% (>90% ee), [(2R,2'R,3R,3'R)-WingPhos]
Packaging: 500mg
Price: $765
Updated: 2024/03/01

Apolloscientific

Product number: OR510258
Product name: (2R,2'R,3R,3'R)-WingPhos
Purity: >98%
Packaging: 100mg
Price: $360
Updated: 2021/12/16

ChemScene

Product number: CS-0020505
Product name: (2R,2'R,3R,3'R)-WingPhos
Purity: >97.0%
Packaging: 100mg
Price: $196
Updated: 2021/12/16

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(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole Chemical Properties,Usage,Production

Reaction

Ligand for rhodium-catalyzed enantioselective addition of arylboroxines to simple aryl ketones.

(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole Suppliers

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1884680-45-8, (2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp holeRelated Search:

(2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-iso propyl-2,3-dihydrobenzo[d ][1,3]oxaphosphole (2R,2'R,3R,3'R)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole (2R,3R)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (2S,3S)-3-(tert-butyl)-4-(2, 6-dimethoxyphenyl)-2-met hyl-2,3-dihydrobenzo[d][1, 3]oxaphosphole (R)-4-(anthracen-9-yl)-3-(t ert-butyl)-2,3-dihydrobenz o[d][1,3]oxaphosphole (R)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole 4-(anthracen-9-yl)-3-(tertbutyl)-2,3-dihydrobenzo[d] [1,3]oxaphosphole (2S,2'S,3S,3'S)-4,4'-di(anth racen-9-yl)-3,3'-di-tert-but yl-2,2',3,3'-tetrahydro-2,2'- bibenzo[d][1,3]oxaphosph ole (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole (S)-3-(tert-butyl)-4-(2,6-di methoxyphenyl)-2,3-dihyd robenzo[d][1,3]oxaphosph ole

(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole

(2R,2'R,3R,3'R)-4,4'-DI(ANTHRACEN-9-YL)-3,3'-DI-T-BUTYL-2,2',3,3'-TETRAHYDRO-2,2'-BIBENZO[D][1,3]OXAPHOSPHOLE,MIN98%(>90%EE),[(2R,2'R,3R,3'R)-WINGPHOS]

(2R,2'R,3R,3'R)-4,4'-Di-9-anthracenyl-3,3'-bis(tert-butyl)-2,2',3,3'-tetrahydro-2,2'-bi-1,3-benzoxaphosphole

(2R,2R’,3R,3R’)-WingPhos

(2R,2'R,3R,3'R)-4,4'-Di-9-anthracenyl-3,3'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-2,2'-bi-1,3-benzoxaphosphole

ZJ-0031

90% ee), [(2R,2'R,3R,3'R)-WingPhos]

(2R,2'R,3R,3'R)-4,4'-Di(anthracen-9-yl)-3,3'-di-t-butyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, min 98% (&gt

2,2'-Bi-1,3-benzoxaphosphole, 4,4'-di-9-anthracenyl-3,3'-bis(1,1-dimethylethyl)-2,2',3,3'-tetrahydro-, (2R,2'R,3R,3'R)-

(2R,2'R,3R,3'R)-4,4'-di(ant hracen-9-yl)-3,3'-di-tert-bu tyl-2,2',3,3'-tetrahydro-2,2' -bibenzo[d][1,3]oxaphosp hole

(2R,2'R,3R,3'R)-WingPhos

1884680-45-8

C50H44O2P2

Chiral Phosphine