ChemicalBook > CAS DataBase List > 2-Bromo-3-fluorobenzoic acid
2-Bromo-3-fluorobenzoic acid
- Product Name
- 2-Bromo-3-fluorobenzoic acid
- CAS No.
- 132715-69-6
- Chemical Name
- 2-Bromo-3-fluorobenzoic acid
- Synonyms
- EOS-61551;BUTTPARK 22\01-97;2-Bromo-3-fluorobenzoic;2-BROMO-3-FLUOROBENZOIC ACID;3-Fluoro-2-Bromo Benzoic Acid;Benzoic acid, 2-broMo-3-fluoro-;2-Bromo-3-fluorobenzoic acid 98%;2-Bromo-3-fluorobenzoic Acid >2-Bromine-3-Fluoride Benzoic Acids;3-Fluoro-2-Bromo Benzoic Acid 2-Bromo-3-Fluorobenzoic Acid
- CBNumber
- CB6417095
- Molecular Formula
- C7H4BrFO2
- Formula Weight
- 219.01
- MOL File
- 132715-69-6.mol
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2-Bromo-3-fluorobenzoic acid Property
- Melting point:
- 158-160°C
- Boiling point:
- 292.7±25.0 °C(Predicted)
- Density
- 1.789±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- powder to crystal
- pka
- 2.51±0.10(Predicted)
- color
- White to Light yellow to Light orange
- InChI
- InChI=1S/C7H4BrFO2/c8-6-4(7(10)11)2-1-3-5(6)9/h1-3H,(H,10,11)
- InChIKey
- KQRCBMPPEPNNDS-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC=CC(F)=C1Br
- CAS DataBase Reference
- 132715-69-6(CAS DataBase Reference)
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Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36/37/38-36-22
- Safety Statements
- 26-36/37/39-37
- HazardClass
- IRRITANT
- HS Code
- 29163990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- B3722
- Product name
- 2-Bromo-3-fluorobenzoic Acid
- Purity
- >96.0%(GC)(T)
- Packaging
- 1g
- Price
- $70
- Updated
- 2025/07/31
TCI Chemical
- Product number
- B3722
- Product name
- 2-Bromo-3-fluorobenzoic Acid
- Purity
- >96.0%(GC)(T)
- Packaging
- 5g
- Price
- $218
- Updated
- 2025/07/31
Usbiological
- Product number
- 415763
- Product name
- 2-Bromo-3-fluorobenzoic acid
- Packaging
- 100mg
- Price
- $305
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FB38482
- Product name
- 2-Bromo-3-fluorobenzoic acid
- Packaging
- 100g
- Price
- $450
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- HCH0018583
- Product name
- 2-BROMO-3-FLUOROBENZOIC ACID
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $606.38
- Updated
- 2021/12/16
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2-Bromo-3-fluorobenzoic acid Chemical Properties,Usage,Production
Chemical Properties
Off-white powder
Synthesis Reference(s)
Tetrahedron Letters, 36, p. 881, 1995 DOI: 10.1016/0040-4039(94)02385-O
Synthesis
825-22-9
132715-69-6
The general procedure for the synthesis of 2-bromo-3-fluorobenzoic acid from 2-amino-3-fluorobenzoic acid is as follows: in a 1L three-necked round-bottomed flask equipped with a dropping funnel and a thermometer, 20g (0.13 mol) of 2-amino-3-fluorobenzoic acid and 160mL of acetonitrile were added. After the mixture was cooled to 0 °C, 160 mL of 47% hydrobromic acid solution was added slowly and dropwise over 10 min. Subsequently, a solution prepared from 10 g (0.145 mol) of sodium nitrite (NaNO2) dissolved in 20 mL of water was added dropwise to the reaction system over 1 hour. After the dropwise addition, the reaction mixture was continued to be stirred at 0°C for 5 min. Next, 21.8 g (0.15 mol) of copper bromide (CuBr) was added in batches over 30 minutes. The reaction mixture was transferred to a 70°C oil bath and stirred continuously for 1 hour. Upon completion of the reaction, the mixture was cooled to 0 °C, diluted with 700 mL of water and the precipitate was collected by filtration. The precipitate was washed with cold water and dried under vacuum to give the orange solid product 2-bromo-3-fluorobenzoic acid in a yield of 22 g and 78%.
References
[1] Patent: US2008/293708, 2008, A1. Location in patent: Page/Page column 37
[2] Journal of Heterocyclic Chemistry, 1990, vol. 27, # 7, p. 2151 - 2163
2-Bromo-3-fluorobenzoic acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Bromo-3-fluorobenzoic acid manufacturers
Shaanxi Dideu Medichem Co. Ltd
- Product
- 2-Bromo-3-fluorobenzoic acid 132715-69-6
- Price
- US $0.10/KG
- Min. Order
- 0.1KG
- Purity
- 98%
- Supply Ability
- 200TONS
- Release date
- 2019-12-24
Career Henan Chemical Co
- Product
- 2-Bromo-3-fluorobenzoic acid 132715-69-6
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- JD 542
- Release date
- 2019-09-01
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