4-Bromobenzyl chloride

Product Name: 4-Bromobenzyl chloride
CAS No.: 589-17-3
Chemical Name: 4-Bromobenzyl chloride
Synonyms: 1-Bromo-4-(chloromethyl)benzene;P-BROMOBENZYL CHLORIDE;4-BROMOBENZYL CHLORIDE;4-bromo-à-chlorotoluene;4-Bromo-α-chlorotoluene;α-Chloro-4-bromotoluene;4-Bromobenzylchloride,97%;4-Bromobenzyl chloride,98%;4-Bromobenzyl Chloride >4-BROMO-ALPHA-CHLOROTOLUENE
CBNumber: CB6708142
Molecular Formula: C7H6BrCl
Formula Weight: 205.48
MOL File: 589-17-3.mol

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4-Bromobenzyl chloride Property

Melting point:: 36-40 °C
Boiling point:: 136-139 °C (27 mmHg)
Density: 1.3431 (rough estimate)
refractive index: 1.5750 (estimate)
Flash point:: 106-107°C/10mm
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder and Granules
color: White
Water Solubility: Insoluble in water.
Merck: 14,1410
BRN: 6123220
InChI: InChI=1S/C7H6BrCl/c8-7-3-1-6(5-9)2-4-7/h1-4H,5H2
InChIKey: BSIIGUGKOPPTPZ-UHFFFAOYSA-N
SMILES: C1(Br)=CC=C(CCl)C=C1
CAS DataBase Reference: 589-17-3(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-bromo-4-(chloromethyl)-(589-17-3)

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Safety

Hazard Codes: C
Risk Statements: 36/37-34
Safety Statements: 45-36/37/39-25-26
RIDADR: 3261
WGK Germany: 3
Hazard Note: Corrosive/Lachrymator
HazardClass: 8
PackingGroup: III
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 726362
Product name: 4-Bromobenzyl chloride
Purity: ≥97.0% (GC)
Packaging: 5g
Price: $36.3
Updated: 2023/06/20

Sigma-Aldrich

Product number: 726362
Product name: 4-Bromobenzyl chloride
Purity: ≥97.0% (GC)
Packaging: 25g
Price: $140
Updated: 2023/06/20

TCI Chemical

Product number: B3042
Product name: 4-Bromobenzyl Chloride
Packaging: 5G
Price: $17
Updated: 2025/07/31

TCI Chemical

Product number: B3042
Product name: 4-Bromobenzyl Chloride
Packaging: 25G
Price: $49
Updated: 2025/07/31

TRC

Product number: B810748
Product name: 4-Bromobenzyl chloride
Packaging: 100mg
Price: $60
Updated: 2021/12/16

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4-Bromobenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

light yellow crystal powder to light yellow liqui

Uses

4-Bromobenzyl chloride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Synthesis

873-75-6

589-17-3

General procedure for the synthesis of 4-bromobenzyl chloride from 4-bromobenzyl alcohol: 4-bromobenzyl alcohol (0.6 g, 0.6 mmol) and dichloromethane (5 mL) were added to a round bottom flask. After stirring for 10 min, oxalyl chloride or oxalyl bromide (0.6 mmol) was slowly added. The reaction mixture was magnetically stirred at room temperature. After the gas was released, 4-bromobenzyl alcohol (0.5 mmol) was added and the reaction mixture was heated to reflux. The progress of the reaction was monitored by TLC and after completion of the reaction, the mixture was cooled to room temperature and filtered. The solid on the funnel was washed with dichloromethane (3 x 10 mL), the filtrate was combined and concentrated under reduced pressure. The purity of the resulting 4-bromobenzyl chloride was confirmed by 1H NMR and 13C NMR spectral analysis.

Purification Methods

Crystallise the chloride from EtOH and distil it in a vacuum. [Beilstein 5 IV 832.] LACHRYMATORY.

References

[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[2] Organic Letters, 2013, vol. 15, # 1, p. 108 - 111
[3] Organic and Biomolecular Chemistry, 2013, vol. 11, # 24, p. 4016 - 4024
[4] Bulletin of the Korean Chemical Society, 2010, vol. 31, # 11, p. 3434 - 3436
[5] Organic Letters, 2018, vol. 20, # 10, p. 3061 - 3064

4-Bromobenzyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromobenzyl chloride Suppliers

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View Lastest Price from 4-Bromobenzyl chloride manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd

Product: 4-Bromobenzyl chloride 589-17-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: Customise
Release date: 2025-11-11

Career Henan Chemical Co

Product: 4-Bromobenzyl chloride 589-17-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-02

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4-Bromobenzyl chloride >=97.0% (GC)

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4-BROMOBENZYL CHLORIDE

4-BROMO-ALPHA-CHLOROTOLUENE

P-BROMOBENZYL CHLORIDE

4-Bromobenzyl chloride/4-Bromo-alpha-chlorotoluene

4-Bromobenzylchloride,97%

Benzene, 1-bromo-4-(chloromethyl)-

4-bromo-à-chlorotoluene

α-Chloro-4-bromotoluene

4-Bromobenzyl chloride,98%

4-Bromobenzyl chloride Solution, 1000ppm

4-Bromobenzyl Chloride &gt

589-17-3