ChemicalBook > CAS DataBase List > Methyl 4-aminopyridine-3-carboxylate

Methyl 4-aminopyridine-3-carboxylate

Product Name: Methyl 4-aminopyridine-3-carboxylate
CAS No.: 16135-36-7
Chemical Name: Methyl 4-aminopyridine-3-carboxylate
Synonyms: 3-Pyridinecarboxylic acid, 4-aMino-, Methyl ester;4-Aminonicotinate;RARECHEM AL BF 1386;METHYL-4-AMINONICOTINATE;4-Amino Methyl nicotinate;Methyl4-Aminonicotinate>Methyl4-aminonicotinate,98%;Methyl 4-aminonicotinate 98%;4-AMINONICOTINIC ACID METHYL ESTER;methyl 4-aminopyridine-3-carboxylate
CBNumber: CB6467292
Molecular Formula: C7H8N2O2
Formula Weight: 152.15
MOL File: 16135-36-7.mol

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Methyl 4-aminopyridine-3-carboxylate Property

Melting point:: 172-174℃
Boiling point:: 288.7±20.0 °C(Predicted)
Density: 1.238±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 7.04±0.12(Predicted)
color: White to Almost white
CAS DataBase Reference: 16135-36-7(CAS DataBase Reference)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-37
RIDADR: UN2811
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: PHB00050
Product name: Methyl 4-aminonicotinate
Purity: AldrichCPR
Packaging: 1 g
Price: $179
Updated: 2025/07/31

TCI Chemical

Product number: M2303
Product name: Methyl 4-Aminonicotinate
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $150
Updated: 2025/07/31

TCI Chemical

Product number: M2303
Product name: Methyl 4-Aminonicotinate
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $598
Updated: 2025/07/31

TRC

Product number: M331128
Product name: Methyl 4-Aminonicotinate
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA61456
Product name: 4-Aminonicotinic acid methyl ester
Packaging: 5G
Price: $90
Updated: 2021/12/16

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Methyl 4-aminopyridine-3-carboxylate Chemical Properties,Usage,Production

Chemical Properties

Off-white solid

Synthesis

280115-84-6

16135-36-7

General procedure for the synthesis of methyl 4-aminonicotinate from methyl 4-((tert-butoxycarbonyl)amino)nicotinate: 4-((tert-butoxycarbonyl)amino)nicotinate (9.08 g, 36.0 mmol) was dissolved in a 50/50 (v/v) trifluoroacetic acid (TFA)/dichloromethane (DCM) mixture (100 mL), and the reaction was stirred at room temperature for 2 hours. Upon completion of the reaction, the mixture was concentrated under reduced pressure to remove the solvent. Subsequently, the concentrate was redissolved in dichloromethane (100 mL), washed with saturated sodium bicarbonate solution, dried over anhydrous sodium sulfate and concentrated again under reduced pressure. Methyl 4-aminonicotinate (5.43 g, 99.1% yield) was finally obtained, the purity of which met the requirements of the subsequent reaction. The mass spectrum (chemical ionization, CI) showed a molecular ion peak (M/E) of 153.1.

References

[1] Patent: WO2003/103575, 2003, A2. Location in patent: Page 74
[2] Patent: WO2005/49604, 2005, A2. Location in patent: Page/Page column 107
[3] Patent: EP1140905, 2003, B1

Methyl 4-aminopyridine-3-carboxylate Preparation Products And Raw materials

Raw materials

Sodium dichromate dihydrate Hydrogen peroxide 3-Picoline Chloroform Palladium

Preparation Products

(4-AMINO-PYRIDIN-3-YL)-METHANOL

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View Lastest Price from Methyl 4-aminopyridine-3-carboxylate manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd

Product: Methyl 4-aminopyridine-3-carboxylate 16135-36-7
Price: US $70.00-700.00/kg
Min. Order: 10kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-11-09

Honest Joy Holdings Limited

Product: Methyl4-Aminonicotinate 16135-36-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.1%
Supply Ability: 100 tons
Release date: 2022-01-14

Career Henan Chemical Co

Product: Methyl 4-aminopyridine-3-carboxylate 16135-36-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2018-12-25

16135-36-7, Methyl 4-aminopyridine-3-carboxylateRelated Search:

4-Aminopyridine 3-Aminopyridine EC 2.6.1.2 METSULFURON METHYL 6-Aminocaproic acid Methyl salicylate Methyl isonicotinate Methyl carbamate Methyl anthranilate Kresoxim-methyl METHYL 6-OXO-1,6-DIHYDRO-3-PYRIDINECARBOXYLATE Aminopyrine Acetaminophen Sulfamic acid Glycine RESMETHRIN Methyl acrylate Thiophanate-methyl

Methyl 4-aminopyridine-3-carboxylate, 4-Aminonicotinic acid methyl ester

RARECHEM AL BF 1386

4-amino-3-pyridinecarboxylic acid methyl ester

4-AMINOPYRIDINE-3-CARBOXYLIC ACID METHYL ESTER

4-AMINONICOTINIC ACID METHYL ESTER

methyl 4-aminopyridine-3-carboxylate

METHYL-4-AMINONICOTINATE

4-Amino-nicotinic acid methyl ester ,97%

Methyl 4-aminonicotinate 98%

3-Pyridinecarboxylic acid, 4-aMino-, Methyl ester

Methyl 4-aminopyridine-3-carboxylate, 4-Amino-3-(methoxycarbonyl)pyridine

Methyl4-aminonicotinate,98%

Methyl4-Aminonicotinate&gt

4-Aminonicotinate

Methyl 4-aminopyridine-3-carboxylate ISO 9001：2015 REACH

4-Amino Methyl nicotinate

16135-36-7

16136-36-7

pharmacetical

Pyridine series

Esters

Pyridines

Pyridine