Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Uses

Product Name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS No.: 35138-22-8
Chemical Name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms: Bis(cycloocta-1,5-dien)rho;dipalladium(II);ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
CBNumber: CB6666011
Molecular Formula: C16H24BF4Rh
Formula Weight: 406.07
MOL File: 35138-22-8.mol

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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Property

Melting point:: 210 °C
Density: 0.42 g/cm3 (20℃)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Powder
color: Red
PH: 7 (5g/l, H2O, 20℃)
Water Solubility: insoluble
Sensitive: Slightly air & moisture sensitive
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey: IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference: 35138-22-8(CAS DataBase Reference)

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-34
Safety Statements: 16-45-36/37/39-26
RIDADR: UN 2921
WGK Germany: 2
Hazard Note: Irritant
TSCA: No
HazardClass: 8
PackingGroup: III
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H228Flammable solid

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 14694
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 100mg
Price: $124
Updated: 2024/03/01

TCI Chemical

Product number: B3961
Product name: Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging: 1g
Price: $653
Updated: 2024/03/01

TCI Chemical

Product number: B3961
Product name: Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging: 100mg
Price: $114
Updated: 2024/03/01

Alfa Aesar

Product number: 044031
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 1g
Price: $600
Updated: 2023/06/20

Alfa Aesar

Product number: 044031
Product name: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging: 5g
Price: $2600
Updated: 2023/06/20

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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Usage,Production

Uses

Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.

Chemical Properties

dark red

Uses

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

reaction suitability

core: rhodium
reagent type: catalyst

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Silver tetrafluoroborate Ethyl acetate 1,5-Cyclooctadiene

Preparation Products

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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Suppliers

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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers

Longyan Tianhua Biological Technology Co., Ltd

Product: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-08

35138-22-8, Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborateRelated Search:

Sodium tetrafluoroborate Octamethylcyclotetrasiloxane Rhodium 1,3-CYCLOOCTADIENE 1,5-Cyclooctadiene Potassium tetrafluoroborate Fluoroboric acid Ammonium fluoborate Dichloro(1,5-cyclooctadiene)palladium(II) methoxy(cyclooctadiene)rhodium(i) dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Tris(dibenzylideneacetone)dipalladium Dichloro(1,5-cyclooctadien)ruthenium(II) polymer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4

Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate

Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate

ooctadiene)rhodium(Ⅰ)tetrafL

(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate

RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX

Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis

BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE

BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&

Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%

Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate

Bis(cycloocta-1,5-dien)rho

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, [Rh(COD)2]BF4

(1Z,5Z)-cycloocta-1,5-diene,rhodium

Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate 1GR

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate ISO 9001：2015 REACH

Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)

bis[(1,2,5,6-η)-1,5-cyclooctadiene]-Rhodium(1+) tetrafluoroborate(1-) (1:1)

Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate

dipalladium(II)

35138-22-8

2C8H12BF4Rh

C16H24BF4Rh

C16H24RhBF4

RhC8H122BF

RhCOD2BF4

RhC8H122BF4

C8H6O4XH2O

Catalysis and Inorganic Chemistry

organometallic complex