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2-Methyl-5-nitroanisole

Uses
Product Name
2-Methyl-5-nitroanisole
CAS No.
13120-77-9
Chemical Name
2-Methyl-5-nitroanisole
Synonyms
2-Methyl-5-nitroanis;5-Nitro-o-metylanisole;5-Nitro-2-MethylAnisole;2-METHYL-5-NITROANISOLE;2-METHOXY-4-NITROTOLUENE;4-nitro-2-Methoxytoluene;2-METHYL-5-NITROANISOLE 99%;2-Methyl-5-nitroanisole,99%;2-Methoxy-4-nitrotoluene>methyl 5-nitro-o-tolyl ether
CBNumber
CB6379720
Molecular Formula
C8H9NO3
Formula Weight
167.16
MOL File
13120-77-9.mol
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2-Methyl-5-nitroanisole Property

Melting point:
69-71 °C (lit.)
Boiling point:
281.2±20.0 °C(Predicted)
Density 
1.180±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Light yellow
CAS DataBase Reference
13120-77-9(CAS DataBase Reference)
EPA Substance Registry System
Benzene, 2-methoxy-1-methyl-4-nitro- (13120-77-9)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
24/25-36-26
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
M1681
Product name
2-Methoxy-4-nitrotoluene
Purity
>98.0%(GC)
Packaging
25g
Price
$25
Updated
2025/07/31
TCI Chemical
Product number
M1681
Product name
2-Methoxy-4-nitrotoluene
Purity
>98.0%(GC)
Packaging
500g
Price
$177
Updated
2025/07/31
Matrix Scientific
Product number
075253
Product name
2-Methyl-5-nitroanisole
Purity
95+%
Packaging
10g
Price
$29
Updated
2021/12/16
Matrix Scientific
Product number
075253
Product name
2-Methyl-5-nitroanisole
Purity
95+%
Packaging
100g
Price
$120
Updated
2021/12/16
ChemScene
Product number
CS-W017839
Product name
2-Methyl-5-nitroanisole
Packaging
500g
Price
$150
Updated
2021/12/16
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2-Methyl-5-nitroanisole Chemical Properties,Usage,Production

Uses

2-Methyl-5-nitroanisole is a useful research chemical.

Chemical Properties

cream to yellow crystalline powder and chunks

Uses

2-Methyl-5-nitroanisole was used in the synthesis of:

  • 2-methoxy-p-toluidine via reduction with tin and hydrochloric acid
  • 2-methoxy-4-nitrobenzyl bromide

Synthesis

5428-54-6

74-88-4

13120-77-9

GENERAL METHOD: Under argon protection, 2-methyl-5-nitrophenol (613 mg, 4.0 mmol) was dissolved in anhydrous DMF (7 mL) and potassium carbonate (608 mg, 4.4 mmol) and iodomethane (12.0 mmol) were added sequentially. The reaction mixture was heated with stirring at 40 °C for 2-3 hours. After completion of the reaction, the mixture was poured into water and extracted with ethyl acetate (EtOAc). The organic layers were combined, washed sequentially with water and saturated brine and dried over anhydrous magnesium sulfate (MgSO4). The solvent was removed by concentration under reduced pressure and the resulting residue was purified by silica gel column chromatography to afford the target product 2-methyl-5-nitroanisole.

References

[1] European Journal of Organic Chemistry, 2009, # 27, p. 4614 - 4621
[2] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 10, p. 3156 - 3172
[3] Chemical and Pharmaceutical Bulletin, 2014, vol. 62, # 10, p. 979 - 988
[4] Patent: US2004/214798, 2004, A1. Location in patent: Page 18

2-Methyl-5-nitroanisole Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methyl-5-nitroanisole Suppliers

Americas 1 Belgium 2 China 165 Europe 3 Germany 4 India 11 Japan 1 Slovakia 1 Switzerland 2 United Kingdom 17 United States 40 Global 247
MDP ChemControl Ltd.
Tel
--
Fax
--
Email
chemcontrol@nextra.sk
Country
Slovakia
ProdList
6700
Advantage
60
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View Lastest Price from 2-Methyl-5-nitroanisole manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-Methyl-5-nitroanisole 13120-77-9
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-Methyl-5-nitroanisole 13120-77-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-Methyl-5-nitroanisole 13120-77-9
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

13120-77-9, 2-Methyl-5-nitroanisoleRelated Search:

Tribenuron methyl Kresoxim-methyl 2,5-Dimethylpyridine Methyl acetate Pirimiphos-methyl 2-Chloro-5-chloromethylpyridine Methyl salicylate Anisole 3,5-Dimethylanisole METSULFURON METHYL 4-Methoxyphenol Thiophanate-methyl Methyl 2-Methoxy-4-nitrobenzoic acid 2-CYANO-5-NITROANISOLE 4-Nitroanisole 4-METHYL-2-NITROANISOLE 99%,4-METHYL-2-NITROANISOLE 2-METHYL-3-NITROANISOLE PESTANAL, 100 MG,2-METHYL-3-NITROANISOLE, 98+%,2-METHYL-3-NITROANISOLE (2-METHOXY-6-NITROTOLUENE),2-METHYL-3-NITROANISOLE

  • 2-methoxy-1-methyl-4-nitro-benzen
  • 1-METHOXY-2-METHYL-5-NITROBENZENE
  • 2-METHYL-5-NITROANISOLE
  • 2-METHOXY-4-NITROTOLUENE
  • 2-METHOXY-1-METHYL-4-NITRO-BENZENE
  • 1-Methoxy-2-methyl-5-nitrobenzene 2-Methyl-5-nitroanisole
  • 4-nitro-2-Methoxytoluene
  • 2-METHYL-5-NITROANISOLE 99%
  • methyl 5-nitro-o-tolyl ether
  • 5-Nitro-2-MethylAnisole
  • 1-Methyl-2-methoxy-4-nitrobenzene
  • 3-Methyl-4-methoxy-1-nitrobenzene
  • 2-Methyl-5-nitroanisole,99%
  • 2-Methyl-5-nitroanis
  • 2-Methoxy-4-nitrotoluene 98%
  • 2-Methoxy-1-methyl-4-nitrobenzene, Methyl 2-methyl-5-nitrophenyl ether
  • 2-Methyl-5-nitroanisole≥ 99% (HPLC)
  • 5-hydroxy-4,7,7-trimethyl-2-bicyclo[2.2.1]heptanone
  • 2-Methoxy-4-nitrotoluene&gt
  • Benzene, 2-methoxy-1-methyl-4-nitro-
  • 2-Methyl-5-nitroanisole ISO 9001：2015 REACH
  • 5-Nitro-o-metylanisole
  • 13120-77-9
  • CH3C6H3NO2OCH3
  • Building Blocks
  • Organic Building Blocks
  • Nitrogen Compounds
  • Nitro Compounds
  • Aromatic Hydrocarbons (substituted) & Derivatives
  • Anisole
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Nitro Compounds
  • Nitro Compounds
  • Nitrogen Compounds
  • Organic Building Blocks