ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Uses- Product Name
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- CAS No.
- 35138-22-8
- Chemical Name
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Synonyms
- Bis(cycloocta-1,5-dien)rho;ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate;Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
- CBNumber
- CB6666011
- Molecular Formula
- C16H24BF4Rh
- Formula Weight
- 406.07
- MOL File
- 35138-22-8.mol
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Property
- Melting point:
- 210 °C
- Density
- 0.42 g/cm3 (20℃)
- storage temp.
- Inert atmosphere,Store in freezer, under -20°C
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Powder
- color
- Red
- PH
- 7 (5g/l, H2O, 20℃)
- Water Solubility
- insoluble
- Sensitive
- Slightly air & moisture sensitive
- Exposure limits
- ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3 - InChIKey
- IEMMJJILGGBYNZ-GSLAGHMSSA-M
- CAS DataBase Reference
- 35138-22-8(CAS DataBase Reference)
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Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-34
- Safety Statements
- 16-45-36/37/39-26
- RIDADR
- UN 2921
- WGK Germany
- 2
- Hazard Note
- Irritant
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28439000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H228Flammable solid
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 14694
- Product name
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Packaging
- 100mg
- Price
- $124
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B3961
- Product name
- Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
- Packaging
- 1g
- Price
- $653
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B3961
- Product name
- Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
- Packaging
- 100mg
- Price
- $114
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 044031
- Product name
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Packaging
- 1g
- Price
- $600
- Updated
- 2023/06/20
Alfa Aesar
- Product number
- 044031
- Product name
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- Packaging
- 5g
- Price
- $2600
- Updated
- 2023/06/20
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Usage,Production
Uses
- Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
- Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions.
Chemical Properties
dark red
Uses
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Suppliers
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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers
Longyan Tianhua Biological Technology Co., Ltd
- Product
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-11
Career Henan Chemical Co
- Product
- Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-08
35138-22-8, Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborateRelated Search:
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