Uses
ChemicalBook > CAS DataBase List > Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Uses
Product Name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS No.
35138-22-8
Chemical Name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Synonyms
Bis(cycloocta-1,5-dien)rho;dipalladium(II);ooctadiene)rhodium(Ⅰ)tetrafL;(1Z,5Z)-cycloocta-1,5-diene,rhodium;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&;BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE;BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE;Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
CBNumber
CB6666011
Molecular Formula
C16H24BF4Rh
Formula Weight
406.07
MOL File
35138-22-8.mol
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Property

Melting point:
210 °C
Density 
0.42 g/cm3 (20℃)
storage temp. 
Inert atmosphere,Store in freezer, under -20°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Powder
color 
Red
PH
7 (5g/l, H2O, 20℃)
Water Solubility 
insoluble
Sensitive 
Slightly air & moisture sensitive
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey
IEMMJJILGGBYNZ-GSLAGHMSSA-M
CAS DataBase Reference
35138-22-8(CAS DataBase Reference)
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-34
Safety Statements 
16-45-36/37/39-26
RIDADR 
UN 2921
WGK Germany 
2
Hazard Note 
Irritant
TSCA 
No
HazardClass 
8
PackingGroup 
III
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
14694
Product name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging
100mg
Price
$124
Updated
2024/03/01
TCI Chemical
Product number
B3961
Product name
Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging
1g
Price
$653
Updated
2024/03/01
TCI Chemical
Product number
B3961
Product name
Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate
Packaging
100mg
Price
$114
Updated
2024/03/01
Alfa Aesar
Product number
044031
Product name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging
1g
Price
$600
Updated
2023/06/20
Alfa Aesar
Product number
044031
Product name
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
Packaging
5g
Price
$2600
Updated
2023/06/20
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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Chemical Properties,Usage,Production

Uses

  1. Convenient catalyst precursor, for example, with (R,R)QuinoxP* for asymmetric alkylations and hydrogenations.
  2. Catalyst precursor with chiral biaryl bisphosphine ligands for [2+2+2] enantioenriched cycloadditions. 

Chemical Properties

dark red

Uses

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is useful for hydrogenation, isomerization reactions and is also employed as a precursor for asymmetric hydrogenations. Furthermore, it is used in the synthesis of cationic COD-Rhodium complexes with phosphine ligands. In addition, it shows an important application for enantioselective hydrogenation and hydrosilylation.

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Preparation Products And Raw materials

Raw materials

Ethanol Rhodium(III) chloride hydrate Silver tetrafluoroborate Ethyl acetate 1,5-Cyclooctadiene

Preparation Products

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Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Suppliers

Americas 1 Belgium 4 Canada 1 China 166 Europe 1 France 1 Germany 7 India 12 Japan 2 South Korea 1 Spain 1 Switzerland 1 United Kingdom 8 United States 40 Global 246
Alfa Aesar, Thermo Fisher Scientific
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Germany
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CHEMOS GmbH & Co. KG
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chemos@chemos.de
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Germany
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W.C.Heraeus GmbH
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chemicals@heraeus.com
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Germany
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Convertex Chemie GmbH
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convertex@tpnet.de
Country
Germany
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Service Chemical Inc.
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sales@chemos-group.com
Country
Germany
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Merck Schuchardt OHG
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schuchardt-vertrieb@merck.de
Country
Germany
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ABCR GmbH & CO. KG
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info@abcr.de
Country
Germany
ProdList
6831
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View Lastest Price from Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 35138-22-8
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-08

35138-22-8, Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborateRelated Search:

Sodium tetrafluoroborate Octamethylcyclotetrasiloxane Rhodium 1,3-CYCLOOCTADIENE 1,5-Cyclooctadiene Potassium tetrafluoroborate Fluoroboric acid Ammonium fluoborate Dichloro(1,5-cyclooctadiene)palladium(II) methoxy(cyclooctadiene)rhodium(i) dimer Chloro(1,5-cyclooctadiene)iridium(I) dimer Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate BIS(1 5-CYCLOOCTADIENE)RHODIUM(I) Bis(1,5-cyclooctadiene)bis(μ-diphenylphosphido)dirhodium Tris(dibenzylideneacetone)dipalladium Dichloro(1,5-cyclooctadien)ruthenium(II) polymer BIS(1,5-CYCLOOCTADIENE)IRIDIUM (I) TETRAFLUOROBORATE

  • Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate,98% [Rh(COD)2]BF4
  • Bis(1,5-cyclooctadiene)rhodium(Ⅰ) tetrafluoroborate
  • Bis(cycloocta-1,5-diene)rhodium(I) tetrafluoroborate
  • ooctadiene)rhodium(Ⅰ)tetrafL
  • (1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
  • RHODIUM(I) TETRAFLUOROBORATE 1,5-CYCLOOCTADIENE COMPLEX
  • Bis(cycloocta-1,5-dien)rhodium(I)-tetrafluoroborat for synthesis
  • BIS(CYCLOOCTA-1,5-DIEN)RHODIUM(I)-TETRAFLUOROBORATE
  • BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
  • BIS(1,5-CYCLOOCTADIENE)RHODIUM TETRAFLUOROBORATE
  • BIS(1,5-CYCLOOCTADIEN)RHODIUM(I) TETRAFLUOROBORATE
  • BIS(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRA&
  • Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,98+%
  • Bis(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate Also available as trifluoromethanesulfonate and hexafluorophosphate
  • Bis(cycloocta-1,5-dien)rho
  • Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, [Rh(COD)2]BF4
  • (1Z,5Z)-cycloocta-1,5-diene,rhodium
  • Bis(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate 1GR
  • Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate ISO 9001：2015 REACH
  • Rhodium(1+), bis[(1,2,5,6-η)-1,5-cyclooctadiene]-, tetrafluoroborate(1-) (1:1)
  • bis[(1,2,5,6-η)-1,5-cyclooctadiene]-Rhodium(1+) tetrafluoroborate(1-) (1:1)
  • Bis[(1,2,5,6-n)-1,5-cyclooctadiene]-rhodium tetrafluoroborate
  • dipalladium(II)
  • 35138-22-8
  • 2C8H12BF4Rh
  • C16H24BF4Rh
  • C16H24RhBF4
  • RhC8H122BF
  • RhCOD2BF4
  • RhC8H122BF4
  • C8H6O4XH2O
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex