ChemicalBook > CAS DataBase List > MENTHONE

MENTHONE

Product Name: MENTHONE
CAS No.: 89-80-5
Chemical Name: MENTHONE
Synonyms: P-MENTHAN-3-ONE;2-Isopropyl-5-methylcyclohexanone;d-Menthone;MENTHON;p-Menthone;trans-Menthone;MENTHONE;FEMA 2667;MENTHON REIN;(±)-Menthone
CBNumber: CB6453271
Molecular Formula: C10H18O
Formula Weight: 154.25
MOL File: 89-80-5.mol

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MENTHONE Property

Melting point:: 147-148 °C
Boiling point:: 210°C
Density: 0.896
vapor pressure: 37Pa at 25℃
refractive index: 1.450
FEMA: 2667 | MENTHONE
Flash point:: 69 ºC
storage temp.: Refrigerator
solubility: Chloroform (Sparingly), Methanol (Sparingly)
form: Oil
color: Colourless
Odor: at 10.00 % in dipropylene glycol. minty
Odor Type: minty
Water Solubility: 688mg/L at 25℃
LogP: 2.295 at 25℃
NIST Chemistry Reference: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, trans-(89-80-5)
EPA Substance Registry System: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2R,5S)-rel- (89-80-5)

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Safety

Hazard Codes: Xn
Risk Statements: 22-36-43-52/53
Safety Statements: 26-36/37-61
HS Code: 29142990
Hazardous Substances Data: 89-80-5(Hazardous Substances Data)
Toxicity: The acute oral LD₅₀ in rats was reported as 2.18 ml/kg (1.82-2.62 ml/kg) (Levenstein, 1973a). The acute dermal LD₅₀ in rabbits exceeded 5 g/kg (Levenstein, 1973b)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M219135
Product name: (±)-Menthone
Packaging: 100mg
Price: $145
Updated: 2021/12/16

Chem-Impex

Product number: 34586
Product name: (-)-Menthone,96-100%(PuritybyGC),meetsFGspecifications,KOSHER,FEMA2667Hazmat
Purity: 96-100%(PuritybyGC)
Packaging: 1KG
Price: $260.92
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 71199
Product name: (+/-)-Menthone
Packaging: 1g
Price: $975
Updated: 2021/12/16

Chem-Impex

Product number: 34586
Product name: (-)-Menthone,96-100%(PuritybyGC),meetsFGspecifications,KOSHER,FEMA2667Hazmat
Purity: 96-100%(PuritybyGC)
Packaging: 180KG
Price: $14560
Updated: 2021/12/16

DC Chemicals

Product number: DCH-058
Product name: Menthone
Purity: >98%,StandardReferencesGrade
Packaging: 20mg
Price: $280
Updated: 2021/12/16

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MENTHONE Chemical Properties,Usage,Production

Description

Menthone has a characteristic odor similar to menthol. May be prepared by oxidation of menthol.

Chemical Properties

Menthone has a characteristic mint-like odor.

Occurrence

Reported found in severalstereoisomersin nature; l-menthone is a constituent of the essential oils of Russian and American peppermint, geranium, Andropogon gragrans, Mentha timija and Mentha arvensis; d-menthone is present in the essential oils of Barosma pulchellum, Nepeta japonica Maxim., and others. d-Isomenthone has been reported isolated from Micromeria abis sinica Benth., Pelargonium tomentosum Jacquin and others; l-isomenthone has been identified in Réunion geranium, Pelargonium capitau and others. Also reported found in lemon peel oil, black currants, celery seed, cinnamon, peppermint, cornmint, pennyroyal and other mentha oils, nutmeg, thymus, cocoa, mushrooms, starfruit, coriander leaf, rice, tarragon, calamus, buckwheat, sweet and bitter fennel, cherimoya, buchu oil, clam and sweet grass oil.

Uses

(±)-Menthone is a Menthol derivative. A volatile flavor compound found in human milk, red and black rice bran and specialty rice types.

Definition

ChEBI: (-)-menthone is a menthone that is cyclohexanone substituted by a methyl and an isopropyl group at positions 5 and 2 respectively (the 2S,5R-stereoisomer). It is an enantiomer of a (+)-menthone.

Preparation

By oxidation of menthol.

Aroma threshold values

Detection: 170 ppb; aroma characteristics at 1.0%: minty, cooling, sweet, refreshing, peppermint fresh, slightly dirty woody, camphoraceous with a green herbal anise nuance.

Taste threshold values

Taste characteristics at 50 ppm: cooling, peppermint, fresh green, minty, herbal, dirty mentholic with a refreshing camphoraceous nuance.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by ingestion, intravenous, and subcutaneous routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also KETONES.

Metabolism

H?m?l?inen (1912) claimed that menthone was probably oxidized in the rabbit to ketomenthone, since the glucuronide produced was converted by warm dilute H₂SO₄ to a substance which was probably △⁴⁽⁸ -p-menthen-3-one (pulegone). Williams (1940), however, showed that it underwent reduction in the rabbit with the production of d-neomenthol. The presence of l-menthol, the other possible reduction product, was not detected and it appeared that the biological reduction was asymmetric (Williams, 1959).

MENTHONE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from MENTHONE manufacturers

Career Henan Chemical Co

Product: MENTHONE 89-80-5
Price: US $6.60/KG
Min. Order: 500g
Purity: 98%
Supply Ability: 1KG, 50KG, 100KG
Release date: 2019-12-25

89-80-5, MENTHONERelated Search:

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P-MENTHAN-3-ONE

(±)-trans-p-menthan-3-one

Cyclohexanone, 5-methyl-2-(1-methylethyl)-, trans-

p-Menthan-3-one, trans-

p-Menthone

trans-Menthan-3-One

trans-Menthone

trans-p-Menthan-3-one

d-Menthone

menthone,trans-p-menthan-3-one,5-methyl-2-(1-methylethyl)-cyclohexanone

Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (2R,5S)-rel-

MENTHONERACEMIC

MENTHONEANDISOMENTHONE

PARA-MENTHAN-3-ONE

DL-PARA-MENTHAN-3-ONE

PARA-MENTHONE

MENTHON REIN

MENTHONE

MENTHON

FEMA 2667

trans-Menthon

L-MENTHONE, NATURAL

2-Isopropyl-5-methylcyclohexanone

(2S,5R)-5-methyl-2-propan-2-ylcyclohexan-1-one

(±)-Menthone

rel-(2S,5R)-5-methyl-2-(1-methylethyl)-cyclohexanone

89-80-5